Preparation and characterization of poly(ε-caprolactone)/Na+-MMT nanocomposites

Applied Clay Science

Volumn 45, Issue 3, 2009, Pages 105-110

  Wu, Tongfei ^a,b   Xie, Tingxiu ^c   Yang, Guisheng ^a,c  

^a INSTITUTE OF CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^c Shanghai Genius Advanced Materials Co Ltd   (China)

Author keywords

Nanocomposites; Poly( caprolactone) clay; Sodium montmorillonite; Solution mixing

Indexed keywords

CAPROLACTONE; CRYSTALLIZATION BEHAVIOR; LASER DIFFRACTIONS; LATERAL DIMENSION; N ,N-DIMETHYLFORMAMIDE; ORGANIC LIQUID; SODIUM MONTMORILLONITE; SOLUTION MIXING; TEM; THERMAL GRAVIMETRIC ANALYSIS; THERMAL RESISTANCE; TWO-STEP PROCESS;

BIODEGRADATION; CLAY MINERALS; DIFFERENTIAL SCANNING CALORIMETRY; DIFFRACTION; DIMETHYLFORMAMIDE; GRAVIMETRIC ANALYSIS; NANOCOMPOSITES; SILICATE MINERALS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

SODIUM;

BIODEGRADATION; CALORIMETRY; COMPOSITE; CRYSTALLIZATION; DISPERSION; EXPERIMENTAL MINERALOGY; MONTMORILLONITE; SAMPLE PREPARATION; SODIUM; THERMOGRAVIMETRY; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION;

EID: 67649390731     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2009.02.009     Document Type: Article

References (36)

1. Alexandre M., and Dubois P. Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Mater. Sci. Eng. R 28 1-2 (2000) 1-63
2. Bharadwaj R.K. Modeling the barrier properties of polymer-layered silicate nanocomposites. Macromolecules 34 26 (2001) 9189-9192
3. Bourbigot S., LeBras M., Dabrowski F., Gilman J.W., and Kashiwagi T. PA-6 clay nanocomposite hybrid as char forming agent in intumescent formulations. Fire Mater. 24 4 (2000) 201-208
4. Chaudhary D.S., Prasad R., Gupta R.K., and Bhattacharya S.N. Clay intercalation and influence on crystallinity of EVA-based clay nanocomposites. Thermochim Acta 433 1-2 (2005) 187-195
5. Di Maio E., Iannace S., Sorrentino L., and Nicolais L. Isothermal crystallization in PCL/clay nanocomposites investigated with thermal and rheometric methods. Polymer 45 26 (2004) 8893-8900
6. Giannelis E.P. Polymer layered silicate nanocomposites. Adv. Mater. 8 1 (1996) 29-35
7. Giannelis E.P. Polymer-layered silicate nanocomposites: synthesis, properties and applications. Appl. Organomet. Chem. 12 10-11 (1998) 675-680
8. Giannelis E.P., Krishnamoorti R., and Manias E. Polymer-silicate nanocomposites: model systems for confined polymers and polymer brushes. Adv. Polym. Sci. 138 (1999) 107-147
9. Gilman J.W. Flammability and thermal stability studies of polymer layered-silicate(clay) nanocomposites. Appl. Clay Sci. 15 1-2 (1999) 31-49
10. Gilman J.W., Kashiwagi T., and Lichtenhan J.D. Nanocomposites: a revolutionary new flame retardant approach. SAMPE J. 33 (1997) 40-46
11. Gilman J.W., Jackson C.L., Morgan A.B., Harris Jr. R., Manias E., Giannelis E.P., Wuthenow M., Hilton D., and Phillips S.H. Flammability properties of polymer-layered silicate nanocomposites: propylene and polystyrene nanocomposites. Chem. Mater. 12 7 (2000) 1866-1873
12. Gorrasi G., Tortora M., Vittoria V., Pollet E., Lepoittevin B., Alexandre M., and Dubois P. Vapor barrier properties of polycaprolactone clay nanocomposites: effect of clay dispersion. Polymer 44 8 (2003) 2271-2279
13. Jimenez G., Ogata N., Kawai H., and Ogihara T. Structure and thermal/mechanical properties of poly (ε-caprolactone)-clay blend. J. Appl. Polym. Sci. 64 11 (1997) 2211-2220
14. Kojima Y., Usuki A., Kawasumi M., Fukushima Y., Okada A., Kurauchi T., and Kamigaito O. Synthesis of nylon 6-clay hybrid. J. Mater. Res. 8 5 (1993) 1179-1184
15. LeBaron P.C., Wang Z., and Pinnavaia T.J. Polymer-layered silicate nanocomposites: an overview. Appl. Clay Sci. 15 1-2 (1999) 11-29
16. Lee S.R., Park H.M., Lim H., Kang T., Li X., Cho W.J., and Ha C.S. Microstructure, tensile properties, and biodegradability of aliphatic polyester/clay nanocomposites. Polymer 43 8 (2002) 2495-2500
17. Lepoittevin B., Devalckenaere M., Pantoustier N., Alexandre M., Kubies D., Calberg C., Jèrôme R., and Dubois P. Poly(ε-caprolactone)/clay nanocomposites prepared by melt intercalation: mechanical, thermal and rheological properties. Polymer 43 14 (2002) 4017-4023
18. Lepoittevin B., Pantoustier N., Devalckenaere M., Alexandre M., Kubies D., Calderg C., Jerome R., and Dubois P. Poly(ε-caprolactone)/clay nanocomposites by in-situ intercalative polymerization catalyzed by dibutyltin dimethoxide. Macromolecules 35 22 (2002) 8385-8390
19. Lepoittevin B., Pantoustier N., Devalckenaere M., Alexandre M., Calberg C., Jerome R., Henrist C., Rulmont A., and Dubois P. Polymer/layered silicate nanocomposites by combined intercalative polymerization and melt intercalation: a masterbatch process. Polymer 44 7 (2003) 2033-2040
20. Liao L., Zhang C., and Gong S. Preparation of Poly(ε-caprolactone)/clay nanocomposites by microwave-assisted in situ ring-opening polymerization. Macromol. Rapid Commun. 28 10 (2007) 1148-1154
21. Liu J.W., Zhao Q., and Wan C.X. Research progresses on degradation mechanism in vivo and medical applications of polylactic acid. Space Med. Med. Engng. 14 4 (2001) 308-312
22. Ludueňa L.N., Alvarez V.A., and Vazquez A. Processing and microstructure of PCL/clay nanocomposites. Mater. Sci. Eng. A 460-461 (2007) 121-129
23. Messersmith P.B., and Giannelis E.P. Polymer-layered silicate nanocomposites: in situ intercalative polymerization of ε-caprolactone in layered silicates. Chem. Mater. 5 8 (1993) 1064-1066
24. Messersmith P.B., and Giannelis E.P. Synthesis and barrier properties of poly(ε-caprolactone)-layered silicate nanocomposites. J. Polym. Sci., Part A. Polym. Chem. 33 7 (1995) 1047-1057
25. +-MMThybrids. Schaefer, D.W., Mark, J.E., MRS Symposium Proceedings, Pittsburgh, 171, 45.
26. Olejnik S., Posner A.M., and Quirk J.P. Swelling of montmorillonite in polar organic liquids. Clay Clay Miner. 22 (1974) 361-365
27. Pantoustier N., Alexandre M., Degee P., Calberg C., Jerome R., Henrist C., Cloots R., Rulmont A., and Dubois P. Poly(ε-caprolactone)/clay nanocomposites prepared by melt intercalation. mechanical, thermal and rheological properties. Polymer 43 14 (2002) 4017-4023
28. Pantoustier N., Lepoittevin B., Alexandre M., Kubies D., Calberg C., Jerome R., and Dubois P. Biodegradable polyester layered silicate nanocomposites based on poly(ε-caprolactone). Polym. Eng. Sci. 42 9 (2002) 1928-1937
29. Ray S.S., and Okamoto M. Polymer/layered silicate nanocomposites. a review from preparation to processing. Prog. Polym. Sci. 28 1 (2003) 1539-1641
30. Ray S.S., Yamada K., Okamoto M., and Ueda K. New polylactide-layered silicate nanocomposites. 2. Concurrent improvements of material properties, biodegradability and melt rheology. Polymer 44 3 (2003) 857-866
31. Shen L., Lin Y., Du Q., and Zhong W. Studies on structure-property relationship of polyamide-6/attapulgite nanocomposites. Compos. Sci. Technol. 66 13 (2006) 2242-2248
32. Tetto J.A., Steeves D.M., Welsh E.A., and Powell B.E. Biodegradable poly(ε-caprolactone)/clay nanocomposites (1999) ANTEC'99 1628-1632
33. Wu T.M., Cheng J.C., and Yan M.C. Crystallization and thermoelectric behavior of conductive-filler-filled poly(ε-caprolactone)/poly(vinyl butyral)/clay nanocomposites. Polymer 44 8 (2003) 2553-2562
34. Xu R., Manias E., Snyder A.J., and Runt J. New biomedical poly(urethaneurea)-layered silicate nanocomposites. Macromolecules 34 2 (2001) 337-339
35. Yano K., Usuki A., Okada A., Kurauchi T., and Kamigaito O. Synthesis and properties of polyimide-clay hybrid. J. Polym. Sci., Part A. Polym. Chem. 31 10 (1993) 2493-2498
36. Zhang Q., Yu Z., Yang M., Ma J., and Mai Y. Multiple melting and crystallization of nylon-66/montmorillonite nanocomposites. J. Polym. Sci. Part A: Polym. Chem. 41 22 (2003) 2861-2869