Bis-GMA co-polymerizations: Influence on conversion, flexural properties, fracture toughness and susceptibility to ethanol degradation of experimental composites

Dental Materials

Volumn 25, Issue 9, 2009, Pages 1136-1141

  Pfeifer, Carmem S ^a   Silva, Laura R ^a   Kawano, Yoshio ^a   Braga, Roberto R ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

Composites; Conversion; Dimethacrylates; Mechanical properties; Organic solvents

Indexed keywords

BEFORE AND AFTER; BIS-GMA; BISPHENOL A; COMPOSITES; CONVERSION; DEGREE OF CONVERSION; DIMETHACRYLATES; DISTILLED WATER; ETHANOL DEGRADATION; ETHANOL SOLUTIONS; FLEXURAL PROPERTIES; FLEXURAL STRENGTH; FT- RAMAN SPECTROSCOPY; GLYCIDYL METHACRYLATE; SINGLE-EDGE NOTCHED BEAMS; THREE-POINT BENDING TEST;

ACRYLIC MONOMERS; BENDING STRENGTH; ETHANOL; FRACTURE; GAS METAL ARC WELDING; MECHANICAL PROPERTIES; ORGANIC SOLVENTS; PHENOLS; RAMAN SPECTROSCOPY;

FRACTURE TOUGHNESS;

2,2 BIS (4 (2 METHACRYLOXYETHOXY)PHENYL)PROPANE; 2,2-BIS-(4-(2-METHACRYLOXYETHOXY)PHENYL)PROPANE; ALCOHOL; BISPHENOL A BIS(2 HYDROXYPROPYL) ETHER DIMETHACRYLATE; METHACRYLIC ACID DERIVATIVE; POLYURETHAN; POLYURETHANE DIMETHACRYLATE; RESIN;

ARTICLE; CHEMISTRY; DENTAL BONDING; DENTAL CARE; HARDNESS; MATERIALS TESTING; PHASE TRANSITION; PLIABILITY; SOLUBILITY; YOUNG MODULUS;

BISPHENOL A-GLYCIDYL METHACRYLATE; COMPOSITE RESINS; DENTAL BONDING, LIGHT-CURED; DENTAL STRESS ANALYSIS; ELASTIC MODULUS; ETHANOL; HARDNESS; MATERIALS TESTING; METHACRYLATES; PHASE TRANSITION; PLIABILITY; POLYURETHANES; SOLUBILITY;

EID: 67651093996     PISSN: 01095641     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.dental.2009.03.010     Document Type: Article

References (26)

1. Ferracane J.L. Hygroscopic and hydrolytic effects in dental polymer networks. Dent Mater 22 (2006) 211-222
2. Peutzfeldt A. Resin composites in dentistry: the monomer systems. Eur J Oral Sci 105 (1997) 97-116
3. Asmussen E., and Peutzfeldt A. Influence of UEDMA BisGMA and TEGDMA on selected mechanical properties of experimental resin composites. Dent Mater 14 (1998) 51-56
4. Sideridou I., Tserki V., and Papanastasiou G. Effect of chemical structure on degree of conversion in light-cured dimethacrylate-based dental resins. Biomaterials 23 (2002) 1819-1829
5. Lovell L.G., Stansbury J.W., Syrpes D.C., and Bowman C.N. Effects of composition and reactivity on reaction kinetics of dimethacrylate/dimethacrylate copolymerizations. Macromolecules 32 (1999) 3913-3921
6. Floyd C.J., and Dickens S.H. Network structure of Bis-GMA- and UDMA-based resin systems. Dent Mater 22 (2006) 1143-1149
7. Sideridou I., Tserki V., and Papanastasiou G. Study of water sorption, solubility and modulus of elasticity of light-cured dimethacrylate-based dental resins. Biomaterials 24 (2003) 655-665
8. Goncalves F., Pfeifer C.S., Ferracane J.L., and Braga R.R. Contraction stress determinants in dimethacrylate composites. J Dent Res 87 (2008) 367-371
9. Ogliari F.A., Ely C., Zanchi C.H., Fortes C.B., Samuel S.M., Demarco F.F., Petzhold C.L., and Piva E. Influence of chain extender length of aromatic dimethacrylates on polymer network development. Dent Mater 24 (2008) 165-171
10. Brunthaler A., König F., Lucas T., Sperr W., and Schedle A. Longevity of direct resin composite restorations in posterior teeth. Clin Oral Invest 7 (2003) 63-70
11. Scherrer S., Kelly J., Quinn G., and Xu K. Fracture toughness (KIc) of a dental porcelain determined by fractographic analysis. Dent Mater 15 (1999) 342-348
12. Bonilla E., Yashar M., and Caputo A. Fracture toughness of nine flowable resin composites. J Prosthet Dent 89 (2003) 261-267
13. Musanje L., and Ferracane J. Effects of resin formulation and nanofiller surface treatment on the properties of experimental hybrid resin composite. Biomaterials 25 (2004) 4065-4071
14. Ferracane J.L., and Condon J.R. In vitro evaluation of the marginal degradation of dental composites under simulated occlusal loading. Dent Mater 15 (1999) 262-267
15. Asmussen E., and Peutzfeldt A. Influence of pulse-delay curing on softening of polymer structures. J Dent Res 80 (2001) 1570-1573
16. Ferracane J., and Berge H.X. Fracture toughness of experimental dental composites aged in ethanol. J Dent Res 74 (1995) 1418-1423
17. Ferracane J., and Marker V. Solvent degradation and reduced fracture toughness in aged composites. J Dent Res 71 (1992) 13-19
18. Odian G. Principles of polymerization (2004), Wiley-Interscience, New York p. 55
19. Sideridou I.D., Karabela M.M., and Vouvoudi E. Volumetric dimensional changes of dental light-cured dimethacrylate resins after sorption of water or ethanol. Dent Mater 24 (2008) 1131-1136
20. Dickens S.H., Stansbury J.W., Choi K.M., and Floyd C.J. Photopolymerization kinetics of methacrylate dental resins. Macromolecules 36 (2003) 6043-6053
21. Van Krevelen D.W. Properties of polymers (1990), Elsevier Science Publishers, Amsterdam
22. Anseth K.S., Kline L.M., Walker T.A., Anderson K.J., and Bowman C.N. Reaction kinetics and volume relaxation during polymerizations of multiethylene glycol dimethacrylates. Macromolecules 28 (1995) 2491-2499
23. Stansbury J.W., and Dickens S.H. Network formation and compositional drift during photo-initiated co-polymerization of dimethacrylate monomers. Polymer 42 (2001) 6363-6369
24. Eick J., Kotha S., Chappelow C., Kilway K., Giese G., Glaros A., and Pinzino C. Properties of silorane-based dental resins and composites containing a stress-reducing monomer. Dent Mater 23 (2007) 1011-1017
25. Eick J., Smith R., Pinzino C., Kotha S., Kostoryz E., and Chappelow C. Photopolymerization of developmental monomers for dental cationically initiated matrix resins. Dent Mater 21 (2005) 384-390
26. McKinney J.E., and Wu W. Chemical softening and wear of dental composites. J Dent Res 64 (1985) 1326-1331