Radical reactions with double memory of chirality (2MOC) for the enantiospecific synthesis of adjacent stereogenic quaternary centers in solution: Cleavage and bonding faster than radical rotation

Journal of the American Chemical Society

Volumn 131, Issue 24, 2009, Pages 8425-8433

  Resendiz, Marino J E ^a   Family, Farnosh ^a   Fuller, Kerrian ^a   Campos, Luis M ^a   Khan, Saeed I ^a   Lebedeva, Natalia V ^b   Forbes, Malcolm D E ^b   Garcia Garibay, Miguel A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSOLUTE CONFIGURATION; BOND FORMING; CHIRAL SHIFT; DECARBONYLATION; ENANTIOSPECIFIC; ENANTIOSPECIFIC SYNTHESIS; LC-MS/MS; MEMORY OF CHIRALITIES; QUATERNARY CENTERS; RADICAL REACTIONS; RADICAL ROTATION; SINGLE CRYSTAL X-RAY DIFFRACTION; SINGLE STATE; STEREOSPECIFIC; TIME-SCALE;

CHIRALITY; ENANTIOMERS; EUROPIUM; KETONES; REACTION KINETICS; ROTATION; STEREOCHEMISTRY;

SYNTHESIS (CHEMICAL);

KETONE DERIVATIVE;

ARTICLE; CARBONYLATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; ENANTIOMER; ENANTIOSELECTIVITY; PHOTOCHEMISTRY; RADICAL REACTION; SYNTHESIS; X RAY DIFFRACTION;

EID: 67650545672     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja900781n     Document Type: Article

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