AD-OX: A sequential oxidative process for water treatment-Adsorption and batch CWAO regeneration of activated carbon

Chemical Engineering Journal

Volumn 152, Issue 1, 2009, Pages 189-194

  Delmas, H ^a   Creanga, C ^a   Julcour Lebigue, C ^a   Wilhelm, A M ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

Author keywords

Activated carbon; Adsorption; Catalytic oxidation; Mathematical modelling; Multiphase reactions; Packed bed; Water treatment

Indexed keywords

ADSORPTION CAPACITIES; CATALYTIC REACTIONS; COMPETITIVE ADSORPTION; DIFFUSIVITIES; FIXED BED REACTOR; IN-BETWEEN; IN-SITU; LONG RANGE; MATHEMATICAL MODELLING; MULTIPHASE REACTIONS; NONISOTHERMAL; ORGANIC POLLUTION; OXIDATIVE PROCESS; SEQUENTIAL PROCESS; THREE PHASE; WATER PURIFICATION; WET AIR;

ACTIVATED CARBON TREATMENT; ADSORPTION; CATALYSIS; CATALYTIC OXIDATION; CHARCOAL; CHEMICALS REMOVAL (WATER TREATMENT); COMPUTER SIMULATION; DESORPTION; DEWATERING; MATHEMATICAL MODELS; PACKED BEDS; WATER RECYCLING; WATER SUPPLY;

ACTIVATED CARBON;

EID: 67649494326     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2009.04.040     Document Type: Article

References (30)

1. Toledo L.C., Bernardes Silva A.C., Augusti R., and Montero Lago R. Application of Fenton's reagent to regenerate activated carbon saturated with organochloro compounds. Chemosphere 50 (2003) 1049-1054
2. Huling S.G., Jones P.K., Ela W.P., and Arnold R.G. Fenton-driven chemical regeneration of MTBE-spent GAC. Water Res. 39 (2005) 2145-2153
3. Okawa K., Suzuki K., Takeshita T., and Nakano K. Regeneration of granular activated carbon with adsorbed trichloroethylene using wet peroxide oxidation. Water Res. 41 (2007) 1045-1051
4. Alvarez P.M., Beltran F.J., Gomez-Serrano V., Jaramillo J., and Rodriguez E.M. Comparison between thermal and ozone regenerations of spent activated carbon exhausted with phenol. Water Res. 38 (2004) 2155-2165
5. Matatov-Meytal Y.I., and Sheintuch M. Abatement of pollutants by adsorption and oxidative catalytic regeneration. Ind. Eng. Chem. Res. 36 10 (1997) 4374-4380
6. Sheintuch M., and Matatov-Meytal Y.I. Comparison of catalytic processes with other regeneration methods of activated carbon. Catal. Today 53 (1999) 73-80
7. Fortuny A., Font J., and Fabregat A. Wet air oxidation of phenol using active carbon as catalyst. Appl. Catal. B: Environ. 19 3-4 (1998) 165-173
8. Eftaxias A., Font J., Fortuny A., Fabregat A., and Stüber F. Catalytic wet air oxidation of phenol over active carbon catalyst. Global kinetic modelling using simulated annealing. Appl. Catal. B: Environ. 67 1-2 (2006) 12-23
9. Suwanprasop S., Eftaxias A., Stüber F., Polaert I., Julcour-Lebigue C., and Delmas H. Scale-up and modeling of fixed bed reactors for the catalytic phenol oxidation over adsorptive active carbon. Ind. Eng. Chem. Res. 44 (2005) 9513-9523
10. Suarez-Ojeda M.E., Stüber F., Fortuny A., Fabregat A., Carrera J., and Font J. Catalytic wet air oxidation of substituted phenols using active carbon catalyst. Appl. Catal. B: Environ. 58 1-2 (2005) 105-114
11. Santos A., Yustos P., Cordero T., Gomis S., Rodriguez S., and Garcia-Ochoa F. Catalytic wet air oxidation of phenol on active carbon: stability, phenol conversion and mineralization. Catal. Today 102-103 (2005) 213-218
12. H. Delmas, A.M. Wilhelm, I. Polaert, A. Fabregat, F. Stüber, J. Font, Sequential process of adsorption and catalytic oxidation on activated carbon for (pre)treatment of water polluted by non-biodegradable organic products, French patent FRXXBL FR 2826356 A1 20021227 (2002).
13. Polaert I., Wilhelm A.M., and Delmas H. Phenol wastewater treatment by a two-step adsorption-oxidation process on activated carbon. Chem. Eng. Sci. 57 9 (2002) 1585-1590
14. Stüber F., Font J., Fortuny A., Bengoa C., Eftaxias A., and Fabregat A. Carbon materials and catalytic wet air oxidation of organic pollutants in wastewater. Top. Catal. 33 1-4 (2005) 3-50
15. Pintar A., and Levec J. Catalytic liquid-phase oxidation of phenol aqueous solutions. A kinetic investigation. Ind. Eng. Chem. Res. 33 12 (1994) 3070-3077
16. Stüber F., Polaert I., Delmas H., Font J., Fortuny A., and Fabregat A. Catalytic wet air oxidation of phenol using active carbon: performance of discontinuous and continuous reactors. J. Chem. Technol. Biotechnol. 76 (2001) 743-751
17. Pintar A., and Levec J. Catalytic oxidation of aqueous p-chlorophenol and p-nitrophenol solutions. Chem. Eng. Sci. 49 24 (1994) 4391-4407
18. Posada D., Betancourt P., Liendo F., and Brito J.L. Catalytic wet air oxidation of aqueous solutions of substituted phenols. Catal. Lett. 106 1-2 (2006) 81-88
19. Tukac V., and Hanika J. Catalytic wet oxidation of substituted phenols in the trickle bed reactor. J. Chem. Technol. Biotechnol. 71 (1998) 262-266
20. Santos A., Yustos P., Rodriguez S., and Garcia-Ochoa F. Wet oxidation of phenol, cresols and nitrophenols catalyzed by activated carbon in acid and basic media. Appl. Catal. B: Environ. 65 3-4 (2006) 269-281
21. Kojima Y., Fukuta T., Yamada T., Onyango M.S., Bernardo E.C., Matsuda H., and Yagishita K. Catalytic wet oxidation of o-chlorophenol at mild temperatures under alkaline conditions. Water Res. 39 1 (2005) 29-36
22. Li N., Descorme C., and Besson M. Catalytic wet air oxidation of aqueous solution of 2-chlorophenol over Ru/zirconia catalysts. Appl. Catal. B: Environ. 71 3-4 (2007) 262-270
23. Pham Minh D., Gallezot P., and Besson M. Degradation of olive oil mill effluents by catalytic wet air oxidation. 1. Reactivity of p-coumaric acid over Pt and Ru supported catalysts. Appl. Catal. B: Environ. 63 1-2 (2006) 68-75
24. Pham Minh D., Aubert G., Gallezot P., and Besson M. Degradation of olive oil mill effluents by catalytic wet air oxidation. 2. Oxidation of p-hydroxyphenylacetic and p-hydroxybenzoic acids over Pt and Ru supported catalysts. Appl. Catal. B: Environ. 73 3-4 (2007) 236-246
25. Beltran-Heredia J., Torregrosa J., Dominguez J.R., and Peres J.A. Comparison of the degradation of p-hydroxybenzoic acid in aqueous solution by several oxidation processes. Chemosphere 42 4 (2001) 351-359
26. Gonzalez M.D., Moreno E., Quevedo-Sarmiento J., and Ramos-Cormenzana A. Studies on antibacterial activity of waste waters from olive oil mills (alpechin): inhibitory activity of phenolic and fatty acids. Chemosphere 20 3-4 (1990) 423-432
27. Creanga Manole C., Julcour-Lebigue C., Wilhelm A.M., and Delmas H. Catalytic oxidation of 4-hydroxybenzoic acid on activated carbon in batch autoclave and fixed bed reactor. Ind. Eng. Chem. Res. 46 25 (2007) 8388-8396
28. Creanga Manole C., Ayral C., Julcour-Lebigue C., Wilhelm A.M., and Delmas H. Catalytic wet air oxidation of aqueous organic mixtures. Int. J. Chem. React. Eng. 5 (2007) A65. http://www.bepress.com/ijcre/vol5/A65
29. C. Creanga Manole, AD-OX process for remediation of non biodegradable organic pollutants (by adsorption then catalytic oxydation), PhD thesis, INP Toulouse, France, 2007, http://www.ethesis.inp-toulouse.fr/archive/00000561/.
30. Ranz W.E., and Marshall W.R. Evaporation from drops. Part 1 & 2. Chem. Eng. Prog. 48 141-146 (1952) 173-180