Revealing a second transmetalation step in the Negishi coupling and its competition with reductive elimination: Improvement in the interpretation of the mechanism of biaryl syntheses

Journal of the American Chemical Society

Volumn 131, Issue 29, 2009, Pages 10201-10210

  Liu, Qiang ^a   Lan, Yu ^b,c   Liu, Jing ^a   Li, Gang ^a   Wu, Yun Dong ^b,c   Lei, Aiwen ^a,d  

^a WUHAN UNIVERSITY   (China)

^b PEKING UNIVERSITY   (China)

^c HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^d SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

BIARYL SYNTHESIS; CROSS-COUPLING; CROSS-COUPLING PRODUCTS; DENSITY FUNCTIONAL; HOMOCOUPLING; NEGISHI COUPLING; ORGANOZINC REAGENTS; REDUCTIVE ELIMINATION; THEORETICAL CALCULATIONS; THEORETICAL INVESTIGATIONS; TRANSMETALATION; TRANSMETALATION REACTION;

COMPETITION; ORGANOMETALLICS; PALLADIUM; ZINC COMPOUNDS;

ARGON;

ARGON; PALLADIUM; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; ZINC CHLORIDE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CROSS COUPLING REACTION; DEHALOGENATION; DENSITY FUNCTIONAL THEORY; NEGISHI COUPLING REACTION; REDUCTION; SYNTHESIS; TRANSMETALATION REACTION;

BENZENE DERIVATIVES; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PALLADIUM; TIME FACTORS;

EID: 67651207200     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja903277d     Document Type: Article

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