Vibrational behavior of matrix-isolated ions in Tutton compounds. I. Infrared spectroscopic study of NH4+ and SO42- ions included in magnesium sulfates and selenates

Journal of Molecular Structure

Volumn 929, Issue 1-3, 2009, Pages 67-72

  Marinova, D ^a   Georgiev, M ^b   Stoilova, D ^a  

^a INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY   (Bulgaria)

^b UNIVERSITY OF CHEMICAL TECHNOLOGY AND METALLURGY   (Bulgaria)

Author keywords

(NH4)2Mg(SeO4)2 6H2O; (NH4)2Mg(SO4)2 6H2O; Crystal matrix infrared spectroscopy; K2Mg(SeO4)2 6H2O; K2Mg(SO4)2 6H2O; Tutton salts

Indexed keywords

ASYMMETRIC BENDING; BAND POSITION; COMPETITIVE EFFECTS; CRYSTAL MATRIX INFRARED SPECTROSCOPY; ELECTROSTATIC FIELD STRENGTH; ENERGETIC DISTORTIONS; INFRARED SPECTROSCOPIC STUDIES; INFRARED SPECTRUM; ION CONCENTRATIONS; ISOLATED IONS; LATTICE SITES; LOWER FREQUENCIES; MAGNESIUM SULFATE; MATRIX; MIXED CRYSTALS; NORMAL MODES; PROTON ACCEPTORS; SITE SYMMETRY; SPECTRAL REGION; STRETCHING MODES; SULFATE ION; TUTTON SALTS; UNIT-CELL VOLUME; VIBRATIONAL BEHAVIOR; WATER LIBRATIONS; WATER MOLECULE;

AMMONIUM COMPOUNDS; BINDING SITES; COMPLEXATION; HYDROGEN; HYDROGEN BONDS; MAGNESIUM; NEGATIVE IONS; POTASSIUM COMPOUNDS; PROTONS; SALTS; SELENIUM COMPOUNDS; SEMICONDUCTOR QUANTUM DOTS; SPECTROSCOPIC ANALYSIS; SPECTRUM ANALYSIS; WATER ANALYSIS;

INFRARED SPECTROSCOPY;

EID: 67349247028     PISSN: 00222860     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molstruc.2009.04.004     Document Type: Article

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