Cu(II)-catalyzed THM formation during water chlorination and monochloramination: A comparison study

Journal of Hazardous Materials

Volumn 170, Issue 1, 2009, Pages 58-65

  Fu, Jun ^a,b   Qu, Jiuhui ^a   Liu, Ruiping ^a   Qiang, Zhimin ^a   Liu, Huijuan ^a   Zhao, Xu ^a  

^a RESEARCH CENTER FOR ECO ENVIRONMENTAL SCIENCES   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Chlorination; Cu(II) catalysis; Humic acid; Monochloramination; Reaction mechanism; Trihalomethane

Indexed keywords

CU(II) CATALYSIS; HUMIC ACID; MONOCHLORAMINATION; REACTION MECHANISM; TRIHALOMETHANE;

CARBOXYLATION; CATALYSIS; CHEMICAL COMPOUNDS; CHLORINATION; CHLORINE; CHLORINE COMPOUNDS; CITRIC ACID; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROXYLATION; ORGANIC ACIDS; PH EFFECTS; SPIN DYNAMICS;

BIOLOGICAL MATERIALS;

CITRIC ACID; COPPER; HUMIC ACID; HYDROXYL RADICAL; MONOCHLORAMINE; TRIHALOMETHANE;

CATALYSIS; CHLORINATION; CITRIC ACID; COMPARATIVE STUDY; COMPLEXATION; COPPER; DECARBOXYLATION; ELECTRON SPIN RESONANCE; FORMATION MECHANISM; HUMIC ACID; HYDROXYL RADICAL; METHANE; OXIDATION; PH;

ARTICLE; CATALYSIS; CHLORINATION; COMPARATIVE STUDY; COMPLEX FORMATION; CONTROLLED STUDY; DECARBOXYLATION; OXIDATION; PH; WASTE COMPONENT REMOVAL; WATER CONTAMINATION; WATER TREATMENT;

AMINATION; CATALYSIS; CHEMICAL PROCESSES; COPPER; HALOGENATION; HUMIC SUBSTANCES; HYDROXYL RADICAL; TRIHALOMETHANES; WATER;

EID: 67651095790     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2009.04.133     Document Type: Article

References (28)

1. Than T.A., Ogino T., Omori M., and Okada S. Monochloramine inhibits etoposide-induced apoptosis with an increase in DNA aberration. Free Radic. Biol. Med. 30 (2001) 932-940
2. Jafvert C.T., and Valentine R.L. Reaction scheme for the chlorination of ammoniacal water. Environ. Sci. Technol. 26 (1992) 577-586
3. Jensen J.N., Johnson J.D., St. Aubin J., and Christman R.F. Effect of monochloramine on isolated fulvic acid. Org. Geochem. 8 (1985) 71-76
4. Pintar A., Bercic G., and Levec J. Catalytic liquid-phase oxidation of aqueous phenol solutions in a trickle-bed reactor. Chem. Eng. Sci. 52 (1997) 4143-4153
5. Wang Z., Liu Q., Yu J., Wu T., and Wang G. Surface structure and catalytic behavior of silica-supported copper catalysts prepared by impregnation and sol-gel methods. Appl. Catal. A: Gen. 239 (2003) 87-94
6. Amariglio A., Benali O., and Amariglio H. Oscillating oxidation of propene on copper oxides. J. Catal. 118 (2002) 164-174
7. Barnes D., Fitzgerald P.A., and Swan H.B. Catalyzed formation of chlorinated organic materials in water. Water Sci. Technol. 21 (1979) 59-63
8. Blatchley E.R., Margetas D., and Duggirala R. Copper catalysis in chloroform formation during water chlorination. Water Res. 37 (2003) 4385-4394
9. Scully F.E., and White W.N. Reactions of chlorine, monochloramine in the GI tract. Environ. Sci. Technol. 25 (1991) 820-828
10. Peters C.J., Young R.J., and Perry R. Factors influencing the formation of haloforms in the chlorination of humic materials. Environ. Sci. Technol. 14 (1980) 1391-1395
11. Yang X., and Shang C. Chlorination byproduct formation in the presence of humic acid, model nitrogenous organic compounds, ammonia, and bromide. Environ. Sci. Technol. 38 (2004) 4995-5001
12. Larson R.A., and Rockwell A.L. Chloroform and chlorophenol production by decarboxylation of natural acids during aqueous chlorination. Environ. Sci. Technol. 13 (1979) 325-329
13. Boyce S.D., and Hornig J.F. Reaction pathways of trihalomethane formation from the halogenation of dihydroxyaromatic model compounds for humic acid. Environ. Sci. Technol. 17 (1983) 202-211
14. Oliver B.G., and Shindler D.B. Trihalomethanes from the chlorination of aquatic algae. Environ. Sci. Technol. 14 (1980) 1502-1505
15. Chang E.E., Chiang P.C., Chao S.H., and Lin Y.L. Relationship between chlorine consumption and chlorination by-products formation for model compounds. Chemosphere 64 (2006) 1196-1203
16. Gallard H., von U., and Gunten. Chlorination of natural organic matter: kinetics of chlorination and of THM formation. Water Res. 36 (2002) 65-74
17. Kasim K., Levallois P., Johnson K.C., Abdous B., and Auger P. Chlorination disinfection by-products in drinking water and the risk of adult leukemia in Canada. Original contribution. Am. J. Epidemiol. 163 (2006) 116-126
18. Fu J., Qu J.H., Liu R.P., Zhao X., and Qiang Z.M. The influence of Cu(II) on the decay of monochloramine. Chemosphere 74 (2009) 181-186
19. Fu J., Qu J.H., Liu R.P., Qiang Z.M., Zhao X., and Liu H.J. Mechanism of Cu(II)-catalyzed monochloramine decomposition in aqueous solution. Sci. Total. Environ. (2009) 10.1016/j.scitotenv.2009.03.007
20. Kirmeyer G.J., Foust G.W.P., and Simmler G.L.J.J. Optimizing Chloramine Treatment (1993), Prepared for the American Water Works Association Research Foundation
21. Takahashi M., Chiba K., and Li P. Formation of hydroxyl radicals by collapsing ozone microbubbles under strongly acidic conditions. J. Phys. Chem. B 111 (2007) 11443-11446
22. Hua G., and Reckhow D.A. Comparison of disinfection byproduct formation from chlorine and alternative disinfectants. Water Res. 41 (2007) 1667-1678
23. Acero J.L., and von Gunten U. Influence of carbonate on the ozone/hydrogen peroxide based advanced oxidation process for drinking water treatment. Ozone Sci. Eng. 22 (2000) 305-328
24. Bansal V.K., Kumar R., Prasad R., Prasad S., and Niraj. Catalytic chemical and electrochemical wet oxidation of phenol using new copper(II) tetraazamacrocycle complexes under homogeneous conditions. J. Mol. Catal. A: Chem. 284 (2008) 69-76
25. 2+/humic acid/goethite at neutral to acidic pH. Environ. Sci. Technol. 39 (2005) 4886-4893
26. Alvarez-Puebla R.A., Valenzuela-Calahorro C., and Garrido J.J. Cu(II) retention on a humic substance. J. Colloid Interface Sci. 270 (2004) 47-55
27. Hernández D., Plaza C., Senesi N., and Polo A. Detection of copper(II) and zinc(II) binding to humic acids from pig slurry and amended soils by fluorescence spectroscopy. Environ. Pollut. 143 (2006) 212-220
28. Streicher R.P., Zimmer H., Bercz J.P., and Coleman W.E. The interactions of aqueous solutions of chlorine with citric acid: a source of mutagens. Anal. Lett. 19 (1986) 681-696