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(f) Xiao, K.; Liu, Y. Q.; Qi, T.; Zhang, W.; Wang, F.; Gao, J. H.; Qiu, W. F.; Ma, Y. Q.; Cui, G. L.; Chen, S. Y.; Zhan, X. W.; Yu, G.; Qin, J. G.; Hu, W. P.; Zhu, D. B. J. Am. Chem. Soc. 2005, 127, 13281-13286.
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67650304609
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Perhaps even more surprisingly, furano[3,2-fe]furan is unknown
-
Perhaps even more surprisingly, furano[3,2-fe]furan is unknown.
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35
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This method utilizes thiophene-3-thiol, which is not commercially available
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67650329291
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Although l,2-bis(2,2-diethoxyethyl)disulfide is commercially available, we have adapted a literature procedure to generate the disulfide Supporting Information, Parham, W. E, Wynberg, H. Org. Syn. 1955, 35, 51-52
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Although l,2-bis(2,2-diethoxyethyl)disulfide is commercially available, we have adapted a literature procedure to generate the disulfide (Supporting Information): Parham, W. E.; Wynberg, H. Org. Syn. 1955, 35, 51-52.
-
-
-
-
44
-
-
67650307734
-
-
The general method used to generate 2 can also be used to make other derivatives and we demonstrate this utility with the production of 3-bromothieno[3,2-fe]thiophene in fewer steps and higher yield than the best literature procedure (Supporting Information).
-
The general method used to generate 2 can also be used to make other derivatives and we demonstrate this utility with the production of 3-bromothieno[3,2-fe]thiophene in fewer steps and higher yield than the best literature procedure (Supporting Information).
-
-
-
-
45
-
-
13644256855
-
-
Slight modifications to the conditions used to obtain 4 were empolyed to generate an isomer, thieno[2,3-b]furan, which has not been previously reported (Supporting Information). Thieno[2,3-b]furan is an analog of cross conjugated thieno[2,3-fe]thiophene, which has been utilized in band gap controlled conjugated copolymers that display among the highest charge carrier mobilities to date for polymer organic thin film transistors: Heeney, M.; Bailey, C.; Genevicius, K.; Shkunov, M.; Sparrowe, D.; Tierney, S.; McCulloch, I. J. Am. Chem. Soc. 2005, 127, 1078-1079.
-
Slight modifications to the conditions used to obtain 4 were empolyed to generate an isomer, thieno[2,3-b]furan, which has not been previously reported (Supporting Information). Thieno[2,3-b]furan is an analog of cross conjugated thieno[2,3-fe]thiophene, which has been utilized in band gap controlled conjugated copolymers that display among the highest charge carrier mobilities to date for polymer organic thin film transistors: Heeney, M.; Bailey, C.; Genevicius, K.; Shkunov, M.; Sparrowe, D.; Tierney, S.; McCulloch, I. J. Am. Chem. Soc. 2005, 127, 1078-1079.
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