Study of cellulose/ethylene diamine/salt systems

Cellulose

Volumn 16, Issue 3, 2009, Pages 381-391

  Xiao, Min ^a   Frey, Margaret W ^a  

^a Cornell University ^*  (United States)

Author keywords

Cellulose dissolution; Conformation; Interaction; Mechanism scheme; NMR

Indexed keywords

BINARY-SOLVENT SYSTEMS; CELLOBIOSE; COMPLEX INTERACTIONS; CROSS-POLARIZATION/MAGIC ANGLE SPINNINGS; CRYSTALLINE POLYMORPHS; DIAMINOPROPANE; DIRECT INTERACTIONS; ETHANOLAMINE; ETHYLENE DIAMINES; HETERONUCLEAR SINGLE-QUANTUM COHERENCES; INTERACTION; MODEL COMPOUNDS; MODEL SYSTEMS; NMR; NMR SPECTROSCOPIES; OH GROUPS; SALT CONCENTRATIONS; SOLUTION COMPONENTS; SUB SYSTEMS; WIDE-ANGLE X-RAY DIFFRACTIONS;

AMINES; CELLULOSE; ETHYLENE; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLVATION; SOLVENTS;

DISSOLUTION;

AMINES; CELLULOSE; CONCENTRATION; DISSOLVING; ETHYLENE; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; SOLVATION; X RAY DIFFRACTION;

CELLULOSE; CHEMICAL ANALYSIS; CRYSTALLINE ORIENTATION; DISSOLUTION; SOLVENT;

EID: 67349086428     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10570-009-9284-2     Document Type: Article

References (28)

1. Atalla RH, Vanderhart DL (1984) Native cellulose - a composite of 2 distinct crystalline forms. Science 223:283-285
2. Atalla RH, Gast JC, Sindorf DW, Bartuska VJ, Maciel GE (1980) C-13 Nmr-spectra of cellulose polymorphs. J Am Chem Soc 102:3249-3251
3. Barry AJ, Peterson FC, King AJ (1936) X-ray studies of reactions of cellulose in non-aqueous systems. I. Interaction of cellulose and liquid ammonia. J Am Chem Soc 58:333-337
4. Brendler E, Fischer S, Leipner H (2001) Li-7 NMR as probe for solvent-cellulose interactions in cellulose dissolution. Cellulose 8:283-288. doi: 10.1023/A:1015120107514
5. Cadars S, Lesage A, Emsley L (2005) Chemical shift correlations in disordered solids. J Am Chem Soc 127:4466-4476
6. Chen XM, Burger C, Fang DF, Ruan D, Zhang L, Hsiao BS, Chu B (2006) X-ray studies of regenerated cellulose fibers wet spun from cotton linter pulp in NaOH/thiourea aqueous solutions. Polymer 47:2839-2848
7. Cuculo JA, Smith CB, Sangwatanaroj U, Stejskal EO, Sankar SS (1994) A study on the mechanism of dissolution of the cellulose/Nh3/Nh4scn system.1. J Polym Sci Part A Polym Chem 32:229-239
8. Davis WE, Barry AJ, Peterson FC, King AJ (1943) X-ray studies of reactions of cellulose in non-aqueous systems. II. Interaction of cellulose and primary amines. J Am Chem Soc 65:1294-1299
9. Degroot AW, Guinnup DE, Theil MH, Cuculo JA (1991a) Light-scattering-studies on solutions of cellulose in the ammonia ammonium thiocyanate solvent system.1. Classical light-scattering. J Polym Sci Part B-Polym Phys 29:547-556
10. Degroot AW, Guinnup DE, Thiel MH, Cuculo JA (1991b) Light-scattering-studies on solutions of cellulose in the ammonia ammonium thiocyanate solvent system.2. Quasi-elastic light-scattering and liquid-crystal study. J Polym Sci Part B-Polym Phys 29:557-563
11. Dudley RL, Fyfe CA, Stephenson PJ, Deslandes Y, Hamer GK, Marchessault RH (1983) High-resolution C-13 Cp/Mas Nmr-spectra of solid cellulose oligomers and the structure of cellulose-Ii. J Am Chem Soc 105:2469-2472. doi: 10.1021/ja00346a059
12. Frey MW, Li L, Xiao M, Gould T (2006) Dissolution of cellulose in ethylene diamine/salt solvent systems. Cellulose 13:147-155
13. Henrissat B, Marchessault RH, Taylor MG, Chanzy H (1987) A solid-state C-13 Nmr-study of the cellulose-I-ethylenediamine complex. Polym Commun (Guildf) 28:113-115
14. Homans SW (1990) Oligosaccharide conformations - application of Nmr and energy calculations. Prog Nucl Magn Reson Spectrosc 22:55-81
15. Isogai A, Usuda M, Kato T, Uryu T, Atalla RH (1989) Solid-state Cp Mas C-13 Nmr-study of cellulose polymorphs. Macromolecules 22:3168-3172
16. Lehninger AL, Nelson DL, Cox MM (2005) Lehninger principles of biochemistry. W.H. Freeman, New York
17. Leipner H, Fischer S, Brendler E, Voigt W (2000) Structural changes of cellulose dissolved in molten salt hydrates. Macromol Chem Phys 201:2041-2049
18. Maciel GE, Kolodziejski WL, Bertran MS, Dale BE (1982) C-13 Nmr and order in cellulose. Macromolecules 15:686-687
19. Moulthrop JS, Swatloski RP, Moyna G, Rogers RD (2005) High-resolution C-13 NMR studies of cellulose and cellulose oligomers in ionic liquid solutions. Chem Commun 1557-1559
20. Nakamura K, Hatakeyama T, Hatakeyama H (1981) Studies on bound water of cellulose by differential scanning calorimetry. Text Res J 51:607-613
21. Nehls I, Wagenknecht W (1994) Application of the high-resolution liquid Nmr-spectroscopy in cellulose research. Papier 48:749-755
22. Nehls I, Wagenknecht W, Philipp B, Stscherbina D (1994) Characterization of cellulose and cellulose derivatives in solution by high-resolution C-13-Nmr spectroscopy. Prog Polym Sci 19:29-78. doi: 10.1016/ 0079-6700(94)90037-X
23. Pionteck H, Berger W, Morgenstern B, Fengel D (1996) Changes in cellulose structure during dissolution in LiCl: N, N -dimethylacetamide and in the alkaline iron tartrate system EWNN. 1. Electron microscopic studies on changes in cellulose morphology. Cellulose 3:127-139. doi: 10.1007/BF02228796
24. Roder T, Morgenstern B, Schelosky N, Glatter O (2001) Solutions of cellulose in N,N-dimethylacetamide/lithium chloride studied by light scattering methods. Polymer 42:6765-6773
25. Ruan D, Zhang LN, Zhou JP, Jin HM, Chen H (2004) Structure and properties of novel fibers spun from cellulose in NaOH/thiourea aqueous solution. Macromol Biosci 4:1105-1112
26. Striegel AM (2003) Advances in the understanding of the dissolution mechanism of cellulose in DMAc/LiCl. J Chil Chem Soc 48:73-77
27. Terbojevich M, Cosani A, Conio G, Ciferri A, Bianchi E (1985) Mesophase formation and chain rigidity in cellulose and derivatives.3. Aggregation of cellulose in N,N-dimethylacetamide lithium-chloride. Macromolecules 18:640-646
28. Xiao M, Frey MW (2007) The role of salt on cellulose dissolution in ethylene diamine/salt solvent systems. Cellulose 14:225-234