Probing the mechanism of the PCl 5-initiated living cationic polymerization of the phosphoranimine Cl 3P=NSiMe 3 using model compound chemistry

Journal of the American Chemical Society

Volumn 131, Issue 10, 2009, Pages 3658-3667

  Blackstone, Vivienne ^a,b   Lough, Alan J ^a,b   Murray, Martin ^a,b   Manners, Ian ^a,b  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

^b UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AMBIENT TEMPERATURES; CATIONIC CHAINS; CATIONIC INTERMEDIATES; CHAIN BRANCHING REACTIONS; CHAIN-ENDS; CHAIN-GROWTH POLYCONDENSATION; KEY FACTORS; LIVING CATIONIC POLYMERIZATION; LOSS OF CONTROL; MODEL COMPOUND; NEAR STOICHIOMETRIC; ONE CHAIN; POLYMERIZATION CONDITIONS; REACTION CONDITIONS;

LIVING POLYMERIZATION; MOLECULAR WEIGHT DISTRIBUTION; OLIGOMERIZATION; PH; POLYCONDENSATION; POLYMERS; SALTS; SILANES;

CATIONIC POLYMERIZATION;

CATION; IMINE; MONOMER; OLIGOMER; PHOSPHORANIMINE; POLY(DICHLOROPHOSPHAZENE); POLYMER; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; ENVIRONMENTAL TEMPERATURE; MOLECULAR MODEL; MOLECULAR PROBE; MOLECULAR WEIGHT; OLIGOMERIZATION; POLYMERIZATION; REACTION ANALYSIS; RING OPENING METATHESIS POLYMERIZATION; STOICHIOMETRY; STRUCTURE ANALYSIS; SUPRAMOLECULAR CHEMISTRY;

EID: 67749114495     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja808517d     Document Type: Article

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