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Volumn 48, Issue 11, 2009, Pages 4625-4627

Synthesis and characterization of new mono- and heptazinc complexes with unusual amide coordination modes

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; ORGANOMETALLIC COMPOUND; ZINC;

EID: 66249116284     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic900373f     Document Type: Article
Times cited : (22)

References (34)
  • 3
  • 16
    • 84868949623 scopus 로고    scopus 로고
    • Synthesis of 1: A methanolic solution (10 mL) of Zn(C104) 2 · 6H20 (0.780 g, 2.094 mmol) was slowly added into a stirring 15 mL methanol solution of H5cadp (0.494 g, 1.047 mmol) and K2CO3 (0.868 g, 6.282 mmol, The reaction mixture was then stirred for 2 h at room temperature. The off-white precipitate formed was filtered and washed with methanol-water (1:1, v/v) followed by Et2O and hexane. The product was dried in vacuo over anhydrous calcium sulfate. The X-ray-quality single crystals were grown by slow ether diffusion into the H2O-MeOH solution of the complex. Yield: 0.680 g 85, Anal. Calcd for C46H70N8O 24Zn3: C, 42.04; H, 5.36; N, 8.52. Found: C, 42.62; H, 5.15; N, 8.76
    • 3: C, 42.04; H, 5.36; N, 8.52. Found: C, 42.62; H, 5.15; N, 8.76.
  • 17
    • 84868949748 scopus 로고    scopus 로고
    • 8: C, 42.38; H, 3.51; N, 7.86. Found: C, 42.57; H, 4.04; N, 7.63.
    • 8: C, 42.38; H, 3.51; N, 7.86. Found: C, 42.57; H, 4.04; N, 7.63.
  • 24
    • 84868938318 scopus 로고    scopus 로고
    • Crystallographic data: 1, C46H94N8O 36Zn3, Mr, 1531.40, triclinic, space group P1̄ α, 10.361(2) Å, b, 12.638(2) Å, c, 14.161(2) Å, α, 76.263(4)° β, 71.423(5)° γ, 65.824(5)° V, 1591.2(5) Å3, Z, 1, μ, 1.225 mm-1, ρcalcd, 1.598 mg/m3, 21 220 reflections collected, 11284 unique (Rint, 0.0305, R, 0.0569 [I > 2ρ(I, Rw, 0.1628 all data
    • w = 0.1628 (all data).
  • 28
    • 84868938319 scopus 로고    scopus 로고
    • Crystallographic data: 2, C90H127N 14O45C13Na4Zn8, M r, 2846.33, monoclinic, space group P21/c, a, 18.482(2) Å, b, 37.887(5) Å, c, 17.466(2) Åβ, 113.341(5)° V, 11229(2) Å3, Z, 4,μ, 1.860 mm -1, ρcalcd, 1.684mg/m3, 95986 reflections collected, 19757 unique (Rint, 0.0254, R, 0.0563 [I > 2ρ(I, Rw, 0.1614 all data
    • w = 0.1614 (all data).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.