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Here we have in mind the geometry where two Ti atoms are connected via three bridging F atoms and coordination of each Ti is completed by three terminal F atoms. In that way, the CN of each Ti in the [Ti2F 9, anion is equal to 6. Another possibility is the case where two Ti atoms are connected via one bridging F atom and coordination of each Ti is completed by four terminal F atoms. In that way, CN of each Ti is equal to 5. CN=5 is clearly energetically less favorable than CN, 6
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- anion is equal to 6. Another possibility is the case where two Ti atoms are connected via one bridging F atom and coordination of each Ti is completed by four terminal F atoms. In that way, CN of each Ti is equal to 5. CN=5 is clearly energetically less favorable than CN = 6.
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