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Volumn 30, Issue 9-10, 2009, Pages 826-839

Segmental mobility in the non-crystalline regions of semicrystalline polymers and its implications on melting

Author keywords

Differential scanning calorimetry (DSC); Lamellar; Melting point; NMR; Polyethylene (PE)

Indexed keywords

CHAIN DYNAMICS; CHAIN MOBILITY; CRYSTAL SUBSTRATES; CRYSTALLINE REGIONS; DIFFERENT PROTOCOLS; LAMELLAR; MELT STATE; MELTING BEHAVIOR; MELTING PROCESS; NMR; NMR SPECTROSCOPY; POLYMERISATION; SEGMENTAL MOBILITY; SEMI-CRYSTALLINE POLYMER; SEMICRYSTALLINE; THERMAL ANALYSIS; UHMW-PE;

EID: 66249140576     PISSN: 10221336     EISSN: 15213927     Source Type: Journal    
DOI: 10.1002/marc.200900025     Document Type: Article
Times cited : (22)

References (39)
  • 8
    • 66249127841 scopus 로고    scopus 로고
    • L. Corbeij-Kurelec, Chain mobility in polymer systems, Chapter 3, PhD. thesis, Eindhoven University of Technology 2001; http://alexandria.tue.nl/extra2/200113706.pdf
    • L. Corbeij-Kurelec, "Chain mobility in polymer systems", Chapter 3, PhD. thesis, Eindhoven University of Technology 2001; http://alexandria.tue.nl/extra2/200113706.pdf
  • 10
    • 3042818233 scopus 로고    scopus 로고
    • The authors are aware that depending on the experimental methods used, different numerical Gibbs-Thomson equations exist (see: T. Y. Cho, B. Heck, G. Strobl, Colloid Polym. Sci. 2004, 282, 825). A difference arises because of different surface free energy values resulting in a somewhat different melting temperature of 136 °C for a crystal thickness of 25 nm. However, such discrepancies in the calculated melting temperatures have no implications on our experimental findings.
    • The authors are aware that depending on the experimental methods used, different numerical Gibbs-Thomson equations exist (see: T. Y. Cho, B. Heck, G. Strobl, Colloid Polym. Sci. 2004, 282, 825). A difference arises because of different surface free energy values resulting in a somewhat different melting temperature of 136 °C for a crystal thickness of 25 nm. However, such discrepancies in the calculated melting temperatures have no implications on our experimental findings.
  • 19
    • 3042818233 scopus 로고    scopus 로고
    • the calculated crystal thickness for the melting temperature of 138.4 °C is 47 nm; this is also larger than the measured thickness. From
    • From T. Y. Cho, B. Heck, G. Strobl, Colloid Polym Sci. 2004, 282, 825, the calculated crystal thickness for the melting temperature of 138.4 °C is 47 nm; this is also larger than the measured thickness.
    • (2004) Colloid Polym Sci , vol.282 , pp. 825
    • Cho, T.Y.1    Heck, B.2    Strobl, G.3
  • 24
    • 66249127139 scopus 로고    scopus 로고
    • th Edition, Chapter 24.6, 27.4. 28.12, Oxford University Press, 1995.
    • th Edition, Chapter 24.6, 27.4. 28.12, Oxford University Press, 1995.
  • 25
    • 66249128883 scopus 로고    scopus 로고
    • -1, a value obtained from the ATHAS data bank (http://athas.prz.rzeszow.pl/).
    • -1, a value obtained from the ATHAS data bank (http://athas.prz.rzeszow.pl/).
  • 27
  • 39
    • 66249105957 scopus 로고    scopus 로고
    • Heterogeneity in polymer melts by controlled melting of polymer crystals
    • PhD Thesis, Eindhoven University of Technology, March 6th
    • th 2007.
    • (2007)
    • Lippits, D.R.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.