New stereoselective synthesis of paeonilactone B

Synthesis

Volumn , Issue 8, 2009, Pages 1287-1290

  Gatti, Francesco G ^a   Serra, Stefano ^b  

^a Dipartimento di Chimica   (Italy)

^b CNR   (Italy)

Author keywords

Homoallylic epoxidation; Lactone; Metalation; Natural product; Terpene

Indexed keywords

HOMOALLYLIC EPOXIDATION; LACTONE; METALATION; NATURAL PRODUCT; TERPENE;

OLEFINS; STEREOCHEMISTRY;

STEREOSELECTIVITY;

(1,2,4,5) 2 [ 1 [(TERT BUTYLDIPHENYLSILOXY)METHYL]VINYL] 4,5 EPOXY 5 METHYLCYCLOHEXAN 1 OL; (1,3,4,6) 6 ACETOXY 4 [ 1 (HYDROXYMETHYL)VINYL] 1 METHYLCYCLOHEXAN 1,3 DIOL; (1,3,4,6) 6 ACETOXY 4 [ 1 [(TERT BUTYLDIPHENYLSILOXY)METHYL]VINYL] 1 METHYLCYCLOHEXAN 1,3 DIOL; (1,6) 6 [ 1 (HYDROXYMETHYL)VINYL] 3 METHYLCYCLOHEX 3 EN 1 OL; (1,6) 6 [ 1 [(TERT BUTYLDIPHENYLSILOXY)METHYL]VINYL] 3 METHYLCYCLOHEX 3 EN 1 OL; (3A,5,6,7A) 5 ACETOXY 6 HYDROXY 6 METHYL 3 METHYLENE HEXAHYDROBENZOFURAN 2 (3H) ONE; (3A,5,6,7A) 5,6 DIHYDROXY 6 METHYL 3 METHYLENE HEXAHYDROBENZOFURAN 2 (3H) ONE; BENZOFURAN DERIVATIVE; CYCLOHEXANE DERIVATIVE; LACTONE DERIVATIVE; PAEONILACTONE B; TERPINEOL; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; DIASTEREOISOMER; DRUG SYNTHESIS; ENANTIOMER; EPOXIDATION; METALLATION; RING OPENING; STEREOCHEMISTRY; STOICHIOMETRY; SYNTHESIS;

EID: 67650090480     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0028-1088039     Document Type: Article

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