Key role of Ti(IV) in the selective radical - radical cross-coupling mediated by the ingold-Fischer effect

Journal of the American Chemical Society

Volumn 130, Issue 52, 2008, Pages 18018-18024

  Spaccini, Raffaele ^a   Pastori, Nadia ^a   Clerici, Angelo ^a   Punta, Carlo ^a   Porta, Ombretta ^a  

^a POLITECNICO DI MILANO   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

[CARBONYL; AZOBISISOBUTYRONITRILE; C-C BONDS; CARBON-CENTERED RADICALS; CROSS-COUPLING; HIGH YIELD; HYDROXYL GROUPS; INNOVATIVE APPROACHES; REACTION MECHANISM; SELECTIVE SYNTHESIS;

CHELATION; KETONES;

FREE RADICAL REACTIONS;

2 PROPANOL; 2,2 AZO BIS ISOBUTYRONITRILE; 3 CYANO 2 HYDROXY 3,3 DIMETHYL 2 PHENYL PROPIONIC ACID; 3 HYDROXY 2,2 DIMETHYL 3 PARA TOLYLPROPANENITRILE; 3 HYDROXY 2,2 DIMETHYL 3 PHENYL PROPRIONITRILE; 3 HYDROXY 2,2 DIMETHYL 4 OXO 3 PHENYL PENTANENITRILE; 3 HYDROXY 2,2 DIMETHYL 4 OXO 3,4 DIPHENYL BUTYRONITRILE; 4 (2 CYANO 1 HYDROXY 2,2 DIMETHYL ETHYL)BENZONITRILE; ALPHA CYANOISOPROPYL RADICAL; ALPHA HYDROXY ALPHA CARBONYL RADICAL; ALPHA,BETA DIHYDROXY KETONE DERIVATIVE; BIPHENYL; CARBONYL DERIVATIVE; DIMETHYL 2,3 DIHYDROXY 2,3 DIPHENYL BUTANEDIOATE; HYDROXYL GROUP; KETONE DERIVATIVE; METAL ION; METHYL MADELATE; NITRILE; PROPIONIC ACID; TITANIUM; TITANIUM TETRACHLORIDE; UNCLASSIFIED DRUG;

ARTICLE; CHELATION; CHEMICAL REACTION; CONTROLLED STUDY; DECOMPOSITION; INGOLD FISCHER EFFECT; ISOMER; POLYMERIZATION; STEREOCHEMISTRY; STOICHIOMETRY; SYNTHESIS; THERMAL ANALYSIS;

EID: 67849101267     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja807613q     Document Type: Article

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