Inclusion polymerization of isoprene in deoxycholic acid

Radiation Physics and Chemistry

Volumn 78, Issue 5, 2009, Pages 338-344

  Cataldo, Franco ^a,b   Ragni, Pietro ^c   Rosati, Aldo ^c   Ursini, Ornella ^c  

^a Soc Lupi Chem Research Institute   (Italy)

^b Istituto Nazionale   (Italy)

^c CNR   (Italy)

Author keywords

Clathrates; Deoxycholic acid; Host guest compounds; Inclusion polymerization; Isoprene; Polyisoprene; Polymerization in clathrates; Supramolecular chemistry; Thiourea; Urea

Indexed keywords

CLATHRATES; DEOXYCHOLIC ACID; HOST-GUEST COMPOUNDS; INCLUSION POLYMERIZATION; ISOPRENE;

ACIDS; CHEMICAL REACTIONS; DYES; EMULSIFICATION; EMULSION POLYMERIZATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FREE RADICALS; HYDRATES; MACROMOLECULES; MELTING POINT; METABOLISM; MICROSTRUCTURE; MONOMERS; POLYMER MELTS; POLYMERS; STEELMAKING; SUPRAMOLECULAR CHEMISTRY; THERMOCHEMISTRY; THERMOGRAVIMETRIC ANALYSIS; THIOUREAS; UREA;

FREE RADICAL POLYMERIZATION;

DEOXYCHOLIC ACID; DEOXYCORTICOSTERONE ACETATE; FREE RADICAL; ISOPRENE; MONOMER; POLYMER; THIOUREA; UREA;

ARTICLE; CHEMICAL STRUCTURE; COMPARATIVE STUDY; CRYSTALLIZATION; DIFFERENTIAL SCANNING CALORIMETRY; EMULSION; INFRARED SPECTROSCOPY; MELTING POINT; POLYMERIZATION; RADIATION RESPONSE; THERMOGRAVIMETRY;

EID: 67349103390     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2009.01.008     Document Type: Article

References (24)

1. Allcock HR. Inclusion of polymers within the crystal structure of tris (o-phenylenedioxy) cyclotriphosphazene. Chem. Mater. 11 (1999) 1243-1252
2. Allcock H.R., Dudley G.K., and Silverberg E.N. Stereocontrolled polymerization of diene monomers within a tris (o-phenylenedioxy)cyclotriphosphazene tunnel clathrate. Macromolecules 27 (1994) 1039-1044
3. Allcock H.R., Silverberg E.N., Dudley G.K., and Pucher S.R. Inclusion polymerization within a Tris(2,3-naphthylenedioxy)cyclotriphosphazene clathrate. Macromolecules 27 (1994) 7550-7555
4. Barlow G.B., and Clamp A.C. Molecular complexes based on derivatives of 4,4′-dihydroxytriphenylmethane. J. Chem. Soc. 1961 (1961) 393-395
5. Bhatnagar V.M. Clathrate Compounds (1970), Chemical Publishing Co. Inc., New York
6. Brydson J.A. Rubber Chemistry (1978), Applied Science Publishers, London
7. Brown J.F., and White D.W. Stereospecific polymerization in thiourea canal complexes. J. Am. Chem. Soc. 82 (1960) 5671-5678
8. Cataldo F., Ursini O., and Lilla E. Radiation-induced polymerization of isoprene. A spectroscopic study. J. Radioanal. Nucl. Chem. 275 (2008) 9-16
9. Cataldo F., Ursini O., and Angelini G. Synthesis of highly cristalline poly(dimethylbutadiene) (PDMB) by radiation-induced inclusion polymerization: a comparison with PDMB synthesized by bulk and emulsion polymerization. Radiat. Phys. Chem. 77 (2008) 941-948
10. Cataldo F., Capitani D., Proietti N., and Ragni P. Gamma radiolyzed amorphous silica. A study with Si CP-MAS NMR spectroscopy. Radiat. Phys. Chem. 77 (2008) 267-272
11. Cataldo F., Ursini O., Lilla E., and Angelini G. Radiation-induced polymerization and grafting of β(-) pinene on silica surface. Radiat. Phys. Chem. 77 (2008) 561-570
12. Di Silvestro G., and Sozzani P. Polymerization in Clathrates. In: Allen G., and Bevington J.C. (Eds). Comprehensive Polymer Science vol. 4 (1989), Pergamon Press, Oxford 303-315
13. Di Silvestro G., Sozzani P., and Farina M. Regioselectivity in isoprene inclusion polymerization. Macromolecules 20 (1987) 999-1003
14. Ivanov V.S., Sokolova M.A., Aver'ianov S.V., Yevdokimov V.F., and Gurliand I.S. Radiation polymerization of isoprene. Polym. Sci. USSR 2 (1961) 199-202
15. Michishita T., Takashima Y., and Harada A. Complex formation between polyisoprene and cyclodextrins. Macromol. Rapid Commun. 25 (2004) 1159-1162
16. Miyata M. Inclusion polymerization. In: Salamone J.C. (Ed). Coincise Polymeric Materials Encyclopedia (1999), CRC Press, Boca Raton, FL 668-670
17. Miyata M., Kitahara Y., Osaki Y., and Takemoto K. Inclusion polymerization of various diene monomers in apocholic acid canals. J. Inclus. Phenom. 2 (1984) 391-398
18. Miyata M., Morioka K., and Takemoto K. Functional monomers and polymers-38, postirradiation polymerization of 2,3-dimethylbutadiene in deoxycholic acid canal complexes. J. Polym. Sci. Polym. Chem. Ed. 15 (1977) 2987-2996
19. Schilling F.C., Sozzani P., and Bovey F.A. Chain conformation and dynamics of crystalline 1,4-trans-polyisoprene and its inclusion compounds with perhydrotriphenylene. Macromolecules 24 (1991) 4369-4375
20. 13C-NMR spectra of methyl-substituted 1,4-trans-polybutadienes. 1. Method of assignment and spectra of some homopolymers. Macromolecules 17 (1984) 2532-2538
21. Steglich W., Fugmann B., and Lang-Fugmann S. Rompp Encyclopedia of Natural Products (2000), Georg Thieme Verlag, Stuttgart
22. Takemoto K., and Miyata M. Polymerization of vinyl and diene monomers in canal complexes. J. Macromol. Sci. Rev. Macromol. Chem. C 18 (1980) 83-107
23. Tonelli A.E. Conformational and motional characteristics of trans-1,4-diene polymers confined to channels. Macromolecules 23 (1990) 3129-3134
24. Vinogradova A.S., Faidysh A.N., Chechik L.Ye., and Chugai A.D. Effect of the polymerization process on the absorption spectrum of isoprene. Polym. Sci. USSR 9 (1967) 1457-1465