Metal-independent decomposition of hydroperoxides by halogenated quinones: Detection and identification of a quinone ketoxy radical

Proceedings of the National Academy of Sciences of the United States of America

Volumn 106, Issue 28, 2009, Pages 11466-11471

  Zhu, Ben Zhan ^a,b   Shan, Guo Qiang ^a   Huang, Chun Hua ^a   Kalyanaraman, Balaraman ^c   Mao, Li ^a   Du, Yu Guo ^a  

^a RESEARCH CENTER FOR ECO ENVIRONMENTAL SCIENCES   (China)

^b OREGON STATE UNIVERSITY   (United States)

^c MEDICAL COLLEGE OF WISCONSIN   (United States)

Author keywords

Carbon centered quinone ketoxy radical; ESR spin trapping; Keto enol tautomerization; Oxygen centered quinone enoxy radical; Spin isomerization

Indexed keywords

2,5 DICHLORO 1,4 BENZOQUINONE; 5,5 DIMETHYL 1 PYRROLINE 1 OXIDE; HYDROPEROXIDE DERIVATIVE; METAL; QUINONE DERIVATIVE; TERT BUTYL HYDROPEROXIDE; UNCLASSIFIED DRUG;

ARTICLE; DECOMPOSITION; ELECTRON SPIN RESONANCE; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; ION CYCLOTRON RESONANCE MASS SPECTROMETRY; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE;

BENZOQUINONES; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; CYCLIC N-OXIDES; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDROCARBONS, HALOGENATED; MASS SPECTROMETRY; MODELS, CHEMICAL; MOLECULAR STRUCTURE; TERT-BUTYLHYDROPEROXIDE;

EID: 67650886071     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.0900065106     Document Type: Article

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