Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(11)-Carboxylate complex

Inorganic Chemistry

Volumn 48, Issue 13, 2009, Pages 5623-5625

  Motreff, Artur ^a   Da Costa, Rosenildo Correa ^a   Allouchi, Hassan ^d   Duttine, Mathieu ^b   Mathoniere, Corine ^b   Duboc, Carole ^c   Vincent, Jean Marc ^a  

^a INSTITUT DES SCIENCES MOLÉCULAIRES   (France)

^b INST CHIM MATIERE COND BORDEAUX   (France)

^c UNIVERSITÉ JOSEPH FOURIER   (France)

^d UNIVERSITÉ DE TOURS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 67649834427     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9005218     Document Type: Article

References (36)

1. (a) Kahn, O.; Larionova, J.piakhmi, J. V. Chem.-Eur. J. 1999, 5, 3443.
2. (b) Maspoch, D.; Ruiz-Molina, D.; Vcciana J. Mater. Chem. 2004, 14, 2713.
3. (c) Kepert, C. J. Chem. Commun. 2006, 695.
4. (d) Ferey, G. Nat. Mater. 2003, 2, 136.
5. Selected examples: (a) Nakatani, K.; Carriat, J.-Y.; Journaux, Y.; Kahn, O.; Lloret, F.; Renard, J. P.; Pei, Y.; Sletten, J.; Verdaguer, M. J. Am. Chem-Soc. 1989, 111, 5739.
6. (b) Larionova, J.; Chavan, S. A.; Yakhmi, J. V.; Gulbrandsen Frystein, A.; Sletten, J.; Sourisseau, C., Kahn. O. Inorg. Chem. 1997, 36, 6374.
7. (c) Yanai, N.; Kaneko, W.; Yoneda, K.; Ohba, M.; Kitagawa, S. J. Am. Chem. Soc. 2007, 129, 3496.
8. (d) Maspoch, D.; Ruiz-Molina, D.; Wurst, K.; Domingo, N.; Cavallini, M.; Biscarini, F.; Tejada, J.; Rovira, C.; Veciana, J. Ngt. Mater. 2003, 2, 190.
9. (e) Guillou, N.; Livage, C.; van Beek, W.; Noguès, M.; Férey, G. Angew. Chem., Int. Ed. 2003, 42, 644.
10. (f) Ohkoshi, S.-I.; Arai, K.-I.; Sato, Y.; Hashimoto, K. Nat. Mater. 2004, 3, 857.
11. (g) Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M. Adv. Mater. 2007, 19, 1494.
12. (h) Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M J. Am. Chem. Soc. 2007, 129, 15738.
13. (i) Kurmoo, M.; Kumagai, H.; Chapman, K. W.; Kepert, C. J. Chem. Commun. 2005, 3012.
14. (j) Ghosh, S. K.; Kaneko, W.; Kiriya, D.; Ohba, M.; Kitagawa, S. Angew. Chem., Int. Ed. 2008, 47. 8843.
15. (k) Wang, Z.; Zhang, B.; Fujiwara, H.; Kobayashi, H.; Kurmoo, M. Chem. Commun. 2004, 416.
16. (l) Sato, Y.; Ohkoshi, S.-I.; Arai, K.-l.; Tozawa, M.; Hashimoto, K. J. Am. Chem. Soc. 2003, 125, 14590.
17. (m) Niel, V.; Thompson, A. L.; Munoz, M. C., Galet, A.; Goeta, A. E.; Real, J. A. Angew. Chem., Int. Ed. 2003, 42, 3760.
18. See the Supporting Information for full details. Because of the high sensitivity of 1 towards humidity, crystals or powdered crystals of 1 should be stored under an inert atmosphere (glovebox. or sealed tube).
19. 1 = 0.073.
20. See, for example: (a) de Wolf, E.; Speck, A. L.; Kuipers, B. W. M.; Philipse, A. P.; Meeldjik, J. D.; Bomans, P. H. H.; Frederik, P. M.; Deelman, B.-J.; van Koten, G. Tetrahedron 2002, 58, 3911.
21. (b) Guillcvic, M. A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1612.
22. See, for example: (a) Stephens, J. C.; Khan, M. A.; Houser, R. P. Ingrg. Chem. 2001, 40, 5064.
23. (b) Lah, N.; Giester, G.; Lah, J.; Šegedin, P.; Leban, I. New J. Chem. 2001, 25, 753.
24. (c) Huang, H.; Yu, S.-H.; Liu, H.-B.; Shi, M. Polyhedron 2004, 23, 55.
25. O'Connor, C. J. Prog. Inorg. Chem. 1982, 29, 203.
26. Melnik, M. Coord. Chem. Rev. 1982, 42, 259.
27. (a) Valko, M.; Mazur, M.; Morris, H.; Klcmcnt, R.; Williams, C. J.; Melnik, M. J. Coord. Chem. 2000, 52, 129.
28. (b) Voissat, B.; Greenaway, F, T.; Morgant, G.; Daran, J.-C.; Dung, N.-H.; Sorenson, J. R, J. Inorg. Biochem. 2005, 99, 355.
29. (c) Contel, M.; Villucndas, P. R.; Fernández-Gallardo, J.; Alonso, P. J.; Vincent, J.-M.; Fish, R. H. Inorg. Chem. 2005, 44, 9771.
30. (d) Ozarowski, A. Inorg. Chem. 2008, 47, 9760.
31. The parameters have been confirmed by simulation of the Q-band EPR spectra recorded at room temperature (Supporting Information).
32. Single-crystal X-ray diffraction analysis performed on crystals of 1 exposed to the air for several days revealed that the hydrated crystals of 1 become amorphous. The X-ray powder pattern of hydrated 1 is given in the Supporting Information (Figure S7).
33. Tackett, J. E. Appl. Spectrosc. 1989, 43, 483.
34. Chavez, F. A.; Que, L. Jr.; Tolman, W. B. Chem. Commun. 2001, 111.
35. Psomas, G.; Raptopoulou, C. P.; lordanidis, L.; Dendrinou-Samara, C: Tangoulis, V.; Kessissoglou, D. P. Inorg. Chem. 2000, 39, 3042.
36. Libri, S.; Mahler, M.; M Unguez; Espallargas, G.; Singh, D. C. N. G.; Soleimannejad, J.; Adams, H.; Burgard, M. D.; Rath, N. P.; Brunelli, M.; Brammer, L. Angew. Chem., Int. Ed. 2008, 47, 1693.