Dissecting enthalpic and entropie barriers to ultrafast equilibrium isomerization of a flexible molecule using 2DIR chemical exchange spectroscopy

Journal of Physical Chemistry A

Volumn 113, Issue 24, 2009, Pages 6544-6547

  Anna, Jessica M ^a   Ross, Matthew R ^a   Kubarych, Kevin J ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; CHEMICAL EXCHANGE; DICOBALT OCTACARBONYL; DYNAMIC EQUILIBRIA; ENTROPIC CONTRIBUTIONS; EYRING EQUATION; FLEXIBLE MOLECULES; PICOSECONDS; QUANTUM CHEMICAL CALCULATIONS; SPECTRAL FEATURE; TEMPERATURE DEPENDENCE; TIME-SCALE; TRANSITION STATE; ULTRA-FAST; WAITING-TIME;

ELECTRON TRANSITIONS; ENERGY BARRIERS; ISOMERIZATION; QUANTUM CHEMISTRY; RATE CONSTANTS;

ISOMERS;

COBALT; DICOBALT OCTACARBONYL;

CHEMISTRY; INFRARED SPECTROSCOPY; ISOMERISM; KINETICS; LETTER; METHODOLOGY; THERMODYNAMICS;

COBALT; ISOMERISM; KINETICS; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; THERMODYNAMICS;

EID: 67049133177     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp903112c     Document Type: Article

References (21)

1. Woutersen, S.; Mu, Y.; Stock, G.; Hamm, P. Chem. Phys. 2001, 266, 137-147.
2. Zheng, J. R.; Kwak, K.; Asbury, J.; Chen, X.; Piletic, I. R.; Fayer, M. D. Science 2005, 309, 1338-1343.
3. Kim, Y. S.; Hochstrasser, R. M. Proc. Natl. Acad. Sci. U.S.A. 2005, 102, 11185-11190.
4. Zheng, J. R.; Kwak, K. W.; Xie, J.; Fayer, M. D. Science 2006, 313, 1951-1955.
5. Ishikawa, H.; Kwak, K; Chung, J. K.; Kim, S.; Fayer. M. D Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 8619-8624.
6. Kim, Y. S.; Hochstrasser, R. M. J. Phys. Chem. B 2007, 111, 96979701.
7. Cahoon, J. F.; Sawyer, K. R.; Schlegel, J. P.; Harris, C. B. Science 2008, 319, 1820-1823.
8. Kim, Y. S.; Liu, L.; Axelsen, P. H.; Hochstrasser, R. M Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 7720-7725.
9. Tannenbaum, R.; Bor, G. J. Organomet. Chem. 1999, 586, 18-22.
10. Chung, Y. K. Crood Chem. Rev. 1999, 188, 297-341.
11. Sweany, R. L.; Brown, T. L. Inorg. Chem. 1977, 17, 415-421.
12. Kenny, J. P.; King, R. B.; Schaefer, H. F. Inorg. Chem. 2001, 40, 900-911.
13. Aullón, G.; Alvarez, S. Eur J. Inorg. Chem. 2001, 2001, 30313038.
14. Jonas, D. M. Annu. Rev. Phys. Chem. 2003, 54, 425-463.
15. Cho, M. H. Chem. Rev. 2008, 108, 1331-1418.
16. Nee, M. J.; Baiz, C. R.; Anna, J. M.; McCanne, R.; Kubarych, K. J. J. Chem. Phys. 2008, 129, 084503.
17. Nee, M. J.; McCanne, R.; Kubarych, K. J.; Joffre, M. Opt. Lett. 2007, 32, 713-715.
18. Baiz, C. R.; Nee, M. J.; McCanne, R.; Kubarych, K. J. Opt Lett. 2008, 33, 2533-2535.
19. Khalil, M.; Demirdoven, N.; Tokmakoff, A. J. Chem. Phys. 2004, 121, 362-373.
20. Flom, S. R.; Nagarajan, V.; Barbara, P. F. J. Phys. Chem. 1986, 90, 2085-2092.
21. Schmidt, M. W.; Baldridge, K. K.; Boatz, J. A.; Elbert, S. T.; Gordon, M. S.; Jensen, J. H.; Koseki, S.; Matsunaga, N.; Nguyen, K. A.; Su, S. J.; Windus, T. L.; Dupuis, M.; Montgomery, J. A. J. Comput. Chem. 1993, 14, 1347-1363.