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Volumn 48, Issue 14, 2009, Pages 6604-6614

Novel bispidine ligands and their first-row transition metal complexes: trigonal bipyramidal and trigonal prismatic geometries

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Indexed keywords


EID: 67650451210     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic900571v     Document Type: Article
Times cited : (28)

References (81)
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    • Börzel, H.; Comba, P.; Hage, R.; Kerscher, M.; Lienke, A.; Merz, M. Ligand and complex for catalytically bleaching a substrate. Patent WO 0248301 Al, June 20, 2002; U.S. Patent 2002/014900, October 17, 2002.
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    • This heterocyclic, amine-substituted building block has been described before.18-20
    • This heterocyclic, amine-substituted building block has been described before.18-20
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    • Note that the large asymmetry with respect to these two angles in some of the complexes is due to a distortion towards square pyramidal. This depends on the size of the metal ion and, to some extent, also on the electronic properties of the metal center, and is reasonably well reproduced by the computational data see Supporting Information
    • Note that the large asymmetry with respect to these two angles in some of the complexes is due to a distortion towards square pyramidal. This depends on the size of the metal ion and, to some extent, also on the electronic properties of the metal center, and is reasonably well reproduced by the computational data (see Supporting Information).
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    • This is supported by the observed stability constants, which do not follow the typical Irving-Williams series behavior29,30 see section on solution properties, i.e, there is no size-match selectivity.24
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    • The Cu-Nl and Cu-N4 distances were constrained (stepwise elongation by 0.05 ̊), and the rest of the structure was fully optimized at each step).
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    • 2+ structures might also be accessible.
    • 2+ structures might also be accessible.
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