Polymerizable anionic gemini surfactants: Physicochemical properties in aqueous solution and polymerization behavior

Journal of Oleo Science

Volumn 58, Issue 8, 2009, Pages 403-413

  Sakai, Kenichi ^a   Wada, Miyuki ^a   Matsuda, Wataru ^a   Tsuchiya, Koji ^a   Takamatsu, Yuichiro ^b   Tsubone, Kazuyuki ^b   Endo, Takeshi ^a   Torigoe, Kanjiro ^a   Sakai, Hideki ^a   Abe, Masahiko ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

^b Miyoshi Oil & Fat Co Ltd   (Japan)

Author keywords

Gemini surfactant; Micelle; Physicochemical property; Polymerization

Indexed keywords

EID: 68149165917     PISSN: 13458957     EISSN: 13473352     Source Type: Journal    
DOI: 10.5650/jos.58.403     Document Type: Article

References (23)

1. Zana, R.; Xia, J. Gemini Surfactants, Synthesis, Interfacial and Solution-Phase Behavior, and Applications (Zana, R.; Xia, J. ed.). Marcel Dekker., New York. Chapter 1 (2003).
2. nd edn. Marcel Dekker. New York. Chapter 7 (2003).
3. Zana, R.; Alami, E. Novel Surfactants: Preparation, Applications, and Biodegradability (Holmberg, K. ed.). Marcel Dekker. New York. Chapter 12 (2003).
4. Israelachvili, J.N. Intermolecular and Surface Forces, 2nd edn. Academic Press. San Diego. Chapter 17 (1992).
5. Pindzola, B.A.; Jin, J.; Gin, D.L. Cross-linked normal hexagonal and bicontinuous cubic assemblies via poly-merizable gemini amphiphiles. J. Am. Chem. Soc. 125, 2940-2949 (2003).
6. Hamid, S.M.; Sherrington, D.C. Novel quaternary ammonium amphiphilic (meth)acrylates: 1. Synthesis, melting and interfacial behaviour. Polymer 28, 325-331 (1987).
7. Summers, M.; Eastoe, J.; Davis, S.; Du, Z.; Richardson, R.M.; Heenan, R.K.; Steytler, D.; Grillo, I. Polymerization of cationic surfactant phases. Langmuir 17, 5388-5397 (2001).
8. Summers, M.; Eastoe, J. Applications of polymerizable surfactants. Adv. Colloid Interface Sci. 100 102, 137-152 (2003).
9. Abe, M.; Tsubone, K.; Koike, T.; Tsuchiya, K.; Ohkubo, T.; Sakai, H. Polymerizable cationic gemini surfactant. Langmuir 22, 8293-8297 (2006).
10. Abe, M.; Koike, T.; Nishiyama, H.; Sharma, S.J.; Tsubone, K.; Tsuchiya, K.; Sakai, K.; Sakai, H.; Shchipunov, Y.A.; Schmidt, J.; Talmon, Y. Polymerized assemblies of cationic gemini surfactants in aqueous solution. J. Colloid Interface Sci. 330, 250-253 (2009).
11. Zhu, Z.; González, Y.I.; Xu, H.; Kaler, E.W.; Liu, S. Polymerization of anionic wormlike micelles. Langmuir 22, 949-955 (2006).
12. Greene, B.W.; Sheetz, D.P. In situ polymerization of surface-active agents on latex particles II. The mechanical stability of styrene/butadiene latexes. J. Colloid Interface Sci. 32, 96-105 (1970).
13. Liu, J.; Chew, C.H.; Gan, L.M.; Teo, W.K.; Gan, L.H. Synthesis of monodisperse polystyrene microlatexes by emulsion polymerization using a polymerizable surfactant. Langmuir 13, 4988-4994 (1997).
14. Tajima, K.; Aida, T. Controlled polymerizations with constrained geometries. Chem. Commun. 2399-2412 (2000).
15. Akbay, C.; Gill, N.L.; Powe, A.; Warner, I.M. Monomeric and polymeric anionic gemini surfactants and mixed surfactant systems in micellar electrokinetic chro-matography. Part I: Characterization and application as novel pseudostationary phases. Electrophoresis 26, 415-425 (2005).
16. Kalyansundaram, K.; Thomas, J.K. Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems. J. Am. Chem. Soc. 99, 2039-2044 (1977).
17. Ananthapadmanabhan, K.P.; Goddard, E.D.; Turro, N.J.; Kuo, P.L. Fluorescence probes for critical micelle con-centration. Langmuir 1, 352-355 (1985).
18. rd edn. John Wiley & Sons Ltd.,New York (2004).
19. Zana, R. Critical micellization concentration of surfactants in aqueous solution and free energy of micellization. Langmuir 12, 1208-1211 (1996).
20. Corrin, M.L.; Harkins, W.D. The effect of salts on the critical concentration for the formation of micelles in colloidal electrolytes. J. Am. Chem. Soc. 69, 683-688 (1947).
21. Ozeki, S.; Ikeda, S. The sphere-rod transition of micelles and the two-step micellization of dodecyltrimethylammonium bromide in aqueous NaBr solutions. J. Colloid Interface Sci. 87, 424-435 (1982).
22. Alami, E.; Beinert, G.; Marie, P.; Zana, R. Alkanediyla,α,ω-bis(dimethylalkylammonium bromide) surfactants. 3. Behavior at the air-water interface. Langmuir 9, 1465-1467 (1993).
23. Sakai, K.; Umezawa, S.; Tamura, M.; Takamatsu, Y.; Tsuchiya, K.; Torigoe, K.; Ohkubo, T.; Yoshimura, T.; Esumi, K.; Sakai, H.; Abe, M. Adsorption and micellization behavior of novel gluconamide-type gemini surfactant. J. Colloid Interface Sci. 318, 440-448 (2008).