A new approach to describe high-pressure adsorption isotherms in subcritical and supercritical conditions

AIChE Journal

Volumn 55, Issue 7, 2009, Pages 1793-1802

  Chilev, C ^a,b   Weinberger, B ^a   Passarello, J P ^a   Lamari, F Darkrim ^a   Pentchev, I ^b  

^a UNIVERSITÉ PARIS 13   (France)

^b UNIVERSITY OF CHEMICAL TECHNOLOGY AND METALLURGY   (Bulgaria)

Author keywords

Adsorption equilibrium; Excess adsorption; High pressure adsorption; Supercritical conditions; Thermodynamic analysis

Indexed keywords

ADSORPTION EQUILIBRIUM; EXCESS ADSORPTION; HIGH-PRESSURE ADSORPTION; SUPERCRITICAL CONDITIONS; THERMODYNAMIC ANALYSIS;

ADSORPTION ISOTHERMS; ATMOSPHERIC TEMPERATURE; STATISTICAL MECHANICS; THERMOANALYSIS; THERMODYNAMIC PROPERTIES;

ADSORPTION;

EID: 68049148651     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.11778     Document Type: Article

References (52)

1. Barto S, Dacey S, Quinn DF. In: Mayers AL, Belfor G, editors. Fundamental of Adsorption. New York: Engineering Foundation, 1984:65.
2. Yang TR. Gas Separation by Adsorption Processes. London: Imperial College Press, 1997.
3. IUPAC. Commission on colloid and surface chemistry including catalysis. Pure Appl Chem. 1985;57:603.
4. IUPAC. Commission on colloid and surface chemistry. Pure Appl Chem. 1994;66:1739.
5. Darkrim F, Vermesse J, Malbrunot P, Levesque D. Monte Carlo simulations of nitrogen and hydrogen physisorption at high pressures and room temperature. Comp Exp J Chem Phys. 1999;110:4020-4027.
6. Specovius J, Findenegg GH. Physical adsorption of gases at high pressures part V Argon and methane onto graphitised carbon black. Ber Bunsenges Phys Chem. 1978;82:174-180.
7. Wakasugi Y, Ozawa S, Kusumi S, Ozima Y. Physical adsorption of gases at high pressure. V. An extension of a generalized adsorption equation to systems with polar adsorbents. J Colloid Interface Sci. 1981;79:399-409.
8. Blumel S, Foster F, Finderberg GH. Physical adsorption of krypton on graphite over a wide density range. J Chem Soc Faraday Trans II. 1982;78:1753-2176
9. Finderberg GH, Korner B, Fischer J, Bohn M. Supercritical adsorption in porous materials. Part I: storage of krypton in molecular sieve. Ger Chem Eng. 1983;6:80-88.
10. Jiang S, Zollweg J, Gubbins K. High pressure adsorption of methane and ethane in activated carbon and carbon fibres. J Phys Chem. 1994;98:5709-5713.
11. Zhou L, Zhou Y. A compressive model for the adsorption of supercritical hydrogen on activated carbon. Ind Engng Chem Res. 1996;35:4166-4172.
12. Bernard P, Chahine R. Modelling of high pressure adsorption isotherms above the critical temperature: application to methane. Langmuir. 1997;13:808-813.
13. Kaneko K, Murata K. An analytical method of micropore filling of a supercritical gas. Adsorption. 1997;3:197-208.
14. Zhou L, Chen LP, Li M, Sun Y, Zhou Y. Prying the nature of supercritical adsorption via isotherm space transformation. In: Do DD, editor. Adsorption Science and Technology. 2000:717-721.
15. Zhou L, Zhou Y, Chen P, Li M, Wang Y. Experimental and modelling study of the adsorption of supercritical methane on a high surface area activated carbon. Langmuir. 2000;16:5955-5959.
16. Keller J, Staudt R. Gas Adsorption Equilibria Experimental Methods and Adsorption Isotherms. Boston: Springer Science, Business Media. 2005.
17. Do DD, Do HD. Adsorption of supercritical fluids in non-porous and porous carbons: analysis of adsorbed phase volume and density. Carbon. 2003;41:1777-1791.
18. Ono S, Kondo S. Molecular Theory of Surface Tension in Liquids. Berlin: Springer-Verlag, 1960.
19. Aranovich LG, Donohue DM. Adsorption isotherms for microporous adsorbents. Carbon. 1995;33:1369-1375.
20. Aranovich LG, Donohue DM. Adsorption of supercritical fluid. J Chem Phys. 1996;104:3851-3859.
21. Aranovich LG, Donohue DM. Analysis of adsorption isotherms: lattice theory predictions, classification of isotherms for gas-solid equilibria, and similarity in gas and liquid adsorption behaviour. J Colloid Interface Sci. 1998;200:273-290.
22. Aranovich LG, Donohue DM. Vapour adsorption on microporous adsorbents. Carbon. 2000;38:701-708.
23. Honigberg MG. Chemical equilibrium and Velocity of Reactions at High Pressures (in Russian). Moscow: Chimia, 1969:117-119.
24. Beutekamp S, Harting P. Experimental determination and analysis of high pressure adsorption data of pour gases and gas mixtures. Adsorption. 2002;8:255-269.
25. Herbst A, Beutekamp S, Harting P. Thermodynamic description of excess isotherms in highpressure adsorption of methane, argon, and nitrogen, Adsorption. 2002;8:111-123.
26. Staudt R, Herbst A, Beutekamp S, Harting P. Adsorption of pure gases and mixtures on porous solid up to high pressure. Adsorption. 2005;11:379-384.
27. Rangarajan B, Lira TC, Subramanian R. Simplified local density model for adsorption over large pressure ranges. AIChE J. 1995;41: 838-845.
28. Subramanian R, Pyada H, Lira TC. An Engineering model for adsorption of gases onto flat surfaces and clustering in supercritical fluids. Ind Eng Chem Res. 1995;34:3830-3837.
29. Chen JH, Wong DSH, Tan CS, Subramanian R, Lira CT, Orth M. Adsorption and desorption of carbon dioxide onto and from activated carbon at high pressure. Ind Eng Chem Res. 1997;36:2808-2815.
30. Do DD. Adsorption Analysis: Equilibrium and Kinetics. London: Imperial College Press, 1998.
31. Dubinin MM. Porous structure of carbon and adsorption property of active carbon. In: Walker PL, editor. Chemistry and Physics of Carbon. New York: Mercel Dekker, 1966:51-120.
32. Dubinin MM, Radushkevich LV. The equation of the characteristic curve of activated charcoal VL. Dokl AN SSSR. 1947;55:327-329.
33. Dubinin MM, Astakhov VA. Development of volumetric filling of micropore with vapours on the micropore adsorbents. Izv Acad Nauk SSSR Ser Chim. 1971;5-17.
34. Murata K, Kaneko K. Nano-range interfacial layer upon high pressure adsorption of supercritical gases. Chem Phys Lett. 2000;321: 342-348.
35. Ozawa S, Kusumi S, Ozima Y. Physical adsorption of gases at high pressure. Part IV: an improvement of Dubinin Astakhov adsorption equation. J Colloid Interface Sci. 1976;56:174-180.
36. Zhou L, Zhou Y. Linearization of adsorption isotherms for highpressure application. Chem Eng Sci. 1998;53:2531-2536.
37. Do DD1, Do HD. Adsorption of argon from sub-to supercritical conditions on graphitised thermal carbon black and in graphitic slit pores: a grand canonical Monte Carlo simulation study. J Chem Phys. 2005;123:084701.
38. Darkrim F, Levesque D. Monte Carlo simulations of hydrogen adsorption in single-walled carbon nanotubes. J Chem Phys. 1998; 109:4981-4984.
39. Weinberger B, Lamari FD, Kayiran S, Giquel A, Levesque D. Molecular modelling of H2 purification on Na-LSX zeolite and experimental validation, AIChE J. 2005;51:142-148.
40. Weinberger PB. Réalisation d'un dispositif d'adsorption et son utilisation pour l'étude de la purification de l'hydrogène par PSA. PhD thesis, Université Paris 13; CNRS UPR1311, 99 Av.J.B. Clément, 93430 Villetaneuse, France. 2005.
41. Menon PG. Adsorption of carbon monoxide on aluminia at high pressures. J Am Chem Soc. 1965;87:3057-3060.
42. Menon PG. Adsorption at high pressures. Chem Rev. 1968;68:277-294.
43. Malbrunot P, Vidal D, Vermesse J, Chahine R, Bose T. Adsorption measurement of argon, neon, krypton, nitrogen and methane on activated carbon up to 650 MPa. Langmuir. 1992;8:557-580.
44. Guggenheim EA. Mixtures the Theory of the Equilibrium Properties of Some Simple Classes of Mixtures Solutions and Alloy. Oxford: Clarendon Press, 1952.
45. Prausnitz JM, Lichtenthaler RN, Azevedo EG. Molecular Thermodynamics of Fluid-Phase Equilibria. New Jersey: PTR Prentice-Hall, 1986.
46. Hocker Th, Aranovich GL, Donohue MD. Monolayer adsorption for the subcritical lattice gas and partially miscible binary mixtures. J Colloid Interface Sci. 1999;211:60-80.
47. Hirschfelder JB, Curtiss FC, Brind RB. Molecular Theory of Gases and Liquid. New York: John Wiley, 1954.
48. Adamson AW, Gast AP. Physical Chemistry of Surfaces. New York: Wiley-interscience, John Wiley, 1997.
49. Reich R, Zlagler WT, Rogers KA. Adsorption of methane, ethane, and ethylene gases and their binary and ternary mixtures and carbon dioxide on activated carbon at 212-301 K and pressure to 35 Atmospheres. Ind Eng Chem Process Des Dev. 1980;19:336-344.
50. Dreisbach F, Lösch HW. Highest Pressure adsorption equilibrium data: measurement with magnetic suspension balance and analysis with a new adsorbent/adsorbat-Volume. Adsorption. 2002;8:95-109.
51. Aranovich GL, Donohue M. Determining surface areas from linear adsorption isotherms at supercritical condition. J Colloid Interface Sci. 1997;194:392-397.
52. Aranovich GL, Sangwichien C, Donohue MD. Intermolecular repulsions in adsorbed layers. J Colloid Interface Sci. 2000;227:553-560.