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Volumn , Issue 27, 2009, Pages 4046-4048

Gold-catalyzed oxidative cleavage of aryl-substituted alkynyl ethers using molecular oxygen. Simultaneous degradation of C-H and single and triple carbon-carbon bonds under ambient conditions

Author keywords

[No Author keywords available]

Indexed keywords

3 ARYL 3 ALKOXYL 1 ALKYNE DERIVATIVE; ALKYL ARYLOATE DERIVATIVE; ALKYNE DERIVATIVE; ALKYNYL ETHER DERIVATIVE; CARBON; ETHER DERIVATIVE; GOLD; OXYGEN; UNCLASSIFIED DRUG;

EID: 67649871115     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b908338c     Document Type: Article
Times cited : (38)

References (27)
  • 1
    • 0003464704 scopus 로고    scopus 로고
    • Activation of Unreactive Bonds and Organic Synthesis, in
    • S. Murai, Springer, Berlin
    • Activation of Unreactive Bonds and Organic Synthesis, in Topics in Organometallic Chemistry, ed., S. Murai, Springer, Berlin, 1999, vol. 3
    • (1999) Topics in Organometallic Chemistry, Ed.
  • 6
    • 58149458880 scopus 로고    scopus 로고
    • For metal-catalyzed cleavage of a CC bond excluding enyne cycloisomerizations and metathesis reactions, see:
    • S. I. Lee N. Chatani Chem. Commun. 2009 371
    • (2009) Chem. Commun. , pp. 371
    • Lee, S.I.1    Chatani, N.2
  • 18
    • 0027195568 scopus 로고
    • 6 (26 h; 2a, 68%; 3a, 9%), 4 mol% AuCl/AgOTf (26 h, 2a, 73%; 3a, 15%). See the ESI, Table S1 for catalysts screenings For formation mechanism of enone 3a, see selected examples:
    • C. Bolm G. Schlingloff K. Weikhardt Tetrahedron Lett. 1993 34 3405
    • (1993) Tetrahedron Lett. , vol.34 , pp. 3405
    • Bolm, C.1    Schlingloff, G.2    Weikhardt, K.3
  • 27
    • 0010890215 scopus 로고
    • This air-oxidative cleavage is inapplicable to tertiary alkynyl ethers which gave enones through a Meyer-Schuster rearrangement. 5
    • D. H. Gibson K. Owens T.-S. Ong J. Am. Chem. Soc. 1984 106 1125
    • (1984) J. Am. Chem. Soc. , vol.106 , pp. 1125
    • Gibson, D.H.1    Owens, K.2    Ong, T.-S.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.