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Volumn 12, Issue 6, 2009, Pages 583-587

Metal-organic frameworks constructed from monomeric, dimeric and trimeric phenanthroline citrate zinc building units

Author keywords

Citric acid; Crystal structure; Interconversion; Mixed ligands; Zinc

Indexed keywords


EID: 67349174759     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.04.028     Document Type: Article
Times cited : (17)

References (30)
  • 19
    • 67349206428 scopus 로고    scopus 로고
    • note
    • 2O (14.9 mg, 0.05 mmol) and citric acid (7.0 mg, 0.033 mmol) in water (10 ml) was stirred for 20 min and the pH of the mixture was adjusted to 5.3 with dilute ammonium hydroxide. The mixture was heated in a water bath at 60 °C for about four days. During heating, a small amount of white floccule appeared from the mixture. The resulting mixture was cooled to room temperature and left standing for a couple of weeks to give colorless transparent prism crystalline product of 1 (73.2 mg, 77%). Positive identification of the crystalline product as 1 came from the IR spectrum and the X-ray unit-cell determinations carried out by single-crystal structural analysis.
  • 20
    • 67349162441 scopus 로고    scopus 로고
    • note
    • 2 = 0.090.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.