Spectroscopic, magnetic and biological studies on some metal(II) complexes of 3-(4,6-Dimethyl-2Pyrimidinylamino)-1-Phenyl-2-Butenone and the Mixed complexes with 2,2' -Bipyridine and 1,10-Phenanthroline

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

Volumn 39, Issue 3, 2009, Pages 165-174

  Osowole, A A ^a   Kolawole, G A ^b   Kempe, R ^a   Fagade, O E ^c  

^a UNIVERSITY OF BAYREUTH   (Germany)

^b UNIVERSITY OF ZULULAND   (South Africa)

^c UNIVERSITY OF IBADAN   (Nigeria)

Author keywords

Adducts; Antimicrobial studies; Ciprofloxacin; Pyrimidinyl ketoimine

Indexed keywords

EID: 67651241490     PISSN: 15533174     EISSN: 15533182     Source Type: Journal    
DOI: 10.1080/15533170902785109     Document Type: Article

References (35)

1. Raman, N., Kulandaisamy, A., and Jeyasubramanian, K. Synthesis, spectroscopic characterization, redox and biological screening of some Schiff base transition metal(II) complexes derived from salicylidene-4-aminoantipyrine and 2-aminophenol/2-aminothiophenol. Synth. React. Inorg. Met.-Org. Chem., 2001, 31(7), 1249-1270.
2. Chohan, Z.H. Synthesis, characterization and biological properties of bivalent transition metal complexes of Co(II), Cu(II), Ni(II) and Zn(II) with some acylhydrazine derived from furanyl and thienyl ONO and SNO donor Schiff base ligands. and Synth. React. Inorg. Met.-Org. Chem., 2001, 31(1), 1-16.
3. Singh, K.N., Singh, D.K., and Singh, S.B. Synthesis, characterization and biological studies on Co(II), Ni(II), Cu(II) and Zn(II) complexes with N-picolinoyl-N-thiobenzoyl hydrazine. Synth. React. Inorg. Met.-Org. Chem., 2001, 32(4), 703-720.
4. Kwiatoski, E., and Kwiatoski, M. Unsymmetrical Schiff base complexes of Ni(II) and Pd(II). Inorg. Chim. Acta., 1980, 47(2), 197-202.
5. Hirotsu, M., Kojima, M., Nakajima, K., Kashino, S., Yoshikawa, Y. Stereochemistry and electrochemistry of Co(II) and Cu(II) complexes containing optically active tetradentate Schiff base ligands. Bull. Chem. Soc. Jpn., 1996, 69(9), 2549-2557.
6. Osowole, A.A., Kolawole, G.A., and Fagade, O.E. Spectroscopic, characterization and biological activities of Ni(II), Cu(II) and Zn(II) complexes of unsymmetrical Sciff bases and their adducts. Bull. Sci. Assoc. Nig., 2004, 25, 57-66.
7. Osowole, A.A., Kolawole, G.A., and Fagade, O. Synthesis, physicochemical and biological properties of nickel(II), copper(II) and zinc(II) complexes of an tetradentate Schiff-base and adducts. Intl. J. Chem., 2005, 15(4), 237-246.
8. Osowole, A.A., Kolawole, G.A., and Fagade, O. Synthesis, physicochemical and biological properties of nickel(II), copper(II) and zinc(II) complexes of an unsymmetrical tetradentate Schiff-base and their adducts. Synth. React. Inorg. Met. Org. Chem. Nano-Met. Chem., 2005, 35, 829-836.
9. Osowole, A.A., Kolawole, G.A., and Fagade, O. Synthesis, characterization and biological studies of unsymmetrical Schiff-base nickel(II), copper(II) and zinc(II) complexes and adducts with 2, 2′-dipyridyl and 1, 10-phenanthroline. J. Coord. Chem., 2008, 61(7), 1046-1055.
10. Fedchuk, A.S., Lozitsky, V.P., Dyachenko, N.S., Nosach, L.N., Povnitsa, O., Zhovnovataya, V.L., Eynde, J.J.V., Lozzitskaya, R.N., Kamalov, G.L., Kryszhanovsky, D., Kuzmin, V.E., and Sausville, E. Anticancer and antiviral properties of macrocyclic pyridinophanes and their derivatives. Exptl. Oncol., 2001, 23, 193-196.
11. Shaban, M.A.E., Taha, M.A.M., and Nasr, A.Z. Synthesis and biological activities of 6-aryl-1,2,4-triazolo(3,4-a)phthalazines and 6-aryl-tetra- tetrazolo(5,1,-a)phthalazines. J. Islamic Acad. Sci., 1990, 3(2), 98-102.
12. Islam, M.S., Farooque, M.A., Bodruddoza, M.A.K., Mosaddik, M.A., and Alam, M.S. Antimicrobial and toxicological studies of mixed ligand transition metal complexes of Schiff bases. Online J. Biol. Sci., 2002, 2(12), 797-799.
13. Gorneva, G., Mateva, R., Gugova, R., and Golovinsky, E. Antimicrobial and toxicological studies of mixed ligand transition metal complexes of Schiff bases. Arch. Oncol., 2005, 13(2), 62-64.
14. Tripathi, L., Kumar, P., and Singhai, A.K. Role of chelates in the treatment of cancer. Indian J. Cancer., 2007, 44(2), 62-71.
15. Laitalainen,T., Serimaa, R., Vahvaselka, S., and Reunanen, A. Preparation and small-angle X-ray scattering study of Pt-pyrimidine greens in aqueous solution. Inorg. Chim. Acta., 1996, 248, 121-127.
16. Thangadurai, T.D., and Natarajan, K. Mixed ligand complexes of ruthenium(II) containing α,/β-unsaturated-/β-ketoamines and their antibacterial activity. Trans. Met. Chem., 2001, 26, 500-504.
17. Osowole, A.A., Woods, J.A.O., and Odunola, O.A. Physicochemical properties of some nickel(II) 3-chloro ß-ketoamines and their adducts with 2,2′-bipyridyl and 1,10-phenanthroline. Intl. J. Chem., 2002, 12(1), 47-56.
18. Osowole, A.A., Woods, J.A.O., and Odunola, O.A. Synthesis and characterisation of some nickel(II) ß-ketoamines and their adducts with 2,2′-bipyridine and 1,10-phenanthroline. Synth. React. Inorg. Met.-Org. Chem., 2002, 32(4), 783-799.
19. Jejurkar, C.R., and Parikh, K. Synthesis and characterization of Schiff base complexes of Cu(II), Ni(II), V(IV). Asian J. Chem., 1997, 9(4), 624-626.
20. Gorneva, G.A., and Golovinsky, E. Comparative study of the apoptogenic effect of fluoropyrimidines on murine leukemia cells. Nova Acta Leopoldina, 2003, 87(329), 183-189.
21. Raman, N., Kulandaisamy, A., Thangaraja, C, and Jeyasubramanian K. Redox and antimicrobial studies of transition metal(II) tetradentate Schiff base complexes. Trans. Met. Chem., 2003, 28(1), 29-36.
22. Bassett, J., Denney, R.C., Jeffery, G.H., and Mendham, J. Vogel's Textbook of Quantitative Inorganic Analysis, 1978, ELBS, London, pp. 325-361.
23. Earnshaw, A. The Introduction to Magnetochemistry, 1980, London: Academic Press, pp. 80-88.
24. Geary, W.J. The use of conductivity measurements in organic solvents for the characterization of coordination compounds. Coord. Chem. Rev., 1971, 7, 81-122.
25. Tans, S-F, and Ang, K-P, Jayachandran, H. Inonization constants of some Schiff bases in 80% (w/w) dimethyl sulphoxide-water solvent at 25°C. J. Chem. Soc. (Perkin Trans II), 1983, 1011-1014.
26. Lever, A.B.P Inorganic Electronic Spectroscopy, 4th Ed., 1980, London: Elsevier, pp. 481-579.
27. Sacconi, L. Electronic structure and stereochemistry of Ni(II). In Transition Metal Chemistry: A Series of Advances, Carlin, R.L., (Ed), 1968, Vol. 4, p 199-298.
28. Cotton, FA., Wilkinson, G., Murillo, C.A., and Bochmann, M. Advanced Inorganic Chemistry, 6th Ed., 1999, New York: John Wiley, pp. 857-859.
29. Osanai, K., Okazawa, A., Nogami, T, and Ishida, T. Strong ferromagnetic exchange couplings in Cu(II) and Ni(II) complexes with a paramagnetic tridentate chelate ligand, 2,2′-bipyridin-6-yl tert-butyl nitroxide. J. Am. Chem. Soc., 2006, 128, 14008-14009.
30. Ishida, T, Mitsubori, S-I., Nogami, T, Ishikawa, Y, Yasui, M., Iwasaki, F, Iwamura, H., Takeda, N., and Ishikawa, M. Intra- and inter-molecular ferromagnetic interaction of transition metal complexes containing pyrimidine or pyrazine derivatives. Synth. Met., 1995, 71, 1791-1792.
31. Chen, L., and Coleman, W.G. Jr. Cloning and characterization of the Escherichia coli K-12 rfa-2 (rfaC) gene, a gene required for lipopolysaccharide inner core synthesis. J. Bacteriology, 1993, 175, 2534- 2540.
32. Raetz, C.R.H. Bacterial endotoxins: extraordinary lipids that activate eucaryotic signal transduction. J. Bacteriology, 1993, 175, 5745- 5753.
33. Peng, L., Yi, L., Xi, L., Lifang, R., and Chaocan, Z.J.Studyon biological effect of a kind of hetero-bimetallic Schiff-base on escherichia coli. Thermal Anal. Colorim., 2007, 89, 881-885.
34. Rehder, D. Biological and medicinal aspects of vanadium. Inorg. Med. Comm., 2003, 6(5), 604-617.
35. Pelczar, M.J.Jr., Chan, E.C.S., and Krieg, N.R. Microbiology, 1996, New York: McGraw-Hill, pp. 469-510.