Evaluation of nanoscale zerovalent iron particles for trichloroethene degradation in clayey soils

Science of the Total Environment

Volumn 407, Issue 18, 2009, Pages 4986-4993

  Katsenovich, Yelena P ^a   Miralles Wilhelm, Fernando R ^a  

^a FLORIDA INTERNATIONAL UNIVERSITY   (United States)

Author keywords

Agglomeration; Deactivation rate constant; Dechlorination; Nanoscale zerovalent iron; Palladized bimetallic particles

Indexed keywords

AGGLOMERATED PARTICLES; BATCH STUDIES; BIMETALLIC PARTICLES; CLAY SEDIMENTS; CLAYEY SOILS; COLUMN EXPERIMENTS; COMPARATIVE STUDIES; DEACTIVATION RATE CONSTANT; DEACTIVATION REACTIONS; DEGRADATION PROCESS; DESIGN STRATEGIES; FIRST ORDER; FLOW CONDITION; HIGH REACTIVITY; INDICATOR PARAMETERS; MORPHOLOGY AND COMPOSITION; NANOSCALE ZEROVALENT IRON; OAK RIDGE RESERVATION; OXIDATION-REDUCTION POTENTIALS; PALLADIZED BIMETALLIC PARTICLES; PARTICLE AGGLOMERATIONS; PARTICLE BEHAVIOR; PH DROP; PSEUDO-FIRST-ORDER KINETIC MODELS; QUANTITATIVE ANALYSIS; REMOVAL EFFICIENCIES; SEM; SEM IMAGE; TRICHLOROETHENE;

CHEMICAL ANALYSIS; CLAY MINERALS; DECHLORINATION; DEGRADATION; EXPERIMENTS; GEOLOGIC MODELS; NANOSTRUCTURED MATERIALS; OXIDATION; POLLUTION; RATE CONSTANTS; REMOVAL; SEDIMENTOLOGY; SOIL POLLUTION CONTROL; SOILS; TRICHLOROETHYLENE;

AGGLOMERATION;

IRON; METAL NANOPARTICLE; TRICHLOROETHYLENE;

CLAY SOIL; DECHLORINATION; EXPERIMENTAL STUDY; QUANTITATIVE ANALYSIS; REMEDIATION; SCANNING ELECTRON MICROSCOPY; TRICHLOROETHYLENE;

ANALYTICAL PARAMETERS; ARTICLE; BIOREMEDIATION; CHEMICAL ANALYSIS; CHEMICAL REACTION KINETICS; CLAY; OXIDATION REDUCTION REACTION; PLUME; PREDICTION; PRIORITY JOURNAL; QUANTITATIVE ANALYSIS; RESIDUE ANALYSIS; SEDIMENT; SOIL POLLUTION; SURFACE PROPERTY; WASTE COMPONENT REMOVAL;

ALUMINUM SILICATES; IRON; MICROSCOPY, ELECTRON, SCANNING; NANOPARTICLES; SOIL; SOIL POLLUTANTS; TRICHLOROETHYLENE;

EID: 67651004287     PISSN: 00489697     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.scitotenv.2009.05.033     Document Type: Article

References (32)

1. Alonso F., Beletskaya I.P., and Yus M. Metal-mediated reductive hydrodehalogenation of organic halides. Chem Rev 102 11 (2002) 4009-4092
2. American Public Health Association (APHA). Standard Methods. 19th Ed. (1995), APHA, Washington, DC
3. Arnold W.A., and Roberts A.L. Pathway and kinetics of chlorinated ethylene and chlorinated acetylene reaction with Fe(0) particles. Environ Sci Technol 34 (2000) 1794-1805
4. Cetin H. Soil-particle and pore orientations during consolidation of cohesive soils. Eng Geol 73 (2004) 1-11
5. Cetin H., Fener M., and Gunaydin O. Geotechnical properties of tire-cohesive clayey soil mixtures as a fill mixture. Eng Geol 88 (2006) 110-120
6. 0. Chemosphere 42 (2001) 367-372
7. Fogler H.S. Elements of Chemical Reaction Engineering. 3rd Ed. (1998), Prentice Hall PTR, Upper Saddle River
8. Gavaskar A., Tatar L., and Condit W. Nanoscale zero-valent iron technologies for source remediation. Cost and performance report. Prepared for Naval Facilities Engineering Service Center under the contract number N47408-01-D-8207 (2005)
9. 2 chlorinated hydrocarbons. Environ Sci Technol 21 (1987) 202-208
10. Grittini C., Malcomson M., Fernando Q., and Korte N. Rapid dechlorination of polychlorinated biphenyls on the surface of a Pd/Fe bimetallic system. Environ Sci Technol 29 (1995) 2898-2900
11. Han F.X., Su Y., Monts D.L., Waggoner C.A., and Plodinec M.J. Binding, distribution, and plant uptake of mercury in a soil from Oak Ridge, Tennessee, USA. Sci Total Environ 368 (2006) 753-768
12. 0 nanoparticles in saturated sand columns. the proceedings of the ACS 82nd Colloids and Surface Science Symposium, NC State University, Raleigh, NC June 15-18, 2008 (2008)
13. Kohn T., Livi K.J.T., Roberts A.L., and Vikesland P.J. Longevity of granular iron in groundwater treatment processes: corrosion product development. Environ Sci Technol 39 (2005) 2867-2879
14. Lee W., and Batchelor B. Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 1. Pyrite and magnetite. Environ Sci Technol 36 (2002) 5147-5154
15. Lee W., and Batchelor B. Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 2. Green Rust. Environ Sci Technol 36 (2002) 5348-5354
16. Lien H.-L., and Zhang W.-x. Nanoscale iron particles for complete reduction of chlorinated ethenes. Colloid Surface A 191 (2001) 97-105
17. 0 content) and solution pH on nZVI reactivity: H2 evolution and TCE dechlorination. Environ Sci Technol 40 (2006) 6085-6090
18. Liu Y., Majetich S.A., Tilton R.D., Sholl D.S., and Lowry G.V. TCE dechlorination rates, pathways, and efficiency of nanoscale iron particles with different properties. Environ Sci Technol 39 (2005) 1338-1345
19. Matheson L.J., and Tratnyek P.G. Reductive dehalogenation of chlorinated methanes by iron metal. Environ Sci Technol 28 (1994) 2045-2053
20. Nurmi J.T., Tratnyek P.G., Sarathy V., Baer D.R., Amonette J.E., Pecher K., Wang C., Linehan J.C., Matson D.W., Penn R.L., and Driessen M.D. Characterization and properties of metallic iron nanoparticles: spectroscopy, electrochemistry, and kinetics. Environ Sci Technol 39 (2005) 1221-1230
21. 0. Environ Sci Technol 30 (1996) 66-71
22. Phenrat T., Saleh N., Sirk K., Tilton R.D., and Lowry G. Aggregation and sedimentation of aqueous nanoscale zerovalent iron dispersions. Environ Sci Technol 41 (2007) 284-290
23. Reddy K., and Karri M.R. Removal and degradation of pentachlorophenol in clayey soil using nanoscale iron particles. Geotechnics of Waste Management and Remediation, Geotechnical Special Publication No.177 (2008), ASCE Press, Reston, Virginia 463-469
24. Roberts A.L., Totten L.A., Arnold W.A., Burris D.R., and Campbell T.J. Reductive elimination of chlorinated ethylenes by zero-valent metals. Environ Sci Technol 30 (1996) 2654-2659
25. Staudinger J., and Roberts P.V. A critical compilation of Henry's law constant temperature dependence relations for organic compounds in dilute aqueous solutions. Chemosphere 44 (2001) 561-576
26. Su C., and Puls R.W. Kinetics of trichloroethene reduction by zerovalent iron and tin: pretreatment effect, apparent activation energy, and intermediate products. Environ Sci Technol 33 (1999) 163-168
27. US EPA. Workshop on Nanotechnology for Site Remediation, U.S. Department of Commerce Washington, DC (2005) October 20-21
28. Van Genuchten M.T., and Wierenga P.J. Solute Dispersion Coefficients and Retardation Factors. Soil Science Society of America Book Series vol. 9 (2003) 1025-1054 Part 1
29. Wang C.-B., and Zhang W.-X. Synthesizing nanoscale iron particles for rapid and complete dechlorination of TCE and PCBs. Environ Sci Technol 31 (1997) 2154-2156
30. Watson D.B., Kostka J.E., Fields M.W., and Jardine P.M. The Oak Ridge Field Research Center Conceptual Model. NABIR report (2004)
31. Zhang W.-x. Nanoscale iron particles for environmental remediation: an overview. J Nanopart Res 5 (2003) 323-332
32. Zhang W.-x., Wang C.-B., and Lien H.-L. Treatment of chlorinated organic contaminants with nanoscale bimetallic particles. Catal Today 40 (1998) 387-395