Square-planar d8 metal push-pull dithiolene complexes: Synthesis and characterization of [Pd(Me2pipdt)(dmit)]

Inorganic Chemistry Communications

Volumn 12, Issue 6, 2009, Pages 490-493

  Pilia, Luca ^a   Artizzu, Flavia ^a   Faulmann, Christophe ^b   Mercuri, Maria Laura ^a   Serpe, Angela ^a   Deplano, Paola ^a  

^a UNIVERSITY OF CAGLIARI   (Italy)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

Dithiolene; Mixed ligands; NLO chromophore; Pd; X ray

Indexed keywords

EID: 67349133672     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.04.001     Document Type: Article

References (32)

1. E.I. Stiefel (Ed.), Dithiolene Chemistry: Synthesis, Properties, and Applications, Progress in Inorganic Chemistry, vol. 52, John Wiley & Sons, 2004.
2. Tanaka H., Okano Y., Kobayashi H., Suzuki W., and Kobayashi A. Science 291 (2001) 285
3. Coomber A.T., Beljonne D., Friend R.H., Brédas J.K., Charlton A., Robertson N., Underhill A.E., Kurmoo M., and Day P. Nature 380 (1996) 144
4. Robertson N., and Cronin L. Coord. Chem. Rev. 227 (2002) 93
5. Coe B.J. In: McCleverty J.A., and Meyer T.J. (Eds). Comprehensive Coordination Chemistry II, vol. 9 (2004), Elsevier-Pergamon 621
6. Tan W.L., Ji W., Zuo J.L., Bai J.F., You X.Z., Lim Y.H., Yang S., Hagan D.J., and Van Stryland E.W. Appl. Phys. B 70 (2000) 809
7. Mueller-Westerhoff U.T. In: Wilkinson G. (Ed). Comprehensive Coordination Chemistry (1987), Pergamon Press, Oxford 595
8. Cummings S.D., and Eisenberg R. J. Am. Chem. Soc. 118 (1996) 1949
9. Vogler A., and Kunkely H. Angew. Chem., Int. Ed. Engl. 21 (1982) 77
10. Kato R., Kashimura Y., Sawa H., and Okano Y. Chem. Lett. (1997) 921
11. Curreli S., Deplano P., Faulmann C., Ienco A., Mealli C., Mercuri M.L., Pilia L., Pintus G., Serpe A., and Trogu E.F. Inorg. Chem. 43 (2004) 5069
12. -1, single crystals] 1524mw, 1455m, 1391m, 1348m, 1283m, 1259ms, 1138ms, 1044w, 936vw, 671vw, 542w, 514m, 472m, 450w, 424w, 383mw, 363ms, 335s.
13. Bigoli F., Chen C.-T., Deplano P., Mercuri M.L., Pellinghelli M.A., Pilia L., Pintus G., Serpe A., and Trogu E.F. Chem. Commun. (2001) 2246
14. Bigoli F., Deplano P., Mercuri M.L., Pellinghelli M.A., Pilia L., Pintus G., Serpe A., and Trogu E.F. Inorg. Chem. 41 (2002) 5241
15. Deplano P., Mercuri M.L., Marchiò M., Pilia L., Salidu M., Serpe A., Congiu F., and Sanna S. Eur. J. Inorg. Chem. (2005) 1829
16. 2 = 0.1011. The data were collected on a Stoe Imaging Plate Diffraction System (IPDS) equipped with an Oxford Cryosystems cooler device. The crystal-to-detector distance was 70 mm, 161 exposures (3.5 min per exposure) were obtained with 0 < φ{symbol} < 225° and with the crystals rotated through 1.4° in φ{symbol}. Crystal decay was monitored by measuring a maximum of 200 reflections per image. Cell parameters were obtained from 8000 reflections taken from the data measurements between 2° and 26°. The structure was solved by using direct methods (Sir97 [21]) and later refined by full-matrix least squares methods on F2 (Shelxl97 [22]). The calculations were carried out with the WINGX [23] programs package running on a PC. An absorption correction based on the multiscan method [24] was applied to the data set. The hydrogen atoms were introduced at their ideal positions and all of their parameters were refined. The structural drawings were generated by using the programs ORTEP [25] and CAMERON [26]. The atomic scattering factors were taken from the International Tables for X-ray Crystallography [27].
17. Mealli C., and Proserpio D.M. J. Chem. Educ. 67 (1990) 399
18. Geary E.A.M., Yellowlees L.J., Parsons S., Pilia L., Serpe A., Mercuri M.L., Deplano P., Clark S.J., and Robertson N. Dalton Trans. (2007) 5453
19. Makedonas C., and Mitsopoulou C.A. Inorg. Chim. Acta 360 (2007) 3997
20. Schläpfer C.W., and Nakamoto K. Inorg. Chem. 14 (1975) 1338
21. Wootton J.L., and Zink J.I. J. Phys. Chem. 99 (1995) 7251
22. Pokhodnya K.I., Faulmann C., Malfant I., Andreu-Solano R., Cassoux P., Mlayah A., Smirnov D., and Leotin J. Synth. Met. 103 (1999) 2016
23. Steimecke G., Sieler H.J., Kirmse R., and Hoyer E. Phosphorus Sulfur Relat. Elem. 7 (1979) 49
24. Altomare A., Burla M.C., Cavalli M., Cascarano G.L., Giacovazzo C., Gagliardi A., Moliterni A.G.G., Polidori G., and Spagna R. J. Appl. Crystallogr. 32 (1999) 115
25. G.M. Sheldrick, Institüt für Anorganische Chemie der Universität, Tammanstrasse 4, D-3400 Göttingen, Germany, 1997.
26. Farrugia L.J. J. Appl. Crystallogr. (1999) 837
27. Blessing R.H. J. Acta Crystallogr. Sect. A 51 (1995) 33
28. ORTEP-III, M.N. Burnett, C.K. Johnson, Report ORNL-6895, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 1996.
29. Farrugia L.J. J. Appl. Chem. 30 (1997) 565
30. Farrugia L.J. J. Appl. Chem. 32 (1999) 837
31. Watkin D.J., Prout C.K., and Pearce L.J. CAMERON, Chemical Crystallography Laboratory (1996), University of Oxford, Oxford, England
32. Cromer D.T., and Waber J.T. International Tables for X-ray Crystallography, vol. IV (1974), Kynoch Press, Birmingham, England