Synthesis and properties of acyclic ammonium-based ionic liquids with allyl substituents as electrolytes

Molecules

Volumn 14, Issue 5, 2009, Pages 1840-1851

  Taeeun, Yim ^a   Chang, Young Choi ^a   Junyoung, Mun ^a   Seung, M Oh ^a   Young, Gyu Kim ^a  

^a Seoul National University   (South Korea)

Author keywords

Allyl substituent; Ammonium; Battery electrolyte; Bis(trifluoromethanesulfonyl)imide (tfsi); Ionic liquid

Indexed keywords

ELECTROLYTE; IONIC LIQUID; ORGANIC COMPOUND; QUATERNARY AMMONIUM DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROCHEMISTRY; SYNTHESIS; TEMPERATURE;

ELECTROCHEMISTRY; ELECTROLYTES; IONIC LIQUIDS; MOLECULAR STRUCTURE; ORGANIC CHEMICALS; QUATERNARY AMMONIUM COMPOUNDS; TEMPERATURE;

EID: 67249132087     PISSN: None     EISSN: 14203049     Source Type: Journal    
DOI: 10.3390/molecules14051840     Document Type: Article

References (16)

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14. To the best of our knowledge, there are no literature precedents of the use of diallyldimethylammonium bis(trifluoromethanesulfonyl)imide ([AAMM]Am-TFSI, CAS No. 521942-10-9) as an electrolyte, although there have been several patents employing it as an additive for its antistatic or antimicrobial properties. There have been also some reports utilizing poly(diallyldimethylammonium bis(trifluoromethanesulfonyl)imide) as an electrolyte that consists of a cyclic N, N-dimethylpyrrolidinium structure instead of the acyclic diallyldimethylammonium ([AAMM]Am) structure. The N,N-dimethylpyrrolidinium structure is derived from polymerization of a bifunctional monomer of the diallyldimethylammonium cation. Diallyldimethylammonium chloride (CAS No. 7398-69-8) and poly(diallyldimethylammonium chloride) (CAS No. 26062-79-3) are commercially available.
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16. 6 and Tetraglyme. Electrochem. Solid-State Lett. 2004, 7, A254-A255.