Synthesis and characterization of side-chain liquid crystalline polymers bearing cholesterol mesogen

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 47, Issue 10, 2009, Pages 2690-2701

  Suk Kyun, A H N ^a   Le, Long T Nguyen ^b   Kasi, Rajeswari M ^a  

^a UNIVERSITY OF CONNECTICUT   (United States)

^b UNIVERSITÉ PARIS DESCARTES   (France)

Author keywords

Cholesterol; Liquid crystalline polymers (LCP); Polynorbornenes; Ring opening metathesis polymerization (ROMP); Smectic phase; Structure property relations

Indexed keywords

LIQUID-CRYSTALLINE POLYMERS (LCP); POLYNORBORNENES; RING OPENING METATHESIS POLYMERIZATION (ROMP); SMECTIC PHASE; STRUCTURE-PROPERTY RELATIONS;

AUTOMOBILE SEATS; CHOLESTEROL; CHROMATOGRAPHIC ANALYSIS; CRYSTALLINE MATERIALS; CRYSTALS; ESTERS; GELATION; INFRARED SPECTROSCOPY; LIQUIDS; MONOMERS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OPTICAL MICROSCOPY; POLYMERS; RING OPENING POLYMERIZATION; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS;

LIQUID CRYSTAL POLYMERS;

EID: 66349097500     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.23354     Document Type: Article

References (71)

1. Schmidtke, J.; Stille, W.; Finkelmann, H.; Kim, S. T. Adv Mater 2002, 14, 746-749.
2. Finkelmann, H.; Kim, S. T.; Munoz, A.; Palffy- Muhoray, P.; Taheri, B. Adv Mater 2001, 13, 1069-1072.
3. Broer, D. J.; Lub, J.; Mol, G. N. Nature 1995, 378, 467-469.
4. Palffy-Muhoray, P. Nature 1998, 391, 745-746.
5. Hrozhyk, U. A.; Serak, S. V.; Tabiryan, N. V.; Bunning, T. J. Adv Funct Mater 2007, 17, 1735-1742.
6. Tamaoki, N. Adv Mater 2001, 13, 1135-1147.
7. Bobrovsky, A. Y.; Boiko, N. I.; Shibaev, V. P. Adv Mater 1999, 11, 1025-1028.
8. Wan, T.; Zou, T.; Cheng, S. X.; Zhuo, R. X. Bioma- cromolecules 2005, 6, 524-529.
9. Nagahama, K.; Ueda, Y.; Ouchi, T.; Ohya, Y. Bio- macromolecules 2007, 8, 3938-3943.
10. Zhou, C.; Yi, Z. Biomaterials 1999, 20, 2093-2099.
11. Li, L.; Tu, M.; Mou, S.; Zhou, C. Biomaterials 2001, 22, 2595-2599.
12. Klok, H. A.; Hwang, J. J.; Iyer, S. N.; Stupp, S. I. Macromolecules 2002, 35, 746-759.
13. Hwang, J. J.; Iyer, S. N.; Li, L.-S.; Claussen, R.; Harrington, D. A.; Stupp, S. I. Proc Natl Acad Sci USA 2002, 99, 9662-9667.
14. Shibaev, V. P.; Plate, N. A.; Freidzon, Y. S.J Polym Sci Polym Chem Ed 1979, 17, 1655-1670.
15. Freidzon, Y. S.; Kharitonov, A. V.; Shibaev, V. P.; Plate, N. A. Eur Polym Mater 1985, 21, 211-216.
16. Plate, N. A.; Freidzon, Y. S.; Shibaev, V. P. Pure Appl Chem 1985, 57, 1715-1726.
17. Leube, H.; Finkelmann, H. Polym Bull 1988, 20, 53-57.
18. Finkelmann, H.; Ringsdorf, H.; Siol, W.; Wendorff, J. H. Makromol Chem 1978, 179, 829-832.
19. Yamaguchi, T.; Asada, T.; Hayashi, H.; Naka- mura, N. Macromolecules 1989, 22, 1141-1144.
20. Yamaguchi, T.; Asada, T. Liq Cryst 1991, 10, 215-228.
21. Hu, J. S.; Zhang, B. Y.; Jia, Y. G.; Chen, S. Macro- molecules 2003, 36, 9060-9066.
22. Hu, J. S.; Zhang, B. Y.; Liu, L. M.; Meng, F. B. J Appl Polym Sci 2003, 89, 3944-3950.
23. Zhang, B. Y.; Hu, J. S.; Zang, B. L.; Zhou, A. J. J Appl Polym Sci 2003, 88, 1936-1941.
24. Hu, J.-S.; Zhang, B.-Y.; He, X.-Z.; Cheng, C.-Z. Liq Cryst 2004, 31, 1357-1365.
25. Hu, J.-S.; Zhang, B.-Y.; Guan, Y.; He, X.-Z. J Polym Sci Part A: Polym Chem 2004, 42, 5262-5270.
26. Zhang, B.-Y.; Meng, F.-B.; He, X.-Z.; Lin, D. Liq Cryst 2005, 32, 1161-1167.
27. Hu, J.-S.; Zhang, B.-Y.; Zhou, A.-J.; Dong, Y.-L.; Zhao, Z.-X. J Polym Sci Part A: Polym Chem 2005, 43, 3315-3323.
28. Zhang, J. H.; Bazuin, C. G.; Freiberg, S.; Brisse, F.; Zhu, X. X. Polymer 2005, 46, 7266-7272.
29. Zhang, B.-Y.; Meng, F.-B.; Tian, M.; Xiao, W.-Q. React Funct Polym 2006, 66, 551-558.
30. Zhang, B.-Y.; Meng, F.-B.; Li, Q.-Y.; Tian, M. Langmuir 2007, 23, 6385-6390.
31. Wang, Y.; Zhang, B.-Y.; He, X.-Z.; Wang, J.-W. Colloid Polym Sci 2007, 285, 1077-1084.
32. Liu, J.-H.; Hung, H.-J.; Yang, P.-C.; Tien, K.-H. J Polym Sci Part A: Polym Chem 2008, 46, 6214-6228.
33. Zhou, Y.; Kasi, R. M. J Polym Sci Part A: Polym Chem 2008, 46, 6801-6809.
34. Pugh, C.; Kiste, A. L. Prog Polym Sci 1997, 22, 601-691.
35. Trimmel, G.; Riegler, S.; Fuchs, G.; Slugovc, C.; Stelzer, F. Adv Polym Sci 2005, 176, 43-87.
36. Komiya, Z.; Pugh, C.; Schrock, R. R. Macromolecules 1992, 25, 3609-3616.
37. Komiya, Z.; Pugh, C.; Schrock, R. R. Macromole-cules 1992, 25, 6586-6592.
38. Pugh, C.; Schrock, R. R. Macromolecules 1992,25, 6593-6604.
39. Komiya, Z.; Schrock, R. R. Macromolecules 1993,26, 1387-1392.
40. Komiya, Z.; Schrock, R. R. Macromolecules 1993,26, 1393-1401.
41. Kim, S. H.; Lee, H. J.; Jin, S. H.; Cho, H. N.;Choi, S. K. Macromolecules 1993, 26, 846-848.
42. Ungerank, M.; Winkler, B.; Eder, E.; Stelzer, F. Macromol Chem Phys 1995, 196, 3623-3641.
43. Winkler, B.; Rehab, A.; Ungerank, M.; Stelzer, F. Macromol Chem Phys 1997, 198, 1417-1425.
44. Weck, M.; Mohr, B.; Maughon, B. R.; Grubbs, R. H. Macromolecules 1997, 30, 6430-6437.
45. Maughon, B. R.; Weck, M.; Mohr, B.; Grubbs, R. H. Macromolecules 1997, 30, 257-265.
46. Arehart, S. V.; Pugh, C. J Am Chem Soc 1997, 119, 3027-3037.
47. Gangadhara, I. C.; Thomas, M.; Reyx, D. J. Polym Sci Part A: Polym Chem 1998, 36, 2807-2821.
48. Pugh, C.; Bae, J.-Y.; Dharia, J.; Ge, J. J.; Cheng, S. Z. D. Macromolecules 1998, 31, 5188-5200.
49. Gabert, A. J.; Verploegen, E.; Hammond, P. T.; Schrock, R. R. Macromolecules 2006, 39, 3993-4000.
50. Singh, R.; Verploegen, E.; Hammond, P. T.; Schrock, R. R. Macromolecules 2006, 39, 8241-8249.
51. Pugh, C.; Zhu, P.; Kim, G.; Zheng, J. X.; Rubal, M. J.; Cheng, S. Z. D. J Polym Sci Part A: Polym Chem 2006, 44, 4076-4087.
52. Pasquier, C.; Van der Schaaf, P. A. PCT Int Appl WO 9937701, 1999.
53. Liu, C.; Qin, H.; Mather, P. T. J Mater Chem 2007, 17, 1543-1558.
54. Behl, M.; Lendlein, A. Soft Matter 2007, 3, 58-67.
55. Ahn, S.-K.; Kasi, R. M.; Kim, S.-C.; Sharma, N.; Zhou, Y. Soft Matter 2008, 4, 1151-1157.
56. Hamley, I. W.; Castelletto, V.; Parras, P.; Lu, Z. B.; Imrie, C. T.; Itoh, T. Soft Matter 2005, 1, 355-363.
57. Shannon, P. J. Macromolecules 1983, 16, 1677-1678.
58. Shannon, P. J. Macromolecules 1984, 17, 1873-1876.
59. Jacobine, A. F.; Glaser, D. M.; Nakos, S. T. Polym Mater Sci Eng 1989, 60, 211-216.
60. Bielawski, C. W.; Grubbs, R. H. Prog Polym Sci 2007, 32, 1-29.
61. Maynard, H. D.; Okada, S. Y.; Grubbs, R. H. Mac- romolecules 2000, 33, 6239-6248.
62. Bielawski, C. W.; Grubbs, R. H. Angew Chem Int Ed 2000, 39, 2903-2906.
63. Pollino, J. M.; Stubbs, L. P.; Weck, M. Macromole- cules 2003, 36, 2230-2234.
64. Craig, A. A.; Imrie, C. T. Macromolecules 1995, 28, 3617-3624.
65. Trilla, M.; Pleixats, R.; Parella, T.; Blanc, C.; Dieudonne, P.; Guari, Y.; Man, M. W. C. Langmuir 2008, 24, 259-265.
66. Kim, G. H.; Pugh, C.; Cheng, S. Z. D. Macromole- cules 2000, 33, 8983-8991.
67. Davidson, P. Prog Polym Sci 1996, 21, 893-950.
68. Lin, W.-Y.; Murugesh, M. G.; Sudhakar, S.; Yang, H.-C.; Tai, H.-C.; Chang, C.-S.; Liu, Y.-H.; Wang, Y.; Chen, I. W. P.; Chen, C.-H.; Luh, T.-Y. Chem Eur J 2005, 12, 324-330.
69. Percec, V.; Schlueter, D. Macromolecules 1997, 30, 5783-5790.
70. Fox, M. A. Acc Chem Res 1999, 32, 201-207.
71. The d-spacing of secondary peak, d2, is comparable to the calculated side-chain length (31.7 A)of the cholesterol and the methylene spacers in its extended conformation.