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complex formed with VTMS and TBE. Equilibrium constants for alkene coordination to (MeC5H 4)2Zr+(OtBu)ClCD2Cl
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66749109278
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13C NMR spectra of the polymers resulting from the copolymerization of 1-hexene with TBE/VTMS are shown in the Supporting Information.
-
13C NMR spectra of the polymers resulting from the copolymerization of 1-hexene with TBE/VTMS are shown in the Supporting Information.
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43
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66749184064
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14 These observations suggest that the partial decomposition of the active species in the polymerization system might have led to the generation of two catalytically active species.
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14 These observations suggest that the partial decomposition of the active species in the polymerization system might have led to the generation of two catalytically active species.
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44
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66749126675
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3 from ordinary MAO), 3.0 mmol; 25 °C.; 60 min.]
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3 from ordinary MAO), 3.0 mmol; 25 °C.; 60 min.]
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3 from ordinary MAO), 3.0 mmol; 25 °C.; 30 min.]
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3 from ordinary MAO), 3.0 mmol; 25 °C.; 30 min.]
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50
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66749089771
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The results regarding the geometry optimization of the proposed catalytically active species and their energy evaluation have been reported in the Supporting Information of the previous communication.10
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