Stability of phyllosilicates in Ca(OH)2 solution: Influence of layer nature, octahedral occupation, presence of tetrahedral Al and degree of crystallinity

Applied Geochemistry

Volumn 24, Issue 7, 2009, Pages 1251-1260

  Mantovani, M ^a   Escudero, A ^b   Alba, M D ^a   Becerro, A I ^a  

^a INSTITUTO DE CIENCIA DE MATERIALES DE SEVILLA   (Spain)

^b UNIVERSITÄT BAYREUTH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALINE CONDITIONS; CLAY STRUCTURE; CRYSTALLINITY; DEGREE OF CRYSTALLINITY; EXPANDABILITY; HYDROTHERMAL CONDITIONS; INTERMEDIATE STAGE; LAYERED SILICATE; MAS-NMR SPECTROSCOPY; PHYLLOSILICATE; PORTLANDITE; POWDER X RAY DIFFRACTION; RADIOACTIVE WASTE REPOSITORY; SEM/EDX; STARTING MATERIALS; TETRAHEDRAL SHEETS;

ALUMINUM; CALCIUM; DISSOLUTION; EMPLOYMENT; INDUSTRIAL WASTE TREATMENT; LEACHING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RADIOACTIVE WASTES; SILICATES; STABILITY;

CLAY MINERALS;

ALKALINITY; CALCIUM; CRYSTALLINITY; LEACHING; NUCLEAR MAGNETIC RESONANCE; PH; PHYLLOSILICATE; RADIOACTIVE WASTE; REPOSITORY; SCANNING ELECTRON MICROSCOPY;

EID: 67349201660     PISSN: 08832927     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apgeochem.2009.03.012     Document Type: Article

References (41)

1. Alba M.D., and Chain P. Persistence of lutetium disilicate. Appl. Geochem. 22 (2007) 192-201
2. Alba M.D., Becerro A.I., Castro M.A., and Perdigón A.C. Hydrothermal reactivity of lu-saturated smectites: Part II. A short-range order study. Am. Miner. 86 (2001) 124-131
3. Allen C.C., and Wood M.I. Bentonite in nuclear waste disposal: a review of research in support of the basalt waste isolation project. Appl. Clay Sci. 3 (1988) 11-30
4. Andersson K., Allard B., Bengtsson M., and Magnusson B. Chemical composition of cement pore solutions. Cem. Concr. Res. 19 (1989) 327-332
5. Becerro, A.I., 1997. Ph.D. Thesis, Univ. Seville.
6. Bauer A., and Berger G. Kaolinite and smectite dissolucion rate in high molear KOH solutions at 35 °C and 80 °C. Appl. Geochem. 13 (1998) 905-916
7. Bauer A., Velde B., and Berger G. Kaolinite transformation in high molar KOH solutions. Appl. Geochem. 13 (1998) 619-629
8. Bentabol M., Ruiz Cruz M.D., Huertas F.J., and Linares J. Hydrothermal transformation of kaolinite to illite at 200 °C and 300 °C. Clay Miner. 38 (2003) 161-172
9. 23Na NMR spectra of sodium silicate crystals and glasses. J. Phys. Chem. B 108 (2004) 4147-4161
10. Chain, P., 2007. Ph.D. Thesis, Univ. Seville.
11. Cong X., and Kirkpatrick R.J. Si-29 MAS NMR study of the structure of calcium silicate hydrate. Adv. Cem. Based Mater. 3 (1996) 144-156
12. 2. Am. J. Sci. Bowen 10 (1952) 7-114
13. Desprairies A. Relation entre le parametre b des smectites et leer contenu en fer et magnesium. Application a ĺetude des sediments. Clay Miner. 18 (1983) 165-175
14. Glasser F.P. Mineralogical aspects of cement in radioactive waste disposal. Mineral. Mag. 65 (2001) 621-633
15. Grim R.E. Clay Mineralogy (1968), McGraw-Hill Book Company, New York
16. 29Si MAS NMR spectroscopy. Inorg. Chem. 42 (2003) 2368-2377
17. 29Si MAS NMR study of the structure of calcium silicate hydrate. Adv. Cem. Based Mater. 14 (1999) 1828-1833
18. Huang W.L. The formation of illitic clays from kaolinite in KOH solution from 225 °C to 350 °C. Clays Clay Miner. 41 (1993) 645-654
19. Kirkpatrick R.J., Kinsey R.A., Smith K.A., Henderson D.M., and Oldfield E. High-resolution solid-state Na-23, Al-27, and Si-29 nuclear magnetic-resonance spectroscopic reconnaissance of alkali and plagioclase feldspars. Am. Miner. 70 (1985) 106
20. Kosuge K., Shimada K., and Tsunashima A. Micropore formation by acid treatment of antigorite. Chem. Mater. 7 (1995) 2241-2246
21. Liebau F. Structural Chemistry of Silicates (1985), Springer-Verlag, Berlin
22. Massiot D., Fayon F., Capron M., King I., Le Calvé S., Alonso B., Durand J.O., Bujoli B., Gan Z., and Hoatson G. Modelling one- and two-dimensional solid-state NMR spectra. Magn. Reson. Chem. 40 (2002) 70-78
23. Mather J.D., Chapman N.A., Black J.H., and Lintern B.C. The geological disposal of high-level radioactive waste - a review of the institute of geological sciences research programme. Nucl. Energy 21 (1982) 167-173
24. McCulloch C.E., Angus M.J., Crawford R.W., Rahman A.A., and Glasser F.P. Mineral. Mag. 49 (1985) 211-218
25. 1H MAS NMR of natural and synthetic xonotlite. Chem. Lett. 3 (1998) 219-220
26. Pusch R., and Yong R. Water saturation and retention of hydrophilic clay buffer - microstructural aspects. Appl. Clay Sci. 23 (2003) 61-68
27. Pusch R., Zwahr H., Gerber R., and Schomburg J. Interaction of cement and smectite clay - theory and practice. Appl. Clay Sci. 23 (2003) 203-210
28. Ramírez S., Cuevas J., Vigil R., and Leguey S. Hydrothermal alteration of "La Serrata" bentonita (Almería, Spain) by alkaline solutions. Appl. Clay Sci. 21 (2002) 257-269
29. Ramírez S., Righi D., and Petit S. Alteration of smectites induced by hydrolitic exchange. Clay Miner. 40 (2005) 15-24
30. Rassineux F., Griffault L., Meunier A., Berger G., Petit S., Viellard P., Zellagui R., and Munoz M. Expandibility-layer stacking relationship during experimental alteration of a Wyoming bentonite in pH 13.5 solutions at 35 °C and 60 °C. Clay Miner. 36 (2001) 197-210
31. Read D., Glasser F.P., Ayora C., Guardiola M.T., and Sneyers A. Mineralogical and microstructural changes accompanying the interaction of boom clay with ordinary Portland cement. Adv. Cem. Res. 13 (2001) 175-183
32. Reardon E.J. An ion interaction model for the determination of chemical equilibrium in cement/water systems. Cem. Concr. Res. 20 (1990) 175-192
33. Sánchez L., Cuevas J., Ramírez S., Ruiz de León D., Fernández R., Vigil R., and Leguey S. Geochemical reactions of FEBEX bentonite in hyperalkaline conditions resembling the cement-bentonite interface. Appl. Clay Sci. 33 (2006) 125-132
34. Sanz J., and Serratosa J.M. Si-29 and Al-27 high-resolution MAS-NMR spectra of phyllosilicates. J. Am. Chem. Soc. 106 (1984) 4790-4793
35. Savage D., and Chapman N.A. Hydrothermal behaviour of simulated waste glass - and waste-rock interaction under repository conditions. Chem. Geol. 36 (1982) 59-86
36. Savage D., Noy D., and Mihara M. Modelling the interaction of bentonite with hyperalkaline fluids. Appl. Geochem. 17 (2002) 207-223
37. Sheriff B.L., Grundy H.D., Hartman J.S., and Hawthorne F.C. The incorporation of alkalis in beryl - multinuclear MAS NMR and crystal-structure study. Can. Miner. 29 (1991) 271-276
38. Vieillard P., and Rassineux F. Thermodynamic and geochemical modeling of the alteration of two cement matrices. Appl. Geochem. 1 (1992) 125-136
39. Vigil R., Cuevas J., Ramírez S., and Leguey S. Zeolite formation during the alkaline reaction of bentonite. Eur. J. Miner. 13 (2001) 635-644
40. Wheeler P.A., Wang J.Z., Baker J., and Mathias L.J. Synthesis and characterization of convalently functionalized laponite clay. Chem. Mater. 17 (2005) 3012-3018
41. 27Al nuclear magnetic resonance spectroscopy. Am. Miner. 74 (1989) 203-215