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ESI-MS is often used for the structure analysis for self-assembled molecules. See: a
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67650465327
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See the Supporting Information
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See the Supporting Information.
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90
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67650444074
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1H NMR spectrum of 19.
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1H NMR spectrum of 19.
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91
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0000483730
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The lability of Pd-N bonds has been exploited in the synthesis of complex structures such as catenanes. See M. Fujita, F. Ibukuro, K. Yamaguchi, K. Ogura, J. Am. Chem. Soc. 1995, 117, 4175
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The lability of Pd-N bonds has been exploited in the synthesis of complex structures such as catenanes. See M. Fujita, F. Ibukuro, K. Yamaguchi, K. Ogura, J. Am. Chem. Soc. 1995, 117, 4175.
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The synthesis of macrocycles by metal-coordination bonds through the directional-bonding approach has two major requirements at its most basic level. The first calls for precursors with predefined angles and symmetry for the desired product form. The second dictates that the precursors should be mixed in the ratios appropriate for the chosen outcome. What is more usual is that when reacting precursors with predefined angles and symmetry, mixtures of macrocycles of different sizes will be formed in different ratios. Then, a careful tuning of the reaction conditions (order of precursor addition, choice of solvent system, concentration, temperature, and often even the rate of mixing of the two building blocks) is required to optimize the yields in the desired self-assembly process
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The synthesis of macrocycles by metal-coordination bonds through the directional-bonding approach has two major requirements at its most basic level. The first calls for precursors with predefined angles and symmetry for the desired product form. The second dictates that the precursors should be mixed in the ratios appropriate for the chosen outcome. What is more usual is that when reacting precursors with predefined angles and symmetry, mixtures of macrocycles of different sizes will be formed in different ratios. Then, a careful tuning of the reaction conditions (order of precursor addition, choice of solvent system, concentration, temperature, and often even the rate of mixing of the two building blocks) is required to optimize the yields in the desired self-assembly process.
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