Shear and elongational flow behavior of acrylic thickener solutions. Part II: Effect of gel content

Rheologica Acta

Volumn 48, Issue 4, 2009, Pages 397-407

  Kheirandish, Saeid ^a,c   Gubaydullin, Ilshat ^b   Willenbacher, Norbert ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

^b BASF SE   (Germany)

^c BOREALIS POLYOLEFINE GMBH   (Austria)

Author keywords

Acrylate thickener; CaBER; Crosslinking; Elongational flow; Oscillatory squeeze flow; Sol gel transition; Steady shear

Indexed keywords

CROSS-LINK DENSITIES; ELONGATIONAL FLOW; EXTENSIONAL FLOWS; FILAMENT DIAMETER; GEL CONTENTS; GIESEKUS MODEL; LINEAR VISCOELASTIC; LOW-SHEAR VISCOSITY; MIXING RATIOS; MODEL SYSTEM; NON-LINEARITY PARAMETER; NONUNIFORM; ORDERS OF MAGNITUDE; OSCILLATORY SQUEEZE FLOW; SHEAR RELAXATION; SINGLE MODE; SMOOTH TRANSITIONS; SOL-GEL TRANSITIONS; STEADY SHEAR;

FILAMENTS (LAMP); FLOW FIELDS; FLUID DYNAMICS; RELAXATION PROCESSES; SOL-GEL PROCESS; SOL-GELS; SOLS; STEADY FLOW; VISCOSITY;

GELS;

EID: 67349200245     PISSN: 00354511     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00397-008-0324-x     Document Type: Article

References (41)

1. Abdala AA, Wu W, Olsen KR, Jenkins RD, Tonelli AE, Khan SA (2004) Solution rheology of hydrophobically modified associative polymers: effects of backbone composition and hydrophobe concentration. J Rheol 48:979-994
2. Agarwal S, Gupta RK (2002) An innovative extensional viscometer for low-viscosity and low-elasticity liquids. Rheol Acta 45:456-460
3. Baumgaertel M, Schausberger A, Winter HH (1990) The relaxation of polymers with linear flexible chains of uniform length. Rheol Acta 29:400-408
4. Bazilevskii AV, Entov VM, Rozhkov AN (2001) Breakup of an Oldroyd liquid bridge as a method for testing the rheological properties of polymer solutions. Polym Sci Ser A 43:716-726
5. Bhardwaj A, Richter D, Chellamuthu M, Rothstein JP (2007) The effect of pre-shear on the extensional rheology of wormlike micelle solutions. Rheol Acta 46:861-875
6. Braun DB, Rosen MR (2000) Rheology modifiers handbook, practical use & application. William Andrew, Norwich
7. Clasen C, Plog JP, Kulicke WM, Owens M, Macosko C, Scriven LE, Verani M, McKinley GH (2006) How dilute are dilute solutions in extensional flows. J Rheol 50:849-881
8. Crassous JJ, Régisser R, Ballauff M, Willenbacher N (2005) Characterization of the viscoelastic behavior of complex fluids using the piezoelectric axial vibrator. J Rheol 49:851-863
9. Dai S, Tam KC, Jenkins RD (2000) Aggregation behavior of methacrylic acid/ethyl acrylate copolymer in dilute solutions. Eur Polym J 36:2671-2677
10. Dexter RW (1996) Measurement of extensional viscosity of polymer solutions and its effects on atomization from a spray nozzle. At Sprays 6:167-191
11. English RJ, Gulati HS, Jenkins RD, Khan SA (1997) Solution rheology of hydrophobically modified alkali soluble associative polymers. J Rheol 41:427-444
12. English RJ, Raghavan SR, Jenkins RD, Khan SA (1999) Associative polymer bearing n-alkyl hydrophobes: Rheological evidence for microgel-like behaviour. J Rheol 43:1175-1194
13. Entov VM, Hinch EJ (1997) Effect of a spectrum of relaxation times on the capillary thinning of a filament of elastic liquid. J Non-Newton Fluid Mech 72:31-53
14. Ferguson J, Hudson NE, Odriozola MA (1997) The interpretation of transient extensional viscosity data. J Non-Newton Fluid Mech 68:241-257
15. Fernando RH, Xing LL, Glass JE (2000) Rheology parameters controlling spray atomization and roll misting behavior of waterborne coatings. Prog Org Coat 40:35-38
16. Giesekus H (1982) A simple constitutive equation for polymer fluids based on the concept of deformation-dependent tensorial mobility. J Non-Newton Fluid Mech 11:69-109
17. Hager O, Martin R (1957) Copolymer of acrylic acid ester, method of making, and use of said polymer to coat textile fabrics. US patent 3003987 and Martin and Hager (1957) Acrylic tetrapolymer and textiles coated with the same. US patent 3070561
18. James DF, Yogachandran N, Roper JA III (2003) Fluid elasticity in extension, measured by a new technique, correlates with misting. 8th TAPPI Advanced coating fundamentals symposium, Chicago, pp 166-171
19. Kennedy JC, Meadows J, Williams P (1995) Shear and extensional viscosity characteristics of a series of hydrophobically associating polyelectrolytes. J Chem Soc Faraday Trans 91:911-916
20. Kheirandish S, Gubaydullin I, Wohlleben W, Willenbacher N (2008) Shear and elongational flow behavior of acrylic thickener solutions. Part I: Effect of intermolecular aggregation. Rheol Acta. doi: 10.1007/ s00397-008-0292-1
21. Kirschenmann L (2003) PhD Thesis Institut für Dynamische Materialprüfung, Universität Ulm
22. Kumacheva E, Rharbi Y, Winnik MA, Guo L, Tam KC, Jenkins RD (1996) Fluorescence studies of an alkaline swellable associative polymer in aqueous solution. Langmuir 12:182-186
23. Macosko CW (1994) Rheology: Principles, measurements and applications. Wiley-VCH
24. McKinley GH, Tripathi A (2000) How to extract the Newtonian viscosity from capillary breakup measurements in a filament rheometer. J Rheol 44:653-670
25. Mewis J, Kaffashi BG, Vermant J, Butera RJ (2001) Determining relaxation modes in flowing associative polymers using superposition flows. Macromolecules 34:1376-1383
26. Miller (1960) Mineral coated paper products and methods of making them. US patent 3081198
27. Ng SL, Mun RP, Boger DV, James DF (1996) Extensional viscosity measurements of dilute solutions of various polymers. J Non-Newton Fluid Mech 65:291-298
28. Plog JP, Kulicke WM, Clasen C (2005) Influence of molar mass distribution on the elongational behavior of polymer solutions in capillary breakup. Appl Rheol 15:28-37
29. Solomon MJ, Muller SJ (1996) The transient extensional behavior of polystyrene-based Boger fluids of varying solvent quality and molecular weight. J Rheol 40:837-856
30. Sridhar T, McKinley GH (2002) Filament-stretching rheometry of complex fluids. Annu Rev Fluid Mech 34:375-415
31. Stelter M, Brenn G, Yarin AL, Singh RP, Durst F (2000) Validation and application of a novel elongational device for polymer solutions. J Rheol 44:595-616
32. Stelter M, Brenn G, Yarin AL, Singh RP, Durst F (2002) Investigation of the elongational behavior of polymer solutions by means of an elongational rheometer. J Rheol 46:507-527
33. Sujatha KS, Matallah H, Banaai MJ, Webster MF (2008) Modeling step-strain filament-stretching (CaBER-type) using ALE techniques. J Non-Newton Fluid Mech 148:109-121
34. Tan H, Tam KC, Tirtaamadja V, Jenkins RD, Bassett DR (2000) Extensional properties of model hydrophobically modified alkali-soluble associative (HASE) polymer solutions. J Non-Newton Fluid Mech 92:167-185
35. Tripathi A, Tam KC, McKinley GH (2006) Rheology and dynamics of associative polymers in shear and extension: Theory and experiments. Macromolecules 39:1981-1999
36. Tuladhar TR, Mackley MR (2008) Filament stretching rheometry and break-up behaviour of low viscosity polymer solutions and inkjet fluids. J Non-Newton Fluid Mech 148:97-108
37. Wang C, Tam KC, Tan CB (2005) Dissolution and swelling behaviors of random and cross-linked methacrylic acid-ethyl acrylate copolymers. Langmuir 21:4191-4199
38. Webster MF, Matallah H, Sujatha KS, Banaai MJ (2008) Numerical modelling of step-strain for stretched filaments. J Non-Newton Fluid Mech 151:38-58
39. Willenbacher N (2004) Elongational viscosity of aqueous thickener solutions from capillary break-up elongational rheometry (CaBER). Proc XIVth Int Cong Rheol, Seoul, S Korea
40. Winter HH, Morganelli P, Chambon F (1988) Stoichiometry effects on rheology of model polyurethanes at the gel point. Macromolecules 21:532-535
41. Yesilata B, Clasen C, McKinley GH (2006) Nonlinear shear and extensional flow dynamics of wormlike surfactant solutions. J Non-Newton Fluid Mech 133:73-90