The Pd-catalyzed hydrodechlorination of chlorophenols in aqueous solutions under mild conditions: A promising approach to practical use in wastewater

Journal of Hazardous Materials

Volumn 169, Issue 1-3, 2009, Pages 1029-1033

  Xia, Chuanhai ^a   Liu, Ying ^a   Zhou, Shiwei ^a   Yang, Cuiyun ^a   Liu, Sujing ^a   Xu, Jie ^b   Yu, Junbao ^a   Chen, Jiping ^b   Liang, Xinmiao ^b  

^a YANTAI INSTITUTE OF COASTAL ZONE RESEARCH   (China)

^b DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

Author keywords

Aqueous solutions; Catalytic hydrodechlorination; Chlorophenols; Pd C; Solvent effect

Indexed keywords

AQUEOUS SOLUTIONS; CATALYTIC HYDRODECHLORINATION; CHLOROPHENOLS; PD/C; SOLVENT EFFECT;

ATMOSPHERIC PRESSURE; CHLORINE; DECHLORINATION; DIMETHYL SULFOXIDE; ETHERS; HYDROGENATION; ORGANIC SOLVENTS; PALLADIUM; PHENOLS; REACTION RATES; WASTEWATER;

SOLUTIONS;

CHLORINE; CHLOROPHENOL; CYCLOHEXANOL; CYCLOHEXANONE; DIMETHYL SULFOXIDE; DIOXANE; N,N DIMETHYLFORMAMIDE; PALLADIUM; SOLVENT; TETRAHYDROFURAN; WATER;

AQUEOUS SOLUTION; CATALYSIS; DECHLORINATION; PHENOLIC COMPOUND; REACTION RATE; SOLVENT; WASTE TREATMENT; WASTEWATER;

AQUEOUS SOLUTION; ARTICLE; ATMOSPHERIC PRESSURE; CONTROLLED STUDY; DECHLORINATION; DEHALOGENATION; GAS CHROMATOGRAPHY; HYDROGENATION; MASS SPECTROMETRY; TEMPERATURE; WASTE WATER MANAGEMENT;

CATALYSIS; CHEMICAL PROCESSES; CHLORINE; CHLOROPHENOLS; CYCLOHEXANOLS; CYCLOHEXANONES; HYDROGENATION; PALLADIUM; PHENOL; SOLUTIONS; WASTE DISPOSAL, FLUID;

EID: 67649771461     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2009.04.043     Document Type: Article

References (33)

1. Gupta S.S., Stadler M., Noser C.A., Ghosh A., Steinho B., Lenoir D., Horwitz C.P., Schramm K.W., and Collins T.J. Rapid total destruction of chlorophenols by activated hydrogen peroxide. Science 296 (2002) 326-328
2. Proposition 65, Office of Environmental Health Hazard, EPA, State of California, USA, 2005.
3. 2-catalyzed destruction of trichlorophenol using molecular oxygen. Angew. Chem. Int. Ed. 44 (2005) 5520-5523
4. 2 catalysts. Appl. Catal. B 77 (2008) 255-263
5. 2 on H-type activated carbons. Appl. Catal. B 73 (2007) 227-235
6. Murena F., and Gioia F. Catalytic hydrotreating of 2,4′-DDT and 4,4′-DDT. J. Hazard. Mater. B112 (2004) 151-154
7. Keane M.A., Pina G., and Tavoularis G. The catalytic hydrodechlorination of mono-, di- and trichlorobenzenes over supported nickel. Appl. Catal. B 48 (2004) 275-286
8. 2. Appl. Catal. B 76 (2007) 34-41
9. Munakata N., and Reinhard M. Palladium-catalyzed aqueous hydrodehalogenation in column reactors: Modeling of deactivation kinetics with sulfide and comparison of regenerants. Appl. Catal. B 75 (2007) 1-10
10. Ordonez S., Sastre H., and Diez F.V. Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts. Appl. Catal. B 25 (2000) 49-58
11. Zinovyev S., Shelepchikov A., and Tundo P. Design of new systems for transfer hydrogenolysis of polychlorinated aromatics with 2-propanol using a Raney nickel catalyst. Appl. Catal. B 72 (2007) 289-298
12. Ukisu Y., and Miyadera T. Complete dechlorination of DDT and its metabolites in an alcohol mixture using NaOH and Pd-C catalyst. J. Hazard. Mater. 152 (2008) 287-292
13. Calvo L., Gilarranz M.A., Casas J.A., Mohedano A.F., and RodrIguez J.J. Hydrodechlorination of 4-chlorophenol in water with formic acid using a Pd-activated carbon catalyst. J. Hazard. Mater. 161 (2009) 842-847
14. Calvo L., Gilarranz M.A., Casas J.A., Mohedano A.F., and Rodriguez J.J. Hydrodechlorination of alachlor in water using Pd, Ni and Cu catalysts supported on activated carbon. Appl. Catal. B 78 (2008) 259-266
15. Zinovyev S., and Tundo P. On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst. Appl. Catal. B 75 (2007) 124-128
16. Ukisu Y. Highly enhanced hydrogen-transfer hydrodechlorination and hydrogenation reactions in alkaline 2-propanol/methanol over supported palladium catalysts. Appl. Catal. A 349 (2008) 229-232
17. 3: a consideration of HC1/catalyst interactions and solution pH effects. Appl. Catal. B 52 (2004) 301-314
18. Felis V., De Bellefon C., Fouilloux P., and Schweich D. Hydrodechlorination and hydrodearomatisation of monoaromatic chlorophenols into cyclohexanol on Ru/C catalysts applied to water depollution: influence of the basic solvent and kinetics of the reactions. Appl. Catal. B 20 (1999) 91-100
19. Aramendia M.A., Burch R., Garcia I.M., Marinas A., Marinas J.M., Southward B.W.L., and Urbano F.J. The effect of the addition of sodium compounds in the liquid-phase hydrodechlorination of chlorobenzene over palladium catalysts. Appl. Catal. B 31 (2001) 163-171
20. Ukisu Y., Kameoka S., and Miyadera T. Catalytic dechlorination of aromatic chlorides with noble-metal catalysts under mild conditions: approach to practical use. Appl. Catal. B 27 (2000) 97-104
21. Xia C.H., Xu J., Wu W.Z., Luo Q., Chen J.P., Zhang Q., and Liang X.M. Catalytic hydrodechlorination of 2,4,4′-trichloro-2′-hydroxydiphenylether under mild conditions. Appl. Catal. B 45 (2003) 281-292
22. Xia C.H., Xu J., Wu W.Z., and Liang X.M. Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure. Catal. Commun. 5 (2004) 383-386
23. Xia C.H., Liu Y., Xu J., Yu J.B., Qin W., and Liang X.M. Catalytic hydrodechlorination reactivity of monochlorophenols in aqueous solutions over palladium/carbon catalyst. Catal. Commun. 10 (2009) 456-458
24. Yang Z.J., Xia C.H., Zhang Q., Chen J.P., Wu W.Z., and Liang X.M. Catalytic detoxification of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in fly ash. Waste Manage. 27 (2007) 588-592
25. Yang Z.J., Xia C.H., Zhang Q., Chen J.P., Wu W.Z., Liang X.M., and Kettrup A. Treatment of PCDD/Fs and PCBs in fly ash extracts under mild conditions. Fresenius Environ. Bull. 15 (2006) 86-94
26. Zhang F., Chen J.P., Zhang H., Ni Y.W., and Liang X.M. The study on the dechlorination of OCDD with Pd/C catalyst in ethanol-water solution under mild conditions. Chemosphere 68 (2007) 1716-1722
27. Pinho S.P., and Macedo E.A. Solubility of NaCl, NaBr, and KCI in water, methanol, ethanol, and their mixed solvents. J. Chem. Eng. Data 50 (2005) 29-32
28. Cerveny L., and Ruzicka V. Competitive catalytic hydrogenation in the liquid phase on solid catalysis. Catal. Rev. Sci. Eng. 24 (1982) 503-566
29. Anwer M.K., Sherman D.B., Roney J.G., and Spatola A.F. Applications of ammonium formate catalytic transfer hydrogenation: 6. Analysis of catalysis of catalyst, donor quantity, and solvent effects upon the efficacy of dechlorination. J. Org. Chem. 54 (1989) 1284-1289
30. Lassova L., Lee H.K., and Hor T.S.A. Catalytic dechlorination of chlorobenzenes: effect of solvent on efficiency and selectivity. J. Mol. Catal. A 144 (1999) 397-403
31. Maxted E.B. The poisoning of metallic catalysts. Adv. Catal. 3 (1951) 129-178
32. Lowry G.V., and Reinhard M. Pd-catalyzed TCE dechlorination in water: Effect of [H-2](aq) and H-2-utilizing competitive solutes on the TCE dechlorination rate and product distribution. Environ. Sci. Technol. 35 (2001) 696-702
33. Alonso F., Beletskaya I.P., and Yus M. Metal-mediated reductive hydrodehalogenation of organic halides. Chem. Rev. 102 (2002) 4009-4091