Structure reactivity and thermodynamic analysis on the oxidation of ampicillin drug by copper(III) complex in aqueous alkaline medium (stopped-flow technique)

Journal of Molecular Structure

Volumn 930, Issue 1-3, 2009, Pages 180-186

  Shetti, Nagaraj P ^a   Hegde, Rajesh N ^a   Nandibewoor, Sharanappa T ^a  

^a KARNATAK UNIVERSITY   (India)

Author keywords

Ampicillin; Diperiodatocuprate(III); Mechanism; Oxidation; Thermodynamic studies

Indexed keywords

6-AMINOPENICILLANIC ACID (6-APA); ACTIVATION PARAMETER; ALKALINE MEDIUM; AMP COMPLEX; AMPICILLIN; COPPER COMPLEXES; DIPERIODATOCUPRATE; DIPERIODATOCUPRATE(III); EXPERIMENTAL EVIDENCE; FREE RADICAL SPECIES; OXIDATION REACTIONS; PROTONATED; RATE DETERMINING STEP; REACTION CONSTANT; STOPPED-FLOW TECHNIQUES; STRUCTURE REACTIVITY; THERMO DYNAMIC ANALYSIS; THERMODYNAMIC QUANTITIES; THERMODYNAMIC STUDIES;

COPPER COMPOUNDS; FREE RADICAL REACTIONS; IONIC STRENGTH; OXIDATION; STOICHIOMETRY; THERMOANALYSIS; THERMODYNAMIC PROPERTIES;

FREE RADICALS;

EID: 67549092939     PISSN: 00222860     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molstruc.2009.05.013     Document Type: Article

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