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Some previous analyses (ref 27) of NMR shifts due to diamagnetic- paramagnetic equilibria replace the isotropic hyperfine coupling constant a with a/2S. Equation (2) is as used in ref 27(g).
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Some previous analyses (ref 27) of NMR shifts due to diamagnetic- paramagnetic equilibria replace the isotropic hyperfine coupling constant a with a/2S. Equation (2) is as used in ref 27(g).
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43
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84868999966
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2 according to eq 2 gives a much superior fit to the data (see Supporting Information) than docs a fit to inverse temperature.
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2 according to eq 2 gives a much superior fit to the data (see Supporting Information) than docs a fit to inverse temperature.
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44
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67149143052
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Hyperfine coupling constants are also affected by solvent but the variations are not large
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Hyperfine coupling constants are also affected by solvent but the variations are not large.
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