Spontaneous resolution of racemic camphorates in the formation of three-dimensional metal - organic frameworks

Inorganic Chemistry

Volumn 48, Issue 14, 2009, Pages 6356-6358

  Chen, Shumei ^a   Zhang, Jian ^a   Bu, Xianhui ^a  

^a CALIFORNIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CAMPHOR; COORDINATION COMPOUND; DRUG DERIVATIVE; LIGAND;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; ANALOGS AND DERIVATIVES;

CAMPHOR; COORDINATION COMPLEXES; LIGANDS; MODELS, MOLECULAR; STEREOISOMERISM;

EID: 67650456769     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic900918z     Document Type: Article

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25. 3 (0.0583 g), DLcamphoric acid (0.1037 g), and triethanolamine (1.9582 g) were mixed in a 23-mL Teflon cup, and the mixture was stirred for 20 min. The vessel was then sealed and heated at 140 °C for 5 days. The autoclave was subsequently allowed to cool to room temperature. Transparent colorless crystals were obtained. The homochiral form Zn(△-Zn(Htea))(D-cam) (1D△) or 1L△ can be obtained by using a similar reaction except D-camphoric acid (or L-camphoric acid) instead of DL-camphoric acid was used.
26. 2.