Pd-supported catalysts: Evolution of support porous texture along Pd deposition and alkali-metal doping

Langmuir

Volumn 25, Issue 11, 2009, Pages 6476-6485

  Pellegrini, R ^a   Leofanti, G ^a,c   Agostini, G ^b   Groppo, E ^b   Rivallan, M ^b,d   Lamberti, C ^b  

^a Chimet SpA Catalyst Division   (Italy)

^b UNIVERSITY OF TURIN   (Italy)

^c Consultant ^*  (Italy)

^d EPFL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONATE CONCENTRATIONS; DOPED SAMPLE; HIGH PLASTICITY; METAL-DOPING; MICROSCALE LEVELS; PD PARTICLE; PD-SUPPORTED CATALYSTS; PORE COLLAPSE; PORE NARROWING; POROUS STRUCTURES; POROUS TEXTURE; POTASSIUM CARBONATES; PRECIPITATING AGENTS; SUPPORT MORPHOLOGY; SUPPORTED PD CATALYSTS; THERMAL TREATMENT; TOTAL COLLAPSE;

ACTIVATED CARBON; ADSORPTION; ALUMINUM; CARBONATION; CATALYSIS; CATALYST SUPPORTS; DISSOLUTION; DOPING (ADDITIVES); METAL RECOVERY; METAL REFINING; POTASH; POTASSIUM; SCANNING ELECTRON MICROSCOPY; SILICON COMPOUNDS; SIMULATED ANNEALING; SINTERING; SURFACE PROPERTIES;

PALLADIUM;

EID: 66749088078     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la900084p     Document Type: Article

References (55)

1. Wiersma, A.; van de Sandt, E. J. A. X.; den Hollander, M. A.; van Bekkum, H.; Makkee, M.; Moulijn, J. A. J. Catal. 1998, 177, 29-39.
2. Panagiotopoulou, P.; Kondarides, D. I. Catal Today 2006, 112, 49-52.
3. Hegedus, L.; Mathe, T.; Tungler, A. Appl. Catal., A 1996, 147, 407-414.
4. Bernas, A.; Kumar, N.; Mäki-Arvela, P.; Kul'kova, N. V.; Holmbom, B.; Salmi, T.; Murzin, D. Y. Appl Catal., A 2003, 245, 257-275.
5. van de Sandt, E. J. A. X.; Wiersma, A.; Makkee, M.; van Bekkum, H.; Moulijn, J. A. Appl Catal. A 1998, 173, 161-173.
6. Pinna, F.; Menegazzo, F.; Signoretto, M.; Canton, P.; Fagherazzi, G.; Pernicone, N. Appl Catal., A 2001, 219, 195-200.
7. Cizmeci, M.; Musavi, A.; Tekin, A.; Kayahan, M. J. Am. Oil Chem. Soc. 2006, 83, 1063-1068.
8. Markus, H.; Plomp, A. J.; Maki-Arvela, P.; Bitter, J. H.; Murzin, D. Y. Catal Lett. 2007, 113, 141-146.
9. Venezia, A. M.; La Parola, V.; Pawelec, B.; Fierro, J. L. G. Appl. Catal. A 2004, 264, 43-51.
10. Ruta, M.; Semagina, N.; Kiwi-Minsker, L. J. Phys. Chem. C 2008, 112, 13635-13641.
11. Min, K.-I.; Choi, J.-S.; Chung, Y.-M.; Ahn, W.-S.; Ryoo, R.; Lim, P. K. Appl Catal. A 2008, 337, 97-104.
12. Okhlopkova, L. B.; Lisitsyn, A. S.; Likholobov, V. A.; Gurrath, M.; Boehm, H. P. Appl. Catal. A 2000, 204, 229-240.
13. Brunelle, J. P. Pure Appl Chem. 1978, 50, 1211-1229.
14. Bernal, S.; Calvino, J. J.; López-Cartes, C.; Pintado, J. M.; Pérez-Omil, J. A.; Rodríguez-Izquierdo, J. M.; Hayek, K.; Rupprechter, G. Catal Today 1999, 52, 29-43.
15. Balint, I.; Miyazaki, A.; Aika, K. Chem. Mater. 2001, 13, 932-938.
16. Shah, A. M.; Regalbuto, J. R. Langmuir 1994, 10, 500-504.
17. Bossi, A.; Leofanti, G.; Moretti, E.; Giordano, N. J. Mater. Sci. 1973, 8, 1101-1109.
18. Guo, S.-L.; Arai, M.; Nishiyama, Y. Appl Catal 1990, 65, 31-44.
19. Arai, H.; Machida, M. Appl. Catal., A 1996, 138, 161-176.
20. Yu, J. G.; Yu, J. C.; Ho, W. K.; Leung, M. K. P.; Cheng, B.; Zhang, G. K.; Zhao, X. J. Appl. Catal., A 2003, 255, 309-320.
21. Mercera, P. D. L.; Vanommen, J. G.; Doesburg, E. B. M.; Burggraaf, A. J.; Ross, J. R. H. Appl Catal. 1990, 57, 127-148.
22. Liu, S.-B.; Wu, J.-F.; Ma, L.-J.; Tsai, T.-C.; Wang, I. J. Catal. 1991, 132, 432-439.
23. Ponec, V. Appl. Catal. A 1997, 149, 27-48.
24. Murata, S.; Aika, K.-I. J. Catal. 1992, 136, 110-117.
25. Pinxt, H. H. C. M.; Kuster, B. F. M.; Marin, G. B. Appl. Catal., A 2000, 191, 45-54.
26. Neri, G.; Visco, A. M.; Donato, A.; Milone, C.; Malentacchi, M.; Gubitosa, G. Appl. Catal., A 1994, 110, 49-59.
27. Scire, S.; Crisafulli, C.; Maggiore, R.; Minico, S.; Galvagno, S. Appl. Surf. Sci. 1996, 93, 309-316.
28. Scirè, S.; Minicò, S.; Crisafulli, C. Appl. Catal., A 2002, 235, 21-31.
29. Mahata, N.; Raghavan, K. V.; Vishwanathan, V. Appl. Catal., A 1999, 182, 183-187.
30. Pillai, U. R.; Sahle-Demessie, E. Appl. Catal., A 2005, 281, 31-38.
31. Park, Y. H.; Price, G. L. Ind. Em. Chem. Res. 1992, 31, 469-474.
32. Gusovius, A. F.; Watling, T. C.; Prins, R. Appl. Catal., A 1999, 188, 187-199.
33. Kazi, A. M.; Chen, B.; Goodwin, J. G.; Marcelin, G.; Rodriguez, N.; Baker, T. K. J. Catal. 1995, 157, 1-13.
34. Gusovius, A. F.; Prins, R. J. Catal. 2002, 211, 273-277.
35. Mercera, P. D. L.; Vanommen, J. G.; Doesburg, E. B. M.; Burggraaf, A. J.; Ross, J. R. H. Appl. Catal. 1991, 71, 363-391.
36. Agostini, G.; Pellegrini, R.; Leofanti, G.; Bertinetti, L.; Bertarione, S.; Groppo, E.; Zecchina, A.; Lamberti, C. J. Phys. Chem. C, submitted for publication, 2009.
37. Pellegrini, R.; Leofanti, G.; Agostini, G.; Bertinetti, L.; Bertarione, S.; Groppo, E.; Zecchina, A.; Lamberti, C. J. Catal., submitted for publication, 2009.
38. Geus, J. W.; van Dillen, A. J. Preparation of supported catalysts by deposition-precipitation. In Handbook of Heterogeneous Catalysis; Ertl, G., Knözinger, H., Weitkamp, J., Eds.; Wiley-VCH: Weinheim, Germany, 1997; Vol. 1, pp 240-257.
39. Simonov, P. A.; Likholobov, V. A. Physicochemical aspects of preparation of carbon-supported noble metal catalysts. In Catalysis and Electrocatalysis at Nanoparticle Surfaces; Wieckowski, A., Savinova, E. R., Vayenas, C. G., Eds.; Marcel Dekker, Inc.: New York, 2003; pp 409-454.
40. Menegazzo, F.; Fantinel, T.; Signoretto, M.; Pinna, F. Catal. Commun. 2007, 8, 876-879.
41. Gregg, S. J.; Sing, K. S. W. Adsorption, Surface Area and Porosity, 2nd ed.; Academic Press, Inc.: New York, 1982.
42. Rouquerol, F.; Rouquerol, J.; Sing, K. Adsorption by Powders & Porous Solids. Principles, Methodology and Applications', Academic Press: New York, 1999.
43. norm = Wt(873)/[1 - ΔWt].
44. Prelazzi, G.; Cerboni, M.; Leofanti, G. J. Catal. 1999, 181, 73-79.
45. Considering the simplest model of pores, i.e., cylindrical blind pores, if carbonate is spread on the walls of the pores, their diameter decreases, causing a decrease of volume equal to the volume of salt and proportional to decrease of the diameter. If the carbonate occupies the bottom of the blind pores, the pore diameter does not change, and the volume decrease is still equal to the volume of salt. If the "cap" is over the bottom of the pores, the diameter does not change, and the closer the "cap" is to the pore mouth, the bigger the volume decrease.
46. p. There is neither information available in order to understand the origin of such micropores (probably localized etching), nor indications that their presence nullifies the reported findings, so, in the following, this fact will no longer be discussed.
47. 2O) sample (180) lies between the values of the unwashed PdK20 sample (199) and the samples with lower K content (152-163).
48. The decomposed fraction is roughly 80% in the PdK4 sample and 30% in the PdK20 one.
49. Büchel, K. H.; Moretto, H.-H.; Woditsch, P. Silicate products. In Industrial Inorganic Chemistry; Wiley-VCH: Weinheim, Germany, 2000; pp 325-350.
50. Randall, M. G. Sintering Theory and Practice; Wiley-Interscience: New York, 1996.
51. Lehman, R. L.; Gentry, J. S.; Glumac, N. G. Thermochim. Acta 1998, 316, 1-9.
52. Busca, G.; Lorenzelli, V. Mater. Chem. 1982, 7, 89-126.
53. Tauster, S. I.; Fung, S. C.; Garten, R. L. J. Am. Chem. Soc. 1978, 100, 170-175.
54. Tauster, S. J. Acc. Chem. Res. 1987, 20, 389-394.
55. Bernal, S.; Calvino, J. J.; Cauqui, M. A.; Gatica, J. M.; López Cartes, C.; Perez Omil, J. A.; Pintado, J. M. Catal Today 2003, 77, 385-406.