Unsymmetrically Bridged Methyl Groups as Intermediates in the Transformation of Bridging Methylene to Bridging Acetyl Groups: Ligand Migrations and Migratory Insertions in Mixed Iridium/Ruthenium Complexes

Organometallics

Volumn 28, Issue 12, 2009, Pages 3407-3420

  Samant, Rahul G ^a   Trepanier, Steven J ^a   Wigginton, James R ^a   Xu, Li ^b   Bierenstiel, Matthias ^a   McDonald, Robert ^c   Ferguson, Michael J ^c   Cowie, Martin ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

^b FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^c CAPE BRETON UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYL GROUPS; AGOSTIC INTERACTIONS; AMBIENT TEMPERATURES; BRIDGING SITES; C-H BOND; C-H COUPLING CONSTANT; CARBONYL LIGAND; DIHYDRIDE; DIHYDROGEN; DIRECT OBSERVATION; DISPROPORTIONATION; H NMR SPECTROSCOPY; HETEROLYTIC CLEAVAGE; INSERTION PRODUCTS; ION DISPLACEMENTS; METHYL COMPLEXES; METHYL GROUP; MIGRATORY INSERTION; NEW SPECIES; PENTACARBONYL; REFLUXING; TERMINAL POSITION; TIME-SCALE; TRIFLATE;

ALDEHYDES; CARBONYLATION; COMPLEXATION; HYDROCARBONS; HYDROGEN; IRIDIUM; LIGANDS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXYGEN; PROTONATION; PROTONS; SUGAR (SUCROSE); SULFUR COMPOUNDS;

GROUP TECHNOLOGY;

EID: 67449136156     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900127u     Document Type: Article

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