Acid-catalyzed oxidation of some sulfated macromolecules. Kinetics and mechanism of oxidation of kappa-carrageenan polysaccharide by permanganate ion in acid perchlorate solutions

Journal of Molecular Catalysis A: Chemical

Volumn 309, Issue 1-2, 2009, Pages 95-102

  Hassan, R M ^a   Fawzy, A ^a   Ahmed, G A ^a   Zaafarany, I A ^b   Asghar, B S ^b   Khairou, K S ^b  

^a Assiut University   (Egypt)

^b UMM AL QURA UNIVERSITY   (Saudi Arabia)

Author keywords

Carrageenans; Catalysis; Kinetics; Mechanism; Oxidation; Permanganate; Polysaccharides

Indexed keywords

ADDED SALT; AUTOACCELERATION; CARRAGEENAN; CARRAGEENANS; CATALYZED OXIDATION; EXPERIMENTAL OBSERVATION; FIRST-ORDER DEPENDENCE; FRACTIONAL-ORDER KINETICS; HYDROGEN ION CONCENTRATION; INITIAL RATE; INTERMEDIATE COMPLEX; KAPPA CARRAGEENAN; KINETIC EVIDENCE; KINETICS AND MECHANISM; KINETICS OF OXIDATION; OXIDATION RATES; PERCHLORATE SOLUTIONS; PERMANGANATE; PSEUDO-FIRST-ORDER; REACTION MECHANISM; REACTIVE SPECIES; TIME PERIODS; TWO STAGE;

ACIDS; BIOPOLYMERS; CATALYSIS; HYDROGEN; IONIC STRENGTH; IONS; MANGANESE; MANGANESE COMPOUNDS; POLYSACCHARIDES; REACTION KINETICS; SUPRAMOLECULAR CHEMISTRY;

OXIDATION;

EID: 67651091525     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2009.05.005     Document Type: Article

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