Binding catalysis and inhibition by metal ions and protons in the enolization of phenylacetylpyrazine

Journal of Organic Chemistry

Volumn 74, Issue 9, 2009, Pages 3356-3369

  Collot, Anne Gaelle ^a   Courtney, Michael ^a   Coyne, Dara ^a   Eustace, Stephen E ^a   More O'Ferrall, Rory A ^a  

^a UNIVERSITY COLLEGE DUBLIN   (Ireland)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORBANCE MEASUREMENTS; AQUEOUS SOLUTIONS; BINDING CONSTANT; DIPROTONATION; ENAMINONE; ENOLATE ANIONS; ENOLIZATION; KETONIZATION; NMR MEASUREMENTS; PYRAZINE NITROGEN; SPECTROPHOTOMETRIC MEASUREMENTS; STABLE ENOL; TAUTOMERIC CONSTANTS; TAUTOMERIZATION; THERMODYNAMIC DRIVING FORCES;

ACIDS; CATALYSIS; COMPLEXATION; EQUILIBRIUM CONSTANTS; METAL IONS; METALS; NEGATIVE IONS; PROTON TRANSFER; PROTONS; RATE CONSTANTS; ZINC;

TRACE ANALYSIS;

ACID; AMPHOLYTE; ANION; BASE; CADMIUM; COBALT; CUPRIC ION; NICKEL; NITROGEN; PROTON; PYRAZINE DERIVATIVE; PYRIDINE DERIVATIVE; ZINC ION;

AQUEOUS SOLUTION; ARTICLE; ATOM; BINDING AFFINITY; BROMINATION; CATALYSIS; CATALYST; CHEMICAL MODIFICATION; CHEMICAL PARAMETERS; CHEMICAL REACTION KINETICS; EQUILIBRIUM CONSTANT; INHIBITION KINETICS; IODINATION; NUCLEAR MAGNETIC RESONANCE; PH; PROTON TRANSPORT; SPECTROPHOTOMETRY; THERMODYNAMICS;

EID: 66449098254     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo802650s     Document Type: Article

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