Hydrothermal synthesis of Titanium silicalite-1 structurally directed by hexamethyleneimine

Industrial and Engineering Chemistry Research

Volumn 48, Issue 9, 2009, Pages 4334-4339

  Zhang, Haijiao ^a,b   Liu, Yueming ^a   Jiao, Zheng ^b   He, Mingyuan ^a   Wu, Peng ^a  

^a EAST CHINA NORMAL UNIVERSITY   (China)

^b SHANGHAI UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

BORON ADDITIONS; COOPERATIVE EFFECTS; CRYSTALLIZATION PROCESS; CRYSTALLIZATION TIME; PHYSICOCHEMICAL PROPERTY; PREPARATION CONDITIONS; SECONDARY BUILDING UNITS; STRUCTURE DIRECTING AGENTS; SYNERGISTIC EFFECT; SYNTHESIS PARAMETERS; TITANIUM ATOMS; TITANIUM SILICALITE-1;

BORON; BORON COMPOUNDS; CRYSTALLIZATION; GELATION; METAL IONS; SILICATE MINERALS; TITANIUM; ZEOLITES;

HYDROTHERMAL SYNTHESIS;

EID: 67049160668     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie8016253     Document Type: Article

References (31)

1. Taramasso, M. Perego, G. Notari, B. Preparation of porous crystalline synthetic material comprised of silicon and titanium oxide. U. S. Patent 4, 410, 501, 1983.
2. van der Pol, A. J. H. P.; Verduyn, A. J.; Van Hooff, J. H. C. Why are some titanium silicalite-1 samples active and others not. Appl. Catal. A 1992, 92, 113-130.
3. Clerici, M. G.; Bellussi, G.; Romano, U. Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite. J. Catal. 1991, 129, 159-167.
4. Roffia, P.; Leofanti, G.; Cesana, A.; Mantegazza, M. Cyclohexanone ammoximation: A breakthrough in the 6-caprolactam production process. Stud. Surf. Sci. Catal. 1990, 55, 43-48.
5. Huybrechts, D. R. C; De Bruycker, L.; Jacobs, P. A. Oxyfunctionalization of alkanes with hydrogen peroxide on titanium silicalite. Nature (London) 1990, 345, 240-242.
6. Thiele, G. F.; Roland, E. Propylene epoxidation with hydrogen peroxide and titanium silicalite catalyst: Activity, deactivation and regeneration of the catalyst. J. Mol. Catal. A: Chem. 1997, 117, 351-356.
7. Fan, W. B.; Duan, R. G.; Yokoi, T.; Wu, P.; Kubota, Y.; Tatsumi, T. Synthesis, crystallization mechanism, and catalytic properties of titaniumrich TS-1 free of extraframework titanium species. J. Am. Chem. Soc. 2008, 130, 10150-10164.
8. Khouw, C. B.; Davis, M. E. Catalytic activity of titanium silicates synthesized in the presence of alkali met al. and alkaline earth ions. J. Catal. 1995, 151, 77-86.
9. Bellussi, G.; Rigutto, M. S. Met al. ions associated to the molecular sieve framework: Possible catalytic oxidation sites. Stud. Surf. Sci. Catal. 1994, 85, 177-213.
10. Tuel, A. Crystallization of titanium silicalite-1 (TS-1) from gels containing hexanediamine and tetrapropylammonium bromide. Zeolites 1996, 16, 108-117.
11. Guo, X.; Li, G.; Wang, X. S.; Zhou, Z. H. Research on UV-vis spectra of titanium silicalite. J. Dalian Univ. Technol. 1998, 38, 359-362.
12. Shibata, M.; Gerard, J.; Gabelica, Z. Exploration of non conventional routes to synthesize MFI type titano- and (boro-titano) - zeolites. Stud. Surf. Sci. Catal. 1997, 105, 245-252.
13. Tuel, A. Crystallization of titanium silicalite-1 from gels containing hexanediamine and tetrapropylammonium bromide. Stud. Surf. Sci. Catal. 1997, 105, 261-268.
14. Xia, Q. H.; Gao, Z. Crystallization kinetics of pure TS-1 zeolite using quaternary ammonium halides as templates. Mater. Chem. Phys. 1997, 47, 225-230.
15. Popa, J. M. Guth, J. L. Kessler, H. Non-hydrothermal method of making a titanium-containing zeolite. European Patent EP 292 363, 1988.
16. Grieneisen, J. L.; Kessler, H.; Fache, E.; Le Govic, A. M. Synthesis of TS-1 in fluoride medium. A new way to a cheap and efficient catalyst for phenol hydroxylation. Microporous Mesoporous Mater. 2000, 37, 379-386.
17. Saxton, R. J.; Zajacek, J. G. Non-hydrothermal method of making a titanium-containing zeolite. U. S. Patent 5, 688, 484, 1997.
18. Zhang, H. J.; M Liu, Y.; Wu, H. H.; Jiang, Y. W.; Chen, L.; He, M. Y.; Wu, P. Hydrothermal synthesis of hexamethyleneimine-templated TS-1 titanosilicate supported by active seeds. Chem. Lett. 2006, 35, 1276-1277.
19. Thangaraj, A.; Eapan, M. J.; Sivasanker, S.; Ratnasamy, R. Studies on the synthesis of titanium silicalite TS-1. Zeolites 1992, 12, 943-950.
20. Leonowicz, M. E.; Lawton, J. A.; Lawton, S. L. A molecular sieve with two independent multidimensional channel systems. Science 1994, 264, 1910-1913.
21. Wu, P.; Tatsumi, T.; Komatsu, T.; Yashima, T. A novel titanosilicate with MWW structure: I. Hydrothermal synthesis, elimination of extraframework titanium and characterizations. J. Phys. Chem. B 2001, 105, 2897-2905.
22. Yamamoto, K.; Plévert, J.; Uneme, M.; Tatsumi, T. Synthesis, characterization, and catalysis of UTM-1: An MTF type zeolite composed of the same building unit as MFI type zeolites. Microporous Mesoporous Mater. 2002, 55, 81-91.
23. David, P. S.; Aguado, J.; Escola, J. M.; Rodríguez, J. M.; Peral, Á. Hierarchical zeolites with enhanced textural and catalytic properties synthesized from organofuncionalized seeds. Chem. Mater. 2006, 18, 2462-2464.
24. Li, G.; Guo, X. W.; Wang, X. S.; Zhao, Q.; Han, X. W.; Lin, L. W. Synthesis of TS-1 in TPABr-TEAOH system and its characterization and catalytic performance. Chin. J. Catal. 1998, 19, 371-374.
25. Cheng, M.; Tan, D. L.; Liu, X. M.; Han, X. W.; Bao, X. H.; Lin, L. W. Effect of aluminum on the formation of zeolite MCM-22 and kenyaite. Microporous Mesoporous Mater. 2001, 42, 307-316.
26. 13C N. M. R. spectroscopy. J. Chem. Soc. Chem. Commun. 1982, 264-265.
27. Zhao, Q.; Bao, X. H.; Guo, X. W.; Li, G.; Wang, X. S. Studies on the cryatallization process of titanium silicalite-1 (TS-1) synthesized using tetrapropylammonium bromide as a template. Mater. Chem. Phys. 2000, 66, 41-50.
28. Thangagraj, A.; Kumar, R.; Mirajkar, S. P. Properties of crystalline titanium silicates. J. Catal. 1991, 130, 1-8.
29. Vayssilov, G. N. Structural and physicochemical features of titanium silicalites.Catal. Rev. -Sci. Eng. 1997, 39, 209-251.
30. Blasco, T.; Camblor, M. A.; Corma, A.; Perez-Pariente, J. The state of Ti in titanoaluminosilicates isomorphous with zeolite beta. J. Am. Chem. Soc. 1993, 115, 11806-11813.
31. Freyhardt, C. C; Tsapatsis, M.; Lobo, R. F.; Balkus, K. J., Jr.; Davis, M. E. A high-silica zeolite with a 14-tetrahedral-atom pore opening. Nature (London) 1996, 381, 295-298.