Kinetic and theoretical comprehension of diverse rate laws and reactivity gaps in Ccoriolus hirsutus laccase-catalyzed oxidation of acido and cyclometalated RuII complexes

Biochemistry

Volumn 48, Issue 21, 2009, Pages 4519-4527

  Kurzeev, Sergey A ^a,b   Vilesov, Alexander S ^a   Fedorova, Tatyana V ^a   Stepanova, Elena V ^a   Koroleva, Olga V ^a   Bukh, Christian ^c   Bjerrum, Morten J ^c   Kurnikov, Igor V ^d   Ryabov, Alexander D ^d  

^a BACH INSTITUTE OF BIOCHEMISTRY   (Russian Federation)

^b MOSCOW STATE UNIVERSITY   (Russian Federation)

^c UNIVERSITY OF COPENHAGEN   (Denmark)

^d CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2-PHENYLPYRIDINE; BIPYRIDINE; CATALYZED OXIDATION; CYCLOMETALATED COMPLEXES; DIOXYGEN; ENZYMATIC OXIDATIONS; ENZYME-SUBSTRATE COMPLEXES; FIRST-ORDER; KINETIC REGIME; LACCASE; LACCASES; MICHAELIS-MENTEN KINETIC; MONTE CARLO SIMULATION; PHENANTHROLINE; PING-PONG MECHANISM; RATE LAWS; RATE-LIMITING STEPS; RE-OXIDATION; SECOND ORDER KINETICS; STOPPED-FLOW MEASUREMENTS; THEORETICAL MODELING; UV-VIS SPECTROSCOPY;

MONTE CARLO METHODS; OXIDATION; REACTION KINETICS; RUTHENIUM COMPOUNDS; ULTRAVIOLET SPECTROSCOPY;

RATE CONSTANTS;

1,10 PHENANTHROLINE; 2,2' BIPYRIDINE; LACCASE; OXYGEN; PYRIDINE DERIVATIVE; QUINOLINE DERIVATIVE; RUTHENIUM; RUTHENIUM COMPLEX;

ARTICLE; CATALYSIS; CHEMICAL INTERACTION; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; CORIOLUS HIRSUTUS; ENZYME SUBSTRATE COMPLEX; MICHAELIS MENTEN KINETICS; MONTE CARLO METHOD; NONHUMAN; OXIDATION; PH; PRIORITY JOURNAL; ULTRAVIOLET SPECTROSCOPY; WHITE ROT FUNGUS;

BIOCATALYSIS; CATALYTIC DOMAIN; KINETICS; LACCASE; MODELS, MOLECULAR; MOLECULAR CONFORMATION; MONTE CARLO METHOD; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; RUTHENIUM; TRAMETES;

CORIOLUS; TRAMETES HIRSUTA;

EID: 66349083493     PISSN: 00062960     EISSN: None     Source Type: Journal    
DOI: 10.1021/bi8020058     Document Type: Article

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