Reactive extraction of propionic acid using tri-n-octylamine, tri-n-butyl phosphate and aliquat 336 in sunflower oil as diluent

Journal of Chemical Technology and Biotechnology

Volumn 84, Issue 4, 2009, Pages 484-489

  Keshav, Amit ^a   Wasewar, Kailas L ^a   Chand, Shri ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY ROORKEE   (India)

Author keywords

Aliquat 336; Propionic acid; Reactive extraction; Sunflower oil; Tri n butylphosphate (TBP); Tri n octylamine (TOA)

Indexed keywords

ALIQUAT 336; PROPIONIC ACID; REACTIVE EXTRACTION; SUNFLOWER OIL; TRI-N-BUTYLPHOSPHATE (TBP); TRI-N-OCTYLAMINE (TOA);

COMPLEXATION; FATTY ACIDS; KETONES; SOLVENTS; TOXICITY; VEGETABLE OILS;

ACIDS;

DECANOL; DILUENT; PROPIONIC ACID; SUNFLOWER OIL; TRIALKYLMETHYLAMMONIUM; TRIBUTYL PHOSPHATE; TRIOCTYLAMINE; UNCLASSIFIED DRUG;

ARTICLE; BIOREACTOR; CHEMICAL REACTION; COMPLEX FORMATION; EQUILIBRIUM CONSTANT; LIQUID LIQUID EXTRACTION; PROCESS OPTIMIZATION; REACTIVE EXTRACTION; TOXICITY TESTING;

HELIANTHUS;

EID: 67449133524     PISSN: 02682575     EISSN: 10974660     Source Type: Journal    
DOI: 10.1002/jctb.2066     Document Type: Article

References (24)

1. Boyaval P and Corre C, Production of propionic acid. Lait 75:453-461 (1995).
2. Wasewar KL, Pangarkar VG, Yawalkar AA and Moulijn JA, Fermentation of glucose to lactic acid coupled with reactive extraction: a review. Ind Eng Chem Res 43:5969-5982 (2004).
3. Wasewar KL and Pangarkar VG, Intensification of propionic acid production by reactive extraction: effect of diluents on equilibrium. Chem Biochem Eng Q 20:325-331 (2006).
4. Uslu H, Linear solvation energy relationship (LSER) modeling and kinetic studies on propionic acid reactive extraction using Alamine 336 in a toluene solution. Ind Eng Chem Res 45:5788-5795 (2006).
5. Uslu H and Inci I, (Liquid + liquid) equilibria of the (water + propionic acid + Aliquat 336 + organic solvents) at T = 298.15 K. J Chem Thermodyn 39:804-809 (2007).
6. Kyuchoukov G, Morales AF, Albet J, Malmary G and Molinier J, Influence of extractant (TBP and TOA), diluent, and modifier on extraction equilibrium of monocarboxylic acids. J Chem Eng Data 48:874-886 (2003).
7. Kyuchoukov G, Marinova M, Albet J and Molinier J, New methods for the extraction of lactic acidbymeans ofmodifiedextractant (Aliquat 336). Ind Eng Chem Res 43:1179-1184 (2004).
8. Kyuchoukov G, Marinova M, Albet J, Molinier J and Malmary G, Separation of tartaric and lactic acids by means of solvent extraction. Sep Purif Technol 37:199-207 (2004).
9. Solichien MS, O Brien D, Hammond EG and Glaz CE, Membrane based extractive fermentation to produce propionic acid and acetic acid: toxicity and mass transfer considerations. Enz Microb Technol 17:23-31 (1995).
10. Laane C, Boeren S and Vos K, On optimizing organic solvents in multiliquid-phase biocatalysis. Trends Biotechnol 3:251-252 (1985).
11. Zhong G, Bonita AG and Charles EG, Propionic acid production by extractive fermentation. I. Solvent considerations. Biotechnol Bioeng 57:454-461 (1998).
12. Yabannavar VM and Wang DIC, Strategies for reducing solvent toxicity in extractive fermentations. Biotechnol Bioeng 37:716-722 (1991).
13. RofIler SR, Randolph TW, Miller DA, Blanch HW and Prausnitz JM, Extractive bioconversions with non-aqueous solvents, in Extractive Bioconversions, ed. by Mattiasson B and Holst O. Marcel Dekker Inc., New York, pp. 135-140 (1991).
14. Poposka FA, Prochazka J, Tomovska R, Nikolovski K and Grizo A, Extraction of tartaric acid from aqueous solutions with tri-isooctylamine (HOSTAREX A 324). Equilibrium and kinetics. Chem Eng Sci 55:1591-1604 (2000).
15. Morales AF, Albet J, Kyuchoukov G, Malmary G and Molinier J, Influence of extractant (TBP and TOA), diluent, and modifier on extraction equilibrium of monocarboxylic acids. J Chem Eng Data 48:874-886 (2003).
16. Marinova M, Kyuchoukov G, Molinier J and Albet J, Specific influence of the modifier (1-decanol) on the extraction of tartaric acid by different extractants. Ind Eng Chem Res 44:6534-6538 (2005).
17. Malmary G, Albet J, Putranto A, Hanine H and Molinier J, Measurement of partition coefficients of carboxylic acids between water and tri-isooctylamine dissolved in various diluents. J Chem Eng Data 43:849-857 (1998).
18. Harington T and Hossain MdM, Extraction of lactic acid into sunflower oil and its recovery into an aqueous solution. Desalination 218:287-296 (2008).
19. Keshav A, Wasewar KL and Chand S, Extraction of propionic acid using tri-n-butyl phosphate, tri-n-octylamine and Aliquat 336. Ind Eng Chem Res 47:6192-6196 (2008).
20. Keshav A, Wasewar KL and Chand S, Equilibrium studies for extraction of propionic acid using tri-n-butyl phosphate in different solvents. J Chem Eng Data 53:1424-1430 (2008).
21. Keshav A, Wasewar KL and Chand S, Reactive extraction of propionic acid with tri-n-octylamine in different diluents. Sep Purif Technol 63:197-183 (2008).
22. Yang ST, White SA and Hsu ST, Extraction of carboxylic acids with tertiary and quaternary amines: effect of pH. Ind Eng Chem Res 30:1335-1342 (1991).
23. Martik J, Rosenbergl M, Schlosser S and Kristofikovi C, Toxicity of organic solvents used in situ microbial fermentation. Biotechnol Techniques 9:247-252 (1995).
24. Playne MJ and Smith BR, Toxicity of organic extraction reagents to anaerobic bacteria. Biotechnol Bioeng 25:1251-1265 (1983).