Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds

Journal of Organometallic Chemistry

Volumn 694, Issue 15, 2009, Pages 2395-2401

  Fuge, Felix ^a   Lehmann, Christian W ^b   Rust, Jörg ^b   Mohr, Fabian ^a  

^a UNIVERSITY OF WUPPERTAL   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

Bifunctional ligands; Bridge cleavage; Cyclometallation; N donor ligands; Palladium

Indexed keywords

8-HYDROXYQUINOLINE; ACETYLACETONE; BIFUNCTIONAL LIGANDS; CLEAVAGE REACTION; CYCLOMETALLATION; DISPROPORTIONATION REACTIONS; DITHIOCARBAMATES; HIGH YIELD; MONOCATIONIC COMPLEXES; N-DONOR LIGANDS; PALLADACYCLE; RELATED COMPOUNDS; THIOAMIDES;

ACETONE; DYES; LIGANDS; ORGANOMETALLICS; PALLADIUM; THIOUREAS; UREA;

PALLADIUM COMPOUNDS;

EID: 66449132884     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2009.03.026     Document Type: Article

References (23)

1. In: Dupont J., and Pfeffer M. (Eds). Palladacycles (2008), Wiley-VCH, Weinheim
2. Spencer J., and Pfeffer M. Adv. Met.-Org. Chem. 6 (1998) 103
3. Dupont J., Consorti C.S., and Spencer J. Chem. Rev. 105 (2005) 2527
4. Dupont J., Pfeffer M., and Spencer J. Eur. J. Inorg. Chem. (2001) 1917
5. Herrmann W.A., Böhm V.P.W., and Reisinger C.P. J. Organomet. Chem. 576 (1999) 23
6. Bedford R.B. Chem. Commun. (2003) 1787
7. Beletskaya I.P., and Cheprakov A.V. J. Organomet. Chem. 689 (2004) 4055
8. Narayan S., Jain V.K., and Butcher R.J. J. Organomet. Chem. 549 (1997) 73
9. Pugliese T., Godbert N., Aiello I., Ghedini M., and La Deda M. Inorg. Chem. Commun. 9 (2006) 93
10. Albinati A., Affolter S., and Pregosin P.S. J. Organomet. Chem. 395 (1990) 231
11. Bruce J.C., and Koch K.R. Acta Crystallogr. C 64 (2008) m1
12. Domínguez M., Anticó E., Beyer L., Aguirre A., García-Granda S., and Salvadó V. Polyhedron 21 (2002) 1429
13. Kampf M., Richter R., Gerber S., and Kirmse R. Z. Anorg. Allg. Chem. 630 (2004) 1437
14. The C{double bond, long}S and C{double bond, long}O distance is the average of 40 occurrences of the acyl-thiourea fragment and the C{double bond, long}Se distance is the average of four entries found in the CSD, Ver. 5.30 (November 2008 + 2 Updates).
15. Constable A.G., McDonald W.S., and Shaw B.L. J. Chem. Soc., Dalton Trans. (1980) 2282
16. Beurskens P.T., Cras J.A., Hummelink T.W., and Noordik J.H. J. Chem. Crystallogr. 1 (1971) 253
17. Bondi A. J. Phys. Chem. 68 (1964) 441
18. * a rotation axis passing through the midpoints of the C-N bonds and the central palladium atom has been defined. One part of the molecule was rotated around this axis and the O⋯O and H⋯H distances were monitored.
19. Douglas I.B. J. Am. Chem. Soc. 59 (1937) 740
20. Otwinowski Z., and Minor W. In: Carter Jr. C.W., and Sweet R.M. (Eds). Methods in Enzymology vol. 276 (1997), Academic Press, New York 307
21. G.M. Sheldrick, shelxs-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
22. G.M. Sheldrick, shelxl-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
23. Flack H.D., and Bernardinelli G. J. Appl. Crystallogr. 33 (2000) 1143