Organoactinide-mediated hydrothiolation of terminal alkynes with aliphatic, aromatic, and benzylic thiols

Journal of the American Chemical Society

Volumn 131, Issue 6, 2009, Pages 2062-2063

  Weiss, Charles J ^a   Wobser, Stephen D ^a   Marks, Tobin J ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALIPHATIC THIOLS; BENZYLIC; CATALYTIC CYCLES; FIRST-ORDER; HYDROTHIOLATION; KINETIC MEASUREMENT; PROTONOLYSIS; TERMINAL ALKYNE;

AROMATIC COMPOUNDS;

ACETYLENE;

ACTINIDE; ALIPHATIC CARBOXYLIC ACID; ALKENE; ALKYL GROUP; ALKYNE; ALLENE DERIVATIVE; AROMATIC CARBOXYLIC ACID; BENZILIC ACID; CARBON; DEUTERIUM; ELEMENT; HYDROGEN; LANTHANIDE; METAL COMPLEX; NICKEL COMPLEX; ORGANOACTINIDE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; THIOBENZYL ALCOHOL; THIOL DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

ARTICLE; BIOTRANSFORMATION; CATALYSIS; CATALYST; CHEMICAL REACTION; CYCLOADDITION; DEUTERON NUCLEAR MAGNETIC RESONANCE; ENERGY YIELD; ENTHALPY; HYDROLYSIS; KINETICS; PHASE TRANSITION; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; STEREOCHEMISTRY; STEREOSPECIFICITY; THERMOSTABILITY;

EID: 67849114613     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja808764q     Document Type: Article

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49. Hydrothiolation has also been successfully carried out with organolanthanide catalysts. Reports will be forthcoming.