Intensely colored mixed-valence iron(II) iron(III) formate analogue of Prussian Blue exhibits Néel N-type ferrimagnetism

Journal of the American Chemical Society

Volumn 131, Issue 22, 2009, Pages 7516-7517

  Hagen, Karl S ^a   Naik, Sunil G ^a   Boi, Hanh Huynh ^a   Masello, Antonio ^b   Christou, George ^b  

^a EMORY UNIVERSITY   (United States)

^b University of Florida ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

3D STRUCTURE; ALTERNATING LAYERS; BLACK CRYSTALS; LOW FIELD; LOW TEMPERATURES; MAGNETIC ORDERING; MIXED VALENCE; MIXED-VALENCE CLUSTERS; NEGATIVE MAGNETIZATION; OPEN FRAMEWORKS; PRUSSIAN BLUE; ROOM TEMPERATURE; THREE DIMENSIONAL (3D) STRUCTURES;

CRYSTALS; DIMETHYLFORMAMIDE; IRON COMPOUNDS; MAGNETIC MATERIALS; NEON; ORGANIC ACIDS; POSITIVE IONS;

THREE DIMENSIONAL;

FERRIC FERROCYANIDE; FERRIC ION; FERROUS ION; FERROCYANIDE; FORMIC ACID DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; MAGNETISM; ROOM TEMPERATURE; SYNTHESIS; CHEMISTRY; METHODOLOGY; MOSSBAUER SPECTROSCOPY;

FERRIC COMPOUNDS; FERROCYANIDES; FERROUS COMPOUNDS; FORMATES; MAGNETICS; MODELS, MOLECULAR; SPECTROSCOPY, MOSSBAUER;

EID: 67650538336     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja901093b     Document Type: Article

References (35)

1. (a) Buser, H. J.; Schwarzenbach, D.; Petter, W.; Ludi, A. Inorg. Chem. 1977, 16, 2704.
2. (b) Dunbar, K. R.; Heintz, R. A. Prog. Inorg. Chem. 1997, 45, 283.
3. (a) Ferlay, S.; Mallah, T.; Ouahès, R.; Veillet, P.; Verdaguer, M. Nature 1995, 378, 701.
4. (b) Entley, W. R.; Girolami, G. S. Science 1995, 268, 397.
5. (c) Holmes, S. M.; Girolami, G. S. J. Am. Chem. Soc. 1999, 121, 5593.
6. Janiak, C. Dalton Trans. 2003, 2718.
7. Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Angew. Chem., Int. Ed. 2004, 43, 1466.
8. (a) Mathonière, C.; Carling, S. G.; Yusheng, D.; Day, P. J. Chem. Soc., Chem. Commun. 1994, 1551.
9. (b) Mathonière, C.; Nuttall, C. J.; Carling, S. G.; Day, P. Inorg. Chem. 1996, 35, 1201.
10. (c) Day, P. J. Chem. Soc., Dalton Trans. 1997, 701.
11. (d) Nuttall, C. J.; Day, P. Chem. Mater. 1998, 10, 3050.
12. (e) Watts, I. D.; Carling, S. G.; Day, P. J. Chem. Soc., Dalton Trans. 2002, 1429.
13. Fishman, R. S.; Clemente-León, M.; Coronado, E. Inorg. Chem. 2009, 48, 3039.
14. (a) Wang, Z.; Zhang, B.; Otsuka, T.; Inoue, K.; Kobayashi, H.; Kurmoo, M. Dalton Trans. 2004, 2209.
15. (b) Wang, X.-Y.; Gan, L.; Zhang, S.-W.; Gao, S. Inorg. Chem. 2004, 43, 4615.
16. (c) Wang, Z.; Zhang, B.; Inoue, K.; Fujiwara, H.; Otsuka, T.; Kobayashi, H.; Kurmoo, M. Inorg. Chem. 2007, 46, 437.
17. (d) Wang, Z.; Zhang, X.; Batten, S. R.; Kurmoo, M.; Gao, S. Inorg. Chem. 2007, 46, 8439.
18. Cornia, A.; Caneschi, A.; Dapporto, P.; Fabretti, A. C.; Gatteschi, D.; Malavasi, W.; Sangregorio, C.; Sessoli, R. Angew. Chem., Int. Ed. 1999, 38, 1780.
19. Tian, Y.-Q.; Zhao, Y.-M.; Xu, H.-J.; Chi, C.-Y. Inorg. Chem. 2007, 46, 1612.
20. 2 = 0.077.
21. (a) Chrétien, A.; Lous, P. Bull. Soc. Chim. Fr. 1944, 11, 446.
22. (b) Johnson, M. K.; Cannon, R. D.; Powell, D. B. Spectrochim. Acta 1982, 38A, 307.
23. 2 = 0.084.
24. (a) Viertelhaus, M.; Adler, P.; Clérac, R.; Anson, C. E.; Powell, A. K. Eur. J. Inorg. Chem. 2005, 692.
25. (b) Fu, Y.-L.; Ji, M.; Shen, X.-L.; Ng, S. W. Acta Crystallogr. 2005, E61, m688.
26. (a) Wills, A. S. VaList; program available from www.ccp14.ac.uk.
27. (b) Brown, I. D.; Altermatt, D. Acta Crystallogr. 1985, B41, 244.
28. (c) Brese, N. E.; O'Keeffe, M. Acta Crystallogr. 1991, B47, 192.
29. (d) Brown, I. D.; Gillespie, R. J.; Morgan, K. R.; Tun, Z.; Ummat, P. K. Inorg. Chem. 1984, 23, 4506.
30. (e) Graphics and volumes: Palmer, D. CrystalMaker, version 8; www.crystalmaker.com.
31. Sato, T.; Ambe, F.; Endo, K.; Katada, M.; Maeda, H.; Nakamoto, T.; Sano, H. J. Am. Chem. Soc. 1996, 118, 3450.
32. Detailed analysis of the magnetic data is in progress.
33. (a) Lee, D.; Krebs, C.; Huynh, B. H.; Hendrich, M. P.; Lippard, S. J. J. Am. Chem. Soc. 2000, 122, 5000.
34. (b) Lee, D.; DuBois, J. L.; Pierce, B.; Hedman, B.; Hodgson, K. O.; Hendrich, M. P.; Lippard, S. J. Inorg. Chem. 2002, 41, 3172.
35. Robin, M.-B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247.