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5
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85032778639
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W. F. Carroll, Jr. http://pubs.acs.org/pressrelease/nobelprize/2005.html.
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Carroll, W.F.1
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A. Fürstner L. Ackermann K. Beck H. Hori D. Koch K. Langemann M. Liebel C. Six W. Leitner J. Am. Chem. Soc. 2001 123 9000-9006.
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Fürstner, A.1
Ackermann, L.2
Beck, K.3
Hori, H.4
Koch, D.5
Langemann, K.6
Liebel, M.7
Six, C.8
Leitner, W.9
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21
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85032781057
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6348551
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A. Fürstner, W. Leitner, D. Koch, K. Langemann and C. Six, US Pat. 6348551 (Feb. 19, 2002).
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(2002)
US Pat.
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Fürstner, A.1
Leitner, W.2
Koch, D.3
Langemann, K.4
Six, C.5
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22
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78049530483
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W. Leitner, N. Theyssen, Z. Hou, K. W. Kottsieper, M. Solinas and D. Giunta, US Pat. 2006252951 (Nov. 09, 2006).
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US Pat.
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Leitner, W.1
Theyssen, N.2
Hou, Z.3
Kottsieper, K.W.4
Solinas, M.5
Giunta, D.6
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41
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F. Bonino A. Damin S. Bordiga M. Selva P. Tundo A. Zecchina Angew. Chemie, Engl. Int. Ed. 2005 44 4774-4777.
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Bonino, F.1
Damin, A.2
Bordiga, S.3
Selva, M.4
Tundo, P.5
Zecchina, A.6
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44
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0009617469
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3, with a metal content ranging from 5 to 18%. See
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3, with a metal content ranging from 5 to 18%. See R. Spronk J. A. R. van Veen J. C. Mol J. Catal. 1993 144 472-483.
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(1993)
J. Catal.
, vol.144
, pp. 472-483
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Spronk, R.1
van Veen, J.A.R.2
Mol, J.C.3
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46
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85032758911
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Otherwise, heterogeneous catalysts for the metathesis of olefins were deactivated by moisture and traces of oxygen (ref. 1)
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Otherwise, heterogeneous catalysts for the metathesis of olefins were deactivated by moisture and traces of oxygen (ref. 1).
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47
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85032768928
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2 was possible thanks to sapphire windows fixed on both head and bottom covers of the autoclave (see Experimental)
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2 was possible thanks to sapphire windows fixed on both head and bottom covers of the autoclave (see Experimental).
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48
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85032778773
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http://webbook.nist.gov.
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49
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85032775524
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It was not advisable (and also particularly difficult) to perform the activation step directly in the autoclave. Possible thermal shocks due to a rapid heating (at 550 °C) and a subsequent cooling (at rt) of the catalyst, could be a danger for the steel reactor
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It was not advisable (and also particularly difficult) to perform the activation step directly in the autoclave. Possible thermal shocks due to a rapid heating (at 550 °C) and a subsequent cooling (at rt) of the catalyst, could be a danger for the steel reactor.
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54
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85032754419
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5. These volatile compounds however, were not observed by GC-MS
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5. These volatile compounds however, were not observed by GC-MS.
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56
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1542316833
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The sustainability of these large-scale processes imposes that catalysts must be recyclable
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J. C. Mol J. Mol. Cat. A: Chemical 2004 213 39-45. The sustainability of these large-scale processes imposes that catalysts must be recyclable.
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(2004)
J. Mol. Cat. A: Chemical
, vol.213
, pp. 39-45
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Mol, J.C.1
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57
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0003816233
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P. G. Jessop, W. LeitnerWiley-VCH, Weinheim, Chapt. 1
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Chemical Synthesis Using Supercritical Fluids, P. G. Jessop, W. Leitner, Eds.; Wiley-VCH, Weinheim, 1999; Chapt. 1.
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(1999)
Chemical Synthesis Using Supercritical Fluids
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58
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85032761336
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No improvements were observed when a freshly distilled or a brand new package (ACS grade) of n-heptane were used
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No improvements were observed when a freshly distilled or a brand new package (ACS grade) of n-heptane were used.
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59
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85032763676
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2
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2.
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68
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85032763980
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Re-based heterogeneous catalysts for the metathesis of olefins may contain up to 18% (by weight) of the active metal (ref. 1)
-
Re-based heterogeneous catalysts for the metathesis of olefins may contain up to 18% (by weight) of the active metal (ref. 1).
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72
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85032767773
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The conventional “teflon-coated” stirring bars were not compatible with the high temperature (550 °C) required for the activation of the catalyst
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The conventional “teflon-coated” stirring bars were not compatible with the high temperature (550 °C) required for the activation of the catalyst.
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73
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85032774857
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2) atmosphere was maintained by a rubber reservoir of 2 L
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2) atmosphere was maintained by a rubber reservoir of 2 L.
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75
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85032777292
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MS spectra of both cis and trans 7-tetradecene gave a match quality of 96–97% when compared to standard products of the Wiley Library of Mass Spectral Data, 2002 (MS database software of the GC-MS instrument)
-
MS spectra of both cis and trans 7-tetradecene gave a match quality of 96–97% when compared to standard products of the Wiley Library of Mass Spectral Data, 2002 (MS database software of the GC-MS instrument).
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