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Volumn 28, Issue 13, 2009, Pages 3686-3690

2,6-bis(imidazol-2-ylidene)pyridine complexes of lanthanoïdes: A theoretical study of the bonding situation and selective complexation

Author keywords

[No Author keywords available]

Indexed keywords

BACK-BONDING; BONDING SITUATION; CARBENE; DFT LEVELS; IMIDAZOL; LANTHANIDE; N-HETEROCYCLIC CARBENE; PYRIDINE LIGANDS; PYRIDYL; THEORETICAL STUDY;

EID: 67650337068     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9000988     Document Type: Article
Times cited : (26)

References (61)
  • 6
    • 34250797354 scopus 로고    scopus 로고
    • Kantchev, E. A. B.; O'Brien, C. J.; Organ, M. G. Angew. Chem., Int. Ed. 2007, 46, 27682813.
    • (f) Kantchev, E. A. B.; O'Brien, C. J.; Organ, M. G. Angew. Chem., Int. Ed. 2007, 46, 27682813.
  • 29
    • 54849413968 scopus 로고    scopus 로고
    • and references therein
    • Kolarik, Z. Chem. Rev. 2008, 108, 4208-4252, and references therein.
    • (2008) Chem. Rev , vol.108 , pp. 4208-4252
    • Kolarik, Z.1
  • 32
    • 33846869728 scopus 로고    scopus 로고
    • and references therein. For pincer complexes of transition metals derived from polydentate NHC-based ligands, see: a
    • For pincer complexes of transition metals derived from polydentate NHC-based ligands, see: (a) Pugh, D.; Danopoulos, A. A. Coord. Chem. Rev. 2007, 251, 610-641, and references therein.
    • (2007) Coord. Chem. Rev , vol.251 , pp. 610-641
    • Pugh, D.1    Danopoulos, A.A.2
  • 34
    • 0037419890 scopus 로고    scopus 로고
    • This peculiar situation has been evidenced for a few NHC adducts of high-valent metal chlorides: (a) Abemethy, C. D, Codd, G. M, Spicer, M. D, Taylor, M. K. J. Am. Chem. Soc. 2003, 125, 11281129
    • This peculiar situation has been evidenced for a few NHC adducts of high-valent metal chlorides: (a) Abemethy, C. D.; Codd, G. M.; Spicer, M. D.; Taylor, M. K. J. Am. Chem. Soc. 2003, 125, 11281129.
  • 38
    • 0346993140 scopus 로고    scopus 로고
    • oarbene interactions were also predicted to be quite accessible in energy for rhodium(I) complexes of phosphino-carbenes: Miqueu, K.; Despagnet-Ayoub, E.; Dyer, P. W.; Bourissou, D.; Bertrand, G. Chem.-Eur. J. 2003, 9, 5858-5864.
    • oarbene interactions were also predicted to be quite accessible in energy for rhodium(I) complexes of phosphino-carbenes: Miqueu, K.; Despagnet-Ayoub, E.; Dyer, P. W.; Bourissou, D.; Bertrand, G. Chem.-Eur. J. 2003, 9, 5858-5864.
  • 47
    • 67650342319 scopus 로고    scopus 로고
    • Frisch, M. J, Trucks, G. W, Schlegel, H. B, Scuseria, G. E, Robb, M. A, Cheeseman, J. R, Zakrzewski, V. G, Montgomery, J. A, Stratman, R. E, Burant, J. C, Dapprich, S, Millam, J. M, Daniels, A. D, Kudin, K. N, Strain, M. C, Farkas, O, Tomasi, J, Barone, V, Cossi, M, Cammi, R, Mennucci, B, Pomelli, C, Adamo, C, Clifford, S, Ochterski, J, Petersson, G. A, Ayala, P. Y, Cui, Q, Morokuma, K, Malick, D. K, Rabuck, A. D, Raghavachari, K, Foresman, J. B, Cioslowswi, J, Ortiz, J. V, Baboul, A. G, Stefanov, B. B, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Gomperts, R, Martin, R, Fox, D. J, Keith, T, Al-Laham, M. A, Peng, C. Y, Nanayakkara, A, Gonzalez, C, Challacombe, M, Gill, P. M. W, Jonhson, B, Chen, W, Wong, M. W, Andres, J. L, Head-Gordon, M, Replogle, E. S, Pople, J. A. Gaussian 98, Revision A.11; Gaussian, Inc, Pittsburgh, PA, 1998
    • Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Montgomery, J. A.; Stratman, R. E.; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Cioslowswi, J.; Ortiz, J. V.; Baboul, A. G.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P. M. W.; Jonhson, B.; Chen, W.; Wong, M. W.; Andres, J. L.; Head-Gordon, M.; Replogle, E. S.; Pople, J. A. Gaussian 98, Revision A.11; Gaussian, Inc.: Pittsburgh, PA, 1998.
  • 49
    • 33845272028 scopus 로고    scopus 로고
    • The optimized structure of the naked MCl3 fragment is trigonal with a pyramidalization at the metal center varying in the series from 0° to 20°
    • 3 fragment is trigonal with a pyramidalization at the metal center varying in the series from 0° to 20°: Perrin, L.; Maron, L.; Eisenstein, O. Faraday Discuss. 2003, 124, 27.
    • (2003) Faraday Discuss , vol.124 , pp. 27
    • Perrin, L.1    Maron, L.2    Eisenstein, O.3
  • 51
    • 33646350253 scopus 로고    scopus 로고
    • 3 - ncomplexes: Mungur, S. A.; Blake, A. J.; Wilson, C.; McMaster, J.; Arnold, P. L. Organometallics 2006, 25, 1861-1867.
    • 3 - ncomplexes: Mungur, S. A.; Blake, A. J.; Wilson, C.; McMaster, J.; Arnold, P. L. Organometallics 2006, 25, 1861-1867.
  • 52
    • 67650338989 scopus 로고    scopus 로고
    • In the context of the lanthanide/actinide selective complexation, the modulation of the electronic properties of NHC has so far only been investigated computationally by adjusting the nuclear charge of the heterocyclic N atoms.10
    • 10


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