N-Bromosuccinimide oxidation of maltose and d-galactose using chloro-complex of Rh(III) in its nano-concentration range as homogeneous catalyst: A kinetic and mechanistic study

Journal of Molecular Catalysis A: Chemical

Volumn 310, Issue 1-2, 2009, Pages 64-74

  Singh, Ashok Kumar ^a   Srivastava, Rashmi ^a   Srivastava, Shalini ^a   Srivastava, Jaya ^a   Rahmani, Shahla ^a   Singh, Bharat ^a  

^a UNIVERSITY OF ALLAHABAD   (India)

Author keywords

Chloro complex of Rh(III); Kinetics; Protonated N bromosuccinimide oxidation; Reducing sugars; Spectrophotometric evidence

Indexed keywords

ACIDIC MEDIUMS; ACTIVATED COMPLEX; ACTIVATION PARAMETER; CHLORO-COMPLEX OF RH(III); CONCENTRATION OF; CONCENTRATION RANGES; D-GALACTOSE; DIELECTRIC CONSTANTS; ENTROPY OF ACTIVATION; FIRST ORDER KINETICS; HOMOGENEOUS CATALYST; KINETIC ORDER; KINETICS OF OXIDATION; MECHANISTIC STUDIES; N-BROMOSUCCINIMIDE; ORDER OF REACTION; OXIDATION PRODUCTS; OXIDATION RATES; PROTONATED; PROTONATED N-BROMOSUCCINIMIDE OXIDATION; PSEUDO-FIRST-ORDER RATE CONSTANT; REACTION PATHS; REACTIVE SPECIES; REDUCING SUGARS; SPECTROPHOTOMETRIC EVIDENCE; SUCCINIMIDE; ZERO EFFECTS;

CATALYSIS; CATALYSTS; CERAMIC CAPACITORS; CHLORINE COMPOUNDS; DIELECTRIC WAVEGUIDES; FORMIC ACID; IONIC STRENGTH; MALTOSE; MERCURY (METAL); ORGANIC ACIDS; OXIDATION; PERMITTIVITY; RATE CONSTANTS; RHODIUM; SPECTROPHOTOMETERS; SPECTROPHOTOMETRY; SUGAR (SUCROSE);

RHODIUM COMPOUNDS;

EID: 67849118610     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2009.05.020     Document Type: Article

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